α-RuCl3/polymer nanocomposites: The first group of intercalative nanocoraposites with transition metal halides

Journal of the American Chemical Society

Volumn 122, Issue 28, 2000, Pages 6629-6640

  Wang, Lei ^a   Rocci Lane, Melissa ^b   Brazis, Paul ^b   Kannewurf, Carl R ^b   Kim, Young Il ^c   Lee, Woo ^c   Choy, Jin Ho ^c   Kanatzidis, Mercouri G ^a  

^a MICHIGAN STATE UNIVERSITY   (United States)

^b Northwestern University   (United States)

^c Seoul National University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

RUBIDIUM CHLORIDE;

ARTICLE; CHEMICAL COMPOSITION; INTERCALATION COMPLEX; ION TRANSPORT; METAL BINDING; POLYMERIZATION; PRECIPITATION; SOLUBILITY; THERMOGRAVIMETRY; X RAY DIFFRACTION;

EID: 0034686680     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9944610     Document Type: Article

References (78)

1. Leroux, F.; Koene, B. E.; Nazar, L. F. J. Electrochem. Soc. 1996, 143 (9), L181.
2. (b) Leroux, F.; Goward, G.; Power, W. P.; Nazar, L. F. J. Electrochem. Soc. 1997, 144, 3886.
3. Wang, Y.; Herron, N. Science 1996, 273 (5275), 632.
4. (a) O'Hare, D. In Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; John Wiley & Sons Ltd: New York, 1992; p 164.
5. (b) Ruiz-Hitzky, E. Adv. Mater. 1993, 5, 334.
6. (c) Alberti, G.; Bein, T., Eds. Comprehensive Supramolecular Chemistry; Elsevier Science Ltd: New York, 1996; Vol. 7.
7. (d) Giannelis, E. P. Adv. Mater. 1996, 8, 29.
8. (a) Giannelis, E. P. Adv. Mater. 1996, 8, 29.
9. (b) Ruiz-Hitzky, E.; Aranda, P.; Casal, B.; Galván, J. C. Adv. Mater. 1995, 7, 180.
10. (a) Hsu, C.-H.; Labes, M. M.; Breslin, J. T.; Edmiston, D. J.; Winter, J. J.; Leupold, H. A.; Rothwarf, F. Nature, Phys. Sci., 1973, 246 (155), 122.
11. (b) Kanatzidis, M. G.; Bissessur, R.; DeGroot, D. C.; Schindler, J. L.; Kannewurf, C. R. Chem. Mater. 1993, 5, 595.
12. (a) Liu, Y.-J.; DeGroot, D. C.; Schindler, J. L.; Kannewurf, C. R.; Kanatzidis, M. G. Adv. Mater. 1993, 5, 369.
13. (b) Nazar, L. F.; Zhang, Z.; Zinkweg, D. J. Am. Chem. Soc. 1992, 114, 6239.
14. Lagadic, I.; Léaustic, A.; Clément, R. J. Chem. Soc., Chem. Commun. 1992, 1396.
15. (a) Schöllhorn, R.; Steffen, R.; Wagner, K. Angew. Chem., Int. Ed. Engl. 1983, 22, 555.
16. (b) Steffen, R.; Schöllhorn, R. Solid State Ionics 1986, 22, 31.
17. (c) Nonte, W.; Lobert, M.; Miller-Warmuth, W.; Schöllhorn, R. Synth. Met. 1989, 34, 665.
18. Wang, L.; Brazis, P.: Rocci, M.; Kannewurf, C. R.: Kanatzidis, M. G. Chem. Mater. 1998, 10, 3298.
19. 2: (a) Bissessur, R.; Kanatzidis, M. G.; Schindler, J. L.; Kannewurf, C. R. J. Chem. Soc., Chem. Commun. 1993, 1582. (b) Wang, L.: Schindler, J.; Kannewurf, C. R.; Kanatzidis, M. G. J. Mater. Chem. 1997, 7, 1277. (c) Wang, L.; Schindler, J.; Kannewurf, C. R.; Kanatzidis, M. G. Manuscript in preparation, (d) Tsai, H.-L., Schindler, J. L.; Kannewurf, C. R.; Kanatzidis, M. G. Chem. Mater. 1997, 9, 875.
20. 2: (a) Bissessur, R.; Kanatzidis, M. G.; Schindler, J. L.; Kannewurf, C. R. J. Chem. Soc., Chem. Commun. 1993, 1582. (b) Wang, L.: Schindler, J.; Kannewurf, C. R.; Kanatzidis, M. G. J. Mater. Chem. 1997, 7, 1277. (c) Wang, L.; Schindler, J.; Kannewurf, C. R.; Kanatzidis, M. G. Manuscript in preparation, (d) Tsai, H.-L., Schindler, J. L.; Kannewurf, C. R.; Kanatzidis, M. G. Chem. Mater. 1997, 9, 875.
21. 2: (a) Bissessur, R.; Kanatzidis, M. G.; Schindler, J. L.; Kannewurf, C. R. J. Chem. Soc., Chem. Commun. 1993, 1582. (b) Wang, L.: Schindler, J.; Kannewurf, C. R.; Kanatzidis, M. G. J. Mater. Chem. 1997, 7, 1277. (c) Wang, L.; Schindler, J.; Kannewurf, C. R.; Kanatzidis, M. G. Manuscript in preparation, (d) Tsai, H.-L., Schindler, J. L.; Kannewurf, C. R.; Kanatzidis, M. G. Chem. Mater. 1997, 9, 875.
22. 2: (a) Bissessur, R.; Kanatzidis, M. G.; Schindler, J. L.; Kannewurf, C. R. J. Chem. Soc., Chem. Commun. 1993, 1582. (b) Wang, L.: Schindler, J.; Kannewurf, C. R.; Kanatzidis, M. G. J. Mater. Chem. 1997, 7, 1277. (c) Wang, L.; Schindler, J.; Kannewurf, C. R.; Kanatzidis, M. G. Manuscript in preparation, (d) Tsai, H.-L., Schindler, J. L.; Kannewurf, C. R.; Kanatzidis, M. G. Chem. Mater. 1997, 9, 875.
23. 2: (a) Wang, L.; Schindler, J. L.; Thomas, J. A.; Kannewurf, C. R.; Kanatzidis, M. G. Chem. Mater. 1995, 7, 1753. (b) Kerr, T. A.; Wu, H.; Nazar, L. F. Chem. Mater 1996, 8, 2005. (c) Wang, L. Intercalated Polymer-Layered Inorganic Nanocomposites, Ph.D. Dissertation, 1999, Department of Chemistry, Michigan State University.
24. 2: (a) Wang, L.; Schindler, J. L.; Thomas, J. A.; Kannewurf, C. R.; Kanatzidis, M. G. Chem. Mater. 1995, 7, 1753. (b) Kerr, T. A.; Wu, H.; Nazar, L. F. Chem. Mater 1996, 8, 2005. (c) Wang, L. Intercalated Polymer-Layered Inorganic Nanocomposites, Ph.D. Dissertation, 1999, Department of Chemistry, Michigan State University.
25. 2: (a) Wang, L.; Schindler, J. L.; Thomas, J. A.; Kannewurf, C. R.; Kanatzidis, M. G. Chem. Mater. 1995, 7, 1753. (b) Kerr, T. A.; Wu, H.; Nazar, L. F. Chem. Mater 1996, 8, 2005. (c) Wang, L. Intercalated Polymer-Layered Inorganic Nanocomposites, Ph.D. Dissertation, 1999, Department of Chemistry, Michigan State University.
26. Brauer, G. Handbook of Preparative Inorganic Chemistry; Academic-Press Inc.: New York, 1965; Vol. 2, p 1597.
27. 3 was determined similarly.
28. (a) Selwood, P. W. Magnetochemistry, 2nd ed.; Interscience Publishers: New York, 1956; p 78.
29. (b) Drago, R. S. Physical Methods for Chemists; 2nd ed.; Saunders College Publishing: Philadelphia/San Diego/ New York, 1992; Chapter 11.
30. (c) Epstein, A. J.; Ginder, J. M.; Richter, A. F.; MacDiarmid, A. G. In Conducting Polymers; Alcácer, L., Ed.; D. Reidel Publishing Company: Dordrecht, The Netherlands, 1986; p 121.
31. Lyding, J. W.; Marcy, H. O.; Mark T. J.; Kannewurf, C. R. IEEE. Trans. Instrum. Meas. 1988, 37, 76.
32. PEAKOC is an XRD powder pattern analysis computer program provided by Inel Inc. (Mail Adress in U.S.A.: P.O. Box 147, Stratham, NH 03885.)
33. Leung, S. Y.; Dresselhaus, M. S.; Underhill, C.; Krapchev, T.; Dresselhaus, G.; Wuensch, B. J. Phys. Rev. B-Cond. Matter 1981, 24 (6), 3505-3518
34. (a) Choy, J. H.; Park, N. G.; Kim, Y. I.; Hwang, S. H.; Lee, J. S.; Yoo, H. I. J. Phys. Chem. 1995, 99, 7845.
35. (b) Lee, J. S.; Yoo, H. I. Solid State Ionics 1994, 68, 139.
36. Wu, C.-G.; DeGroot, D. C.; Marcy, H. O.; Schindler, J. L.; Kannewurf, C. R.; Bakas, T.; Papaefthymiou, V.; Hirpo, W.; Yesinowski, J. P.; Liu, Y.-J.; Kanatzidis, M. G. J. Am. Chem. Soc. 1995, 117, 9229.
37. Wu, C.-G.; Marcy, H. O.; Kannewurf, C. R.; Kanatzidis, M. G. J. Am. Chem. Soc. 1989, 111, 4139.
38. Nakajima, H.; Matsubayashi, G. J. Mater. Chem. 1994, 4 (8) 1325.
39. Bissessur, R.; Schindler, J. L.; Kannewurf, C. R.; Kanatzidis, M. G. Mol. Cryst. Liq. Cryst. 1993, 245, 249-254
40. 3, suggesting no change in intralayer structure during intercalation and thus a truly topotactic process.
41. -1: Kang, E. T.; Neoh, K. G.; Tan, T. C.; Ong, Y. K. J. Macromol. Sci.-Chem. 1987, A24 (6), 631.
42. 2 layer one unit cell contains one Mo and two S atoms: its a-axis dimension is 3.159 Å. By comparison, for one unit cell of two Ru and six Cl atoms has 5.87 Å as its a-axis dimension.)
43. Toshima, N.; Ihata, O. Synth. Met. 1996, 79, 165.
44. (a) Wu, C. G.; DeGroot, D. C.; Marcy, H. O.; Schindler, J. L.; Kannewurf, C. R.; Liu, Y. J.; Hirpo, W.; Kanatzidis, M. G. Chem Mater 1996, 8 (8) 1992.
45. (b) Wu, C. G. Ph.D. Dissertation, Michigan State University, 1992.
46. 3 even after one month.
47. Binotto, L.; Pollini, I.; Spinolo, G. Phys. Status Solidi B 1971, 44, 245.
48. Kobayashi, Y.; Okada, T.; Asai, K.; Katada, M.; Sano, H.; Ambe, F. Inorg. Chem. 1992, 31, 4570.
49. (a) Nazar, L. F.; Zhang, Z.; Zinkweg, D. J. Am. Chem. Soc. 1992, 114, 6239.
50. (b) Aranda, P.; Ruiz-Hitzky, E. Chem. Mater. 1992, 4, 1395.
51. (c) Nazar, L. F.; Wu, H.; Power, W. P. J. Mater. Chem. 1995, 5, 1985.
52. (d) Liu, Y.-J.; Schindler, J, L.; DeGroot, D. C.; Kannewurf, C. R.; Hirpo, W.; Kanatzidis, M. G. Chem. Mater. 1996, 8, 525.
53. (e) Matsuo, Y.; Tahara, K.; Sugie, Y. Carbon 1997, 35, 113.
54. (f) Kerr, T. A.; Wu, H.; Nazar, L. F. Chem. Mater. 1996, 8, 2005.
55. (a) Takahashi, Y.; Tadokoro, H. Macromolecules 1973, 6, 672.
56. (b) Brandrup, J.; Immergut, E. H. Polymer Handbook, 3rd ed.; John Wiley & Sons: New York, 1989, pp VI/72.
57. Price, F. P.; Kilb, R. W. J. Polym. Sci. 1962, 57, 395.
58. Takahashi, Y.; Sumita, I.; Tadokoro, H. J. Polym. Sci., Polym. Phys. Ed. 1973, 11, 2113.
59. (a) Blumberg, A. A.; Pollack, S. S. J. Polym. Sci., Part A 1964, 2, 2499.
60. (b) Ishihara, H.; Saito, Y.; Ishihara, H.; Tadokoro, H. J. Polym. Sci., A-2 1968, 6, 1509.
61. Yokoyama, M.; Ishihara, H.; Ishihara, H.; Tadokoro, H. Macromolecules 1969, 2, 184.
62. Parker, J. M.; Wright, P. V.; Lee, C. C. Polymer 1981, 22, 1305.
63. (a) Chatani, Y.; Okamura, S. Polymer 1987, 28, 1815.
64. (b) Lightfoot, P.; Mehta, M. A.; Bruce, P. G. Science 1993, 262, 883.
65. (c) Lightfoot, P.; Nowinski, J. L.; Bruce, P. G. J. Am. Chem. Soc. 1994, 116, 7469.
66. Chatani, Y.; Fujii, Y.; Takayanagi, T.; Honma, A. Polymer 1990, 31, 2238.
67. Tadokoro, H.; Yoshihara, T.; Chatani, Y.; Murahashi, S. J. Polym. Sci. B 1964, 2, 363.
68. Tadokoro, H. Macromol. Rev. 1966, 1, 119.
69. Point, J. J.; Coutelier, C. J. Polym. Sci., Polym. Phys. Ed. 1985, 23, 231.
70. (a) Point, J. J.; Damman, P. Macromolecules 1992, 25, 1184.
71. (b) Damman, P.; Point, J. J. Macromolecules 1994, 27, 3919.
72. 2 conformations. These calculated maps do not match the experimental data and are not presented.
73. 2 side. Tunney. J. J., Detellier, C. Chem. Mater. 1996, 8, 927.
74. 3 ratio was determined to be 0.2 with EDS analysis. The amount of PEO was determined from C, H, N analysis.
75. Yang, D.-K.; Zax, D. B. J. Chem. Phys. 1999, 110, 5325.
76. Gray, F. M. Solid Polymer Electrolytes; VCH Publisher: New York, 1991; Chapter 5, p 83.
77. Papke, B. L.; Ratner, M. A.; Shriver, D. F. J. Phys Chem. Solids 1981, 42, 493.
78. Reference 35b provides the spectra of two orientations with the electric vector perpendicular and parallel to the fiber axes. A spectrum from an un-oriented sample should correspond to the superposition of the two spectra.