Structural approach of the features of the spin crossover transition in iron (II) compounds

Journal of Materials Chemistry

Volumn 9, Issue 4, 1999, Pages 985-994

  Guionneau, Philippe ^a,b   Létard, Jean François ^b   Yufit, Dimitrii S ^a   Chasseau, Daniel ^b   Bravic, Georges ^b   Goeta, Andrés E ^a   Howard, Judith A K ^a   Kahn, Olivier ^b  

^a DURHAM UNIVERSITY   (United Kingdom)

^b INST CHIM MATIERE COND BORDEAUX   (France)

Author keywords

[No Author keywords available]

Indexed keywords

FERROUS ION; IRON COMPLEX;

ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; HIGH TEMPERATURE; HYSTERESIS; LOW TEMPERATURE; PHASE TRANSITION; STRUCTURE ANALYSIS;

EID: 0032951148     PISSN: 09599428     EISSN: None     Source Type: Journal    
DOI: 10.1039/a808075e     Document Type: Article

References (42)

1. 1 H. A. Goodwin, Coord. Chem. Rev., 1976, 18, 293; P. Gütlich,Struct. Bonding (Berlin), 1981, 44, 83; E. König, Prog. Inorg.Chem., 1987, 35, 527; P. Gütlich and A. Hauser, Coord. Chem.Rev., 1990, 97, 1; P. Gütlich, A. Hauser and H. Spiering, Angew.Chem., Int. Ed. Engl., 1994, 33, 2024 and references therein; P. Gütlich, J. Jung and H. A. Goodwin, Molecular magnetism:from Molecular Assemblies to the devices, NATO ASI Ser. E, ed.E. Coronado, 1996, vol. 321, pp. 327-378.
2. 1 H. A. Goodwin, Coord. Chem. Rev., 1976, 18, 293; P. Gütlich, Struct. Bonding (Berlin), 1981, 44, 83; E. König, Prog. Inorg.Chem., 1987, 35, 527; P. Gütlich and A. Hauser, Coord. Chem.Rev., 1990, 97, 1; P. Gütlich, A. Hauser and H. Spiering, Angew.Chem., Int. Ed. Engl., 1994, 33, 2024 and references therein; P. Gütlich, J. Jung and H. A. Goodwin, Molecular magnetism:from Molecular Assemblies to the devices, NATO ASI Ser. E, ed.E. Coronado, 1996, vol. 321, pp. 327-378.
3. 1 H. A. Goodwin, Coord. Chem. Rev., 1976, 18, 293; P. Gütlich,Struct. Bonding (Berlin), 1981, 44, 83; E. König, Prog. Inorg. Chem., 1987, 35, 527; P. Gütlich and A. Hauser, Coord. Chem.Rev., 1990, 97, 1; P. Gütlich, A. Hauser and H. Spiering, Angew.Chem., Int. Ed. Engl., 1994, 33, 2024 and references therein; P. Gütlich, J. Jung and H. A. Goodwin, Molecular magnetism:from Molecular Assemblies to the devices, NATO ASI Ser. E, ed.E. Coronado, 1996, vol. 321, pp. 327-378.
4. 1 H. A. Goodwin, Coord. Chem. Rev., 1976, 18, 293; P. Gütlich,Struct. Bonding (Berlin), 1981, 44, 83; E. König, Prog. Inorg.Chem., 1987, 35, 527; P. Gütlich and A. Hauser, Coord. Chem. Rev., 1990, 97, 1; P. Gütlich, A. Hauser and H. Spiering, Angew.Chem., Int. Ed. Engl., 1994, 33, 2024 and references therein; P. Gütlich, J. Jung and H. A. Goodwin, Molecular magnetism:from Molecular Assemblies to the devices, NATO ASI Ser. E, ed.E. Coronado, 1996, vol. 321, pp. 327-378.
5. 1 H. A. Goodwin, Coord. Chem. Rev., 1976, 18, 293; P. Gütlich,Struct. Bonding (Berlin), 1981, 44, 83; E. König, Prog. Inorg.Chem., 1987, 35, 527; P. Gütlich and A. Hauser, Coord. Chem.Rev., 1990, 97, 1; P. Gütlich, A. Hauser and H. Spiering, Angew. Chem., Int. Ed. Engl., 1994, 33, 2024 and references therein; P. Gütlich, J. Jung and H. A. Goodwin, Molecular magnetism:from Molecular Assemblies to the devices, NATO ASI Ser. E, ed.E. Coronado, 1996, vol. 321, pp. 327-378.
6. 1 H. A. Goodwin, Coord. Chem. Rev., 1976, 18, 293; P. Gütlich,Struct. Bonding (Berlin), 1981, 44, 83; E. König, Prog. Inorg.Chem., 1987, 35, 527; P. Gütlich and A. Hauser, Coord. Chem.Rev., 1990, 97, 1; P. Gütlich, A. Hauser and H. Spiering, Angew.Chem., Int. Ed. Engl., 1994, 33, 2024 and references therein; P. Gütlich, J. Jung and H. A. Goodwin, Molecular magnetism: from Molecular Assemblies to the devices, NATO ASI Ser. E, ed. E. Coronado, 1996, vol. 321, pp. 327-378.
7. 2 O. Kahn and J. P. Launay, Chemtronics, 1988, 3, 140; J. Zarembovitch and O. Kahn, New. J. Chem., 1991, 15, 181; O. Kahn, Molecular Magnetism, VCH, New York, 1993.
8. 2 O. Kahn and J. P. Launay, Chemtronics, 1988, 3, 140; J. Zarembovitch and O. Kahn, New. J. Chem., 1991, 15, 181; O. Kahn, Molecular Magnetism, VCH, New York, 1993.
9. 2 O. Kahn and J. P. Launay, Chemtronics, 1988, 3, 140; J. Zarembovitch and O. Kahn, New. J. Chem., 1991, 15, 181; O. Kahn, Molecular Magnetism, VCH, New York, 1993.
10. 3 W. Vreugdenhil, J. H. van Diemen, R. A. G. de Graaf, J. G. Haasnoot, J. Reedgijk, A. M. Kraan, O. Kahn and J. Zarembovitch, Polyhedron, 1990, 9, 2971; O. Kahn, J. Kröberand C. Jay, Adv. Mater., 1992, 4, 178; J. Krôber, J. P. Audière,R. Claude, E. Codjovi, O. Kahn, J. G. Haasnoot, F. Grolière,C. Jay, A. Bousseksou, J. Linarès, F. Varret and A. Gonthier-Vassal, Chem. Mater., 1994, 6, 1404; L. G. Lavrenova, V. N.Ikorskii, V. A. Varnek, I. M. Oglezneva and S. V. Larionov,Polyhedron, 1995, 14, 1333; G. Lemercier, M. Verelst,A. Bousseksou, F. Varret and J. P. Tuchagues, Magnetism: ASupramolecular Function, NATO ASI Ser. E, ed. O. Kahn, KluwerAcademic, 1996, pp. 335-356.
11. 3 W. Vreugdenhil, J. H. van Diemen, R. A. G. de Graaf, J. G.Haasnoot, J. Reedgijk, A. M. Kraan, O. Kahn andJ. Zarembovitch, Polyhedron, 1990, 9, 2971; O. Kahn, J. Kröber and C. Jay, Adv. Mater., 1992, 4, 178; J. Krôber, J. P. Audière,R. Claude, E. Codjovi, O. Kahn, J. G. Haasnoot, F. Grolière,C. Jay, A. Bousseksou, J. Linarès, F. Varret and A. Gonthier-Vassal, Chem. Mater., 1994, 6, 1404; L. G. Lavrenova, V. N.Ikorskii, V. A. Varnek, I. M. Oglezneva and S. V. Larionov,Polyhedron, 1995, 14, 1333; G. Lemercier, M. Verelst,A. Bousseksou, F. Varret and J. P. Tuchagues, Magnetism: ASupramolecular Function, NATO ASI Ser. E, ed. O. Kahn, KluwerAcademic, 1996, pp. 335-356.
12. 3 W. Vreugdenhil, J. H. van Diemen, R. A. G. de Graaf, J. G.Haasnoot, J. Reedgijk, A. M. Kraan, O. Kahn andJ. Zarembovitch, Polyhedron, 1990, 9, 2971; O. Kahn, J. Kröberand C. Jay, Adv. Mater., 1992, 4, 178; J. Krôber, J. P. Audière, R. Claude, E. Codjovi, O. Kahn, J. G. Haasnoot, F. Grolière, C. Jay, A. Bousseksou, J. Linarès, F. Varret and A. Gonthier-Vassal, Chem. Mater., 1994, 6, 1404; L. G. Lavrenova, V. N.Ikorskii, V. A. Varnek, I. M. Oglezneva and S. V. Larionov,Polyhedron, 1995, 14, 1333; G. Lemercier, M. Verelst,A. Bousseksou, F. Varret and J. P. Tuchagues, Magnetism: ASupramolecular Function, NATO ASI Ser. E, ed. O. Kahn, KluwerAcademic, 1996, pp. 335-356.
13. 3 W. Vreugdenhil, J. H. van Diemen, R. A. G. de Graaf, J. G.Haasnoot, J. Reedgijk, A. M. Kraan, O. Kahn andJ. Zarembovitch, Polyhedron, 1990, 9, 2971; O. Kahn, J. Kröberand C. Jay, Adv. Mater., 1992, 4, 178; J. Krôber, J. P. Audière,R. Claude, E. Codjovi, O. Kahn, J. G. Haasnoot, F. Grolière,C. Jay, A. Bousseksou, J. Linarès, F. Varret and A. Gonthier-Vassal, Chem. Mater., 1994, 6, 1404; L. G. Lavrenova, V. N. Ikorskii, V. A. Varnek, I. M. Oglezneva and S. V. Larionov, Polyhedron, 1995, 14, 1333; G. Lemercier, M. Verelst,A. Bousseksou, F. Varret and J. P. Tuchagues, Magnetism: ASupramolecular Function, NATO ASI Ser. E, ed. O. Kahn, KluwerAcademic, 1996, pp. 335-356.
14. 3 W. Vreugdenhil, J. H. van Diemen, R. A. G. de Graaf, J. G.Haasnoot, J. Reedgijk, A. M. Kraan, O. Kahn andJ. Zarembovitch, Polyhedron, 1990, 9, 2971; O. Kahn, J. Kröberand C. Jay, Adv. Mater., 1992, 4, 178; J. Krôber, J. P. Audière,R. Claude, E. Codjovi, O. Kahn, J. G. Haasnoot, F. Grolière,C. Jay, A. Bousseksou, J. Linarès, F. Varret and A. Gonthier-Vassal, Chem. Mater., 1994, 6, 1404; L. G. Lavrenova, V. N.Ikorskii, V. A. Varnek, I. M. Oglezneva and S. V. Larionov,Polyhedron, 1995, 14, 1333; G. Lemercier, M. Verelst, A. Bousseksou, F. Varret and J. P. Tuchagues, Magnetism: A Supramolecular Function, NATO ASI Ser. E, ed. O. Kahn, Kluwer Academic, 1996, pp. 335-356.
15. 4 J. F. Létard, P. Guionneau, E. Codjovi, L. Olivier, G. Bravic, D. Chasseau and O. Kahn, J. Am. Chem. Soc., 1997, 199, 10861.
16. 3, R = 0.043.
17. 6 V. Ksenofontov, G. Levchenko, H. Spiering, P. Gütlich, J. F. Létard, Y. Bouhedja and O. Kahn, Chem. Phys. Lett., 1998, 294, 545.
18. 7 J. F. Létard, S. Montant, P. Guionneau, P. Martin, A. Le Calvez, E. Freysz, D. Chasseau, R. Lapouyade and O. Kahn, Chem. Commun., 1997, 745. See the journal instructions to obtain the corresponding. cif files.
19. 8 SMART Version 4.050, Siemens Analytical X-ray Instruments, Madison, WI, 1995.
20. 9 SAINT Version 4.050, Siemens Analytical X-ray Instruments, Madison, WI, 1995.
21. 10 G. M. Sheldrick, SHELXTL-Plus, Release 4.1, Siemens Analytical X-ray Instruments Inc., Madison, WI, 1991.
22. 11 G. M. Sheldrick, SADABS Empirical Absorption Program, Univ. of Gottingen, 1995.
23. 12 R. C. B. Copley, A. E. Goeta, C. W. Lehmann, J. Cole, D. S. Yufit, J. A. K Howard and J. Archer, J. Appl. Crystallogr., 1997, 30, 413.
24. 13 C. J. Gilmore, MITHRIL, J. Appl. Crystallogr., Sect. B, 1984, 17, 42.
25. 14 C. Roux, J. Zarembovitch, B. Gallois, T. Granier and R. Claude, Inorg. Chem. 1994, 33, 2273.
26. 15 E. König and K. J. Watson, Chem. Phys. Lett., 1970, 6, 457.
27. 16 G. Vos, R. A. G. de Graaf, J. G. Haasnot, A. M. van der Kraan, P. de Vaal and J. Reedijk, Inorg. Chem., 1984, 23, 2905.
28. 17 J. A. Real, B. Gallois, T. Granier, F. Suez-Panama and J. Zarembovitch, Inorg. Chem., 1992, 31, 4972.
29. 18 B. Gallois, J. A. Real, C. Hauw and J. Zarembovitch, Inorg. Chem., 1990, 29, 1152.
30. 19 M. A. Hoselton, L. J. Wilson and R. S. Drago, J. Am. Chem. Soc., 1975, 97, 1722.
31. 20 M. Mikami and Y. Saito, Acta Crystallogr., Sect. B, 1982, 38, 452.
32. 21 L. Wiehl, G. Kiel, C. P. Köhler, H. Spiering and P. Gütlich, Inorg. Chem., 1986, 25, 1565.
33. 22 J. Gaultier, T. Granier, B. Gallois, J. A. Real and J. Zarembovitch, High Pressure Res., 1991, 7, 336.
34. 23 T. Granier, B. Gallois, J. Gaultier, J. A. Real and J. Zarembovitch, Inorg. Chem., 1993, 32, 5305.
35. 24 M. Mikami, M. Konno and Y. Saito, Acta Crystallogr., Sect. B, 1980, 36, 275.
36. 25 P. Guionneau, J. Gaultier, D. Chasseau, G. Bravic, Y. Barrans, L. Ducasse, D. Kanazawa, P. Day and M. Kurmoo, J. Phys. I Fr., 1996, 6, 1581; P. Guionneau, C. J. Kepert, M. Rosseinsky, D.Chasseau, J. Gaultier, M. Kurmoo, M. B. Hursthouse and P. Day,J. Mater. Chem., 1997, 7, 367; D. Chasseau, J. Gaultier, G. Bravic,L. Ducasse, M. Kurmoo and P. Day, Proc. R. Soc. London Ser. A,1993, 442, 207.
37. 25 P. Guionneau, J. Gaultier, D. Chasseau, G. Bravic, Y. Barrans,L. Ducasse, D. Kanazawa, P. Day and M. Kurmoo, J. Phys. I Fr.,1996, 6, 1581; P. Guionneau, C. J. Kepert, M. Rosseinsky, D. Chasseau, J. Gaultier, M. Kurmoo, M. B. Hursthouse and P. Day, J. Mater. Chem., 1997, 7, 367; D. Chasseau, J. Gaultier, G. Bravic,L. Ducasse, M. Kurmoo and P. Day, Proc. R. Soc. London Ser. A,1993, 442, 207.
38. 25 P. Guionneau, J. Gaultier, D. Chasseau, G. Bravic, Y. Barrans,L. Ducasse, D. Kanazawa, P. Day and M. Kurmoo, J. Phys. I Fr.,1996, 6, 1581; P. Guionneau, C. J. Kepert, M. Rosseinsky, D.Chasseau, J. Gaultier, M. Kurmoo, M. B. Hursthouse and P. Day,J. Mater. Chem., 1997, 7, 367; D. Chasseau, J. Gaultier, G. Bravic, L. Ducasse, M. Kurmoo and P. Day, Proc. R. Soc. London Ser. A, 1993, 442, 207.
39. 26 J. K. McCuster, A. L. Rheingold and D.N. Hendrickson, Inorg. Chem., 1996, 35, 2100; E. König, Struct. Bonding (Berlin), 1991,76, 51.
40. 26 J. K. McCuster, A. L. Rheingold and D.N. Hendrickson, Inorg.Chem., 1996, 35, 2100; E. König, Struct. Bonding (Berlin), 1991, 76, 51.
41. 27 F. Cecconi, M. DiVaira, S. Midollini, A. Orlandini and L. Sacconi, Inorg. Chem., 1981, 20, 2043.
42. 28 C.-C. Wu, J. Jung, P. K. Gantzel, P. Gütlich and D. N. Hendrickson, Inorg. Chem., 1997, 36, 5339.