Redox intercalative polymerization of aniline in V2O5 xerogel. The postintercalative intralamellar polymer growth in polyaniline/metal oxide nanocomposites is facilitated by molecular oxygen

Chemistry of Materials

Volumn 8, Issue 8, 1996, Pages 1992-2004

  Wu, C G ^a   DeGroot, D C ^b   Marcy, H O ^b   Schindler, J L ^b   Kannewurf, C R ^b   Liu, Y J ^a   Hirpo, W ^a   Kanatzidis, M G ^a  

^a MICHIGAN STATE UNIVERSITY   (United States)

^b Northwestern University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DEGREE OF POLYMERIZATION; GEL PERMEATION CHROMATOGRAPHY (GPC); INTERLAYER SEPARATION; PHYSICO-CHEMICAL DATA; REDOX INTERCALATIVE POLYMERIZATION; ROOM-TEMPERATURE CONDUCTIVITY; SITU OXIDATIVE POLYMERIZATION; VARIABLE TEMPERATURE;

ANILINE; CHAINS; GEL PERMEATION CHROMATOGRAPHY; MAGNETIC MOMENTS; OXYGEN; POLYANILINE; POLYMERIZATION; POLYMERS; XEROGELS;

EXTRACTION;

EID: 59449091928     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/cm9600236     Document Type: Article

References (58)

1. (a) Kanatzidis, M. G.; Wu, C.-G.; Marcy, H. O.; Kannewurf, C. R. J. Am. Chem. Soc. 1989, 111, 4139-4141.
2. (b) Wu, C.-G.; Kanatzidis, M. G.; Marcy, H. O.; DeGroot, D. C.; Kannewurf, C. R. Polym. Mater. Sci. Eng. 1989, 61, 969-973.
3. (c) Wu, C.-G.; Kanatzidis, M. G.; Marcy, H. O.; DeGroot, D. C.; Kannewurf, C. R. NATO Advanced Study Institute, Lower Dimensional Systems and Molecular Devices, Metzger, R. M., Ed.; Plenum Press: New York, 1991; pp 427-434.
4. (d) Kanatzidis, M. G.; Wu, C.-G.; Marcy, H. O.; DeGroot, D. C.; Kannewurf, C. R. Chem. Mater. 1990, 2, 221-224.
5. (e) Wu, C.-G.; Kanatzidis, M. G. Symposium on Solid State Ionics Nazri, G., Huggins, R. A., Shriver, D. F., Balkanski, M. Eds.; MRS Symp. Proc. 1991, 210, 429-442.
6. (f) DeGroot, D. C.; Schindler, J. L; Kannewurf, C. R.; Liu, Y.-J.; Wu, C.-G.; Kanatzidis, M. G. Symposium on Submicron Multiphase Materials; Baney, R., Gilliom, L., Schmidt, H., Hirano, S.-I., Eds.; Mater. Res. Soc. Symp. Proc. 1992, 133-138.
7. (a) Wu, C.-G.; DeGroot, D. C.; Marcy, H. O.; Schindler, J. L.; Kannewurf, C. R.; Bakas, T.; Papaefthymiou, V.; Hirpo, W.; Yesinowski, J.; Liu, Y.-J.; Kanatzidis, M. G. J. Am. Chem. Soc. 1995, 117, 9229-9242.
8. (b) Kanatzidis, M. G.; Wu, C.-G.; Marcy, H. O.; DeGroot, D. C.; Schindler, J. L.; Kannewurf, C. R.; Benz, M; LeGoff, E. Supramolecular Chemistry in Two and Three Dimensions; Bein, T., Ed.; ACS Symp. Ser. 1992, 499, 194-219.
9. (c) Kanatzidis, M. G.; Wu, C.-G.; DeGroot, D. C.; Schindler, J. L.; Benz, M; LeGoff, E.; Kannewurf, C. R. NATO Advanced Study Institute in Chemical Physics of Intercalation; Bernier, P., Fischer, J. E., Roth, S., Solin, S., Eds.; Plenum Press: New York, 1993; pp 63-72.
10. (a) Yao T.; Oka, Y.; Yamamoto, N. Mater. Res. Bull. 1992, 27, 669-675.
11. (b) Yao T.; Oka, Y.; Yamamoto, N. J. Mater. Chem. 1992, 2, 331-336.
12. (c) Yao T.; Oka, Y.; Yamamoto, N. J. Mater. Chem. 1992, 2, 337-340
13. (d) Legendre, J.-J.; Livage, J. J. Colloid Interface Sci. 1983, 94, 75-83.
14. (e) Livage, J. Chem. Mater. 1991, 3, 573-593.
15. Siminovitch, D. J.; Raleigh, D. P.; Olejniczak, E. T.; Griffin, R. G. J. Chem. Phys. 1986, 84, 2556.
16. (a) Diel, B. N.; Inabe, T.; Lyding, J. W.; Schock, K. F., Jr.; Kannewurf, C. R.; Marks, T. J. J. Am. Chem. Soc. 1983, 105, 1551-1567.
17. (b) Lyding, J. W.; Marcy, H. O.; Marks, T. J.; Kannewurf, C. R. IEEE. Trans. Instrum. Meas. 1988, 37, 76-80.
18. (a) Kim, Y. H.; Foster, C.; Chiang, J.; Heeger, A. J. Synth. Met. 1988, 26, 49-59.
19. (b) Ohira, M.; Sakai, T.; Takeuchi, M.; Kobayashi, Y.; Tsuji, M. Synth. Met. 1987, 18, 347-352.
20. (c) Wudl, F.; Augus, R. O., Jr.; Lu, F. L.; Allemand, P. H.; Vachon, D. J.; Nowak, M.; Liu, Z. X.; Heeger, A. J. J. Am. Chem. Soc. 1987, 109, 3677-3684.
21. (d) Vachon, D.; Angus, R. O.; Lu, F. L.; Nowak, M.; Liu, Z. X.; Schaffer, H.; Wudl, F.; Heeger, A. J. Synth. Met. 1987, 18, 297-302.
22. (e) Lu, F.-L.; Wudl, F.; Nowak, M.; Heeger, A. J. J. Am Chem. Soc. 1986, 108, 8311-8313.
23. Scherrer formula: D = (0.9λ)/β cos θ. D: average crystallite size normal to the reflection plane in Å. λ: radiation wavelength (Å). β: half-width in radiants. θ = Bragg angle in degrees.
24. Livage, J.; Gharbi, N.; Leroy, N. C.; Michaud, M. Mater. Res. Bull. 1978, 13, 1117-1124.
25. Kanatzidis, M. G.; et al., work in progress.
26. (a) Genti, G.; Pinelli D.; Trifiro, F. J. Mol. Catal. 1990, 59, 221-231.
27. (b) Ross, R. A.; Fairbridge, C. Can. J. Chem. 1984, 62, 1483-1491.
28. (a) Genies, E, M.; Syed, A. A.; Tsintavis, C. Mol. Cryst. Liq. Cryst. 1985, 121, 181-185.
29. (b) Watanabe, A.; Mori, K.; Iwasaki, Y.; Nakamura, J. J. Chem. Soc., Chem. Commun. 1987, 3-4.
30. (c) Wei, Y.; Hsuech, K.; Tang, X.; Sun, Y. Polym. Prepr. 1989, 30, 226-227.
31. (d) MacDiarmid, A. G.; Epstein, A. J. In European Physical Society Industrial Workshop, Science and Applications of Conducting Polymers; IOP Publishing: Lofthus, Norway, 1990.
32. It should be noted that the MW values reported here should be used only on a relative basis since they probably do not represent the true MW of the polymers. The reason for the discrepancy lies in the assumption that polystyrene in NMP is a good model polymer for polyaniline in NMP.
33. (a) Kaplan, S.; Conwell, E. M.; Richter, A. F.; MacDiarmid, A. G. Macromolecules 1989, 22, 1669.
34. (b) Kaplan, S.; Conwell, E. M.; Richter, A. F.; MacDiarmid, A. G. J. Am. Chem. Soc. 1988, 110, 7647.
35. (c) Devreux, F.; Bidan, G.; Syed, A. A.; Tsintavis, C. J. Phys. 1985, 46, 1595.
36. Liu, Y. J.; Cowen, J. A.; Kaplan, T. A.; DeGroot, D. C.; Schindler, J. L.; Kannewurf, C. R.; Kanatzidis, M. G., Chem. Mater. 1995, 7, 1616-1624.
37. (a) Ioffe, N. T.; Kogen, Y. L.; Mairanovskii, V. G. Synth. Met. 1990, 37, 74-75.
38. (b) Lapkosk, M.; Genies, E. M. J. Electroanal. Chem. 1990, 279, 158-168.
39. (c) Javadi, H. H. S.; Laversanne, R.; Epstein, A. J.; Kohli, R. K.; Scherr, E. M.; MacDiarmid, A. G. Synth. Met. 1989, 29, E439-444.
40. (a) Enzel, P.; Bein, T. J. Phys. Chem. 1989, 93, 6270-6272.
41. (b) Bein, T.; Enzel, P. Synth. Met. 1989, 29, E163-E168.
42. (c) Enzel, P.; Bein, T. J. Chem. Soc., Chem. Commun. 1989, 1326-1327.
43. Wu, C. G.; Marcy, H. O.; DeGroot, D. C.; Schindler, J. L.; Kannewurf, C. R.; Kanatzidis, M. G. Synth. Met. 1991, 41/43 693-698.
44. (a) Ginder, J. M.; Richter, A. F.; MacDiarmid, A. G.; Epstein, A. J. Solid State Commun. 1987, 63, 97-101.
45. (b) Fite, C.; Cao, Y.; Heeger, A. J. Solid State Commun. 1989, 70, 245-247.
46. (c) Wudl, F.; Angus, R. O.; Lu, F. L.; Allemand, P. M.; Vachon, D. J.; Nowak, M.; Liu, Z. X.; Heeger, A. J. J. Am. Chem. Soc. 1987, 109, 3677-3684.
47. (a) Earnshaw, A. Introduction to Magnetochemistry; Academic Press: New York, 1968.
48. (b) Boudreaux, E. A.; Mulay, L. N. Theory and Applications of Molecular Paramagnetism; John Wiley and Sons: New York, 1976 pp 122-124.
49. (c) Gladney, H. M.; Swalen, J. D. J. Chem. Phys. 1965, 42, 1999-2009.
50. (d) Drago, R. S. Physical Methods in Chemistry; W. B. Sanders Co.: Philadelphia, 1977 pp 417-426.
51. 5+ ratio.
52. (a) Javadi, H. H.; Cromack, K. R.; MacDiarmid, A. G.; Epstein, A. J. Phys. Rev. B 1989, 39, 3579-3584.
53. (b) Javadi, H. H. S.; Laversanne, R.; Epstein, A. J.; Kohli, R. K.; Scherr, E. M.; MacDiarmid, A. G. Synth. Met. 1989, 29, E439-444.
54. (c) Zuo, F.; Angelopoulos, M.; MacDiarmid, A. G.; Epstein, A. J. Phys. Rev. B 1989, 39, 3570-3578.
55. (a) Park, Y. W.; Lee, Y. S.; Park, C. Solid State Commun. 1987, 63, 1063.
56. (b) Zuo, F.; Angelopoulos, M.; MacDiarmid, A. G.; Epstein, A. J. Phys. Rev. 1987, B36, 3475-3478.
57. Liu, J.-Y.; Kanatzidis M. G. Inorg. Chem. 1993, 32, 2989-2991.
58. Liu, J.-Y.; Kanatzidis M. G. Chem. Mater. 1995, 7, 1525-1533.