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0343694310
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Aldrich catalog (1998-1999, Japan): 3-bromobenzotrifluoride; 11 000 yen (100 g), 3-(trifluoromethyl)aniline; 4900 yen (100 g)
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Aldrich catalog (1998-1999, Japan): 3-bromobenzotrifluoride; 11 000 yen (100 g), 3-(trifluoromethyl)aniline; 4900 yen (100 g).
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28
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0033515561
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Recently, asymmetric transfer hydrogenation of 6 was improved up to 97% ee by chiral rhodium complex. Murata, K.; Ikariya, T.; Noyori, R. J. Org. Chem. 1999, 64, 2186.
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-
-
-
-
31
-
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0342823871
-
-
note
-
2O, L-tartaric acid was selected due to higher cost of D-tartaric acid. Aldrich catalog (1998-1999, Japan): D-tartaric acid; 7800 yen (99% ee, 100 g), L-tartaric acid; 2700 yen (99% ee, 500 g).
-
-
-
-
32
-
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0342823870
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note
-
N,N-Diethylaniline and n-heptane could be recycled by fractional distillation of the filtrate.
-
-
-
-
33
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0343258641
-
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note
-
2O [2:1 (v/v)] was 95:5.
-
-
-
-
34
-
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0343694308
-
-
note
-
(Z)-Ketoxime ethers were not detected at all by HPLC.
-
-
-
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35
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0008503285
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Behrens, O.K.5
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36
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0029125707
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Naemura, K.; Fukuda, R.; Murata, M.; Konishi, M.; Hirose, K.; Tobe, Y Tetrahedron: Asymmetry 1995, 6, 2385.
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37
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