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For reviews on fluorous synthesis, see: (a)
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For reviews on fluorous synthesis, see: (a) Horvath, I. T. Acc. Chem. Res. 1998, 31, 641; (b) Barthel-Rosa, L. P.; Gladysz, J. A. Coord. Chem. Rev. 1999, 190-192, 587; (c) Cornils, B. Angew. Chem., Int. Ed. Engl. 1997, 36, 2057.
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For reviews on fluorous synthesis, see: (a) Horvath, I. T. Acc. Chem. Res. 1998, 31, 641; (b) Barthel-Rosa, L. P.; Gladysz, J. A. Coord. Chem. Rev. 1999, 190-192, 587; (c) Cornils, B. Angew. Chem., Int. Ed. Engl. 1997, 36, 2057.
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For reviews on fluorous synthesis, see: (a) Horvath, I. T. Acc. Chem. Res. 1998, 31, 641; (b) Barthel-Rosa, L. P.; Gladysz, J. A. Coord. Chem. Rev. 1999, 190-192, 587; (c) Cornils, B. Angew. Chem., Int. Ed. Engl. 1997, 36, 2057.
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For a report on the synthesis of (R)- and (S)-7,7′-bis(diphenylphosphino)-2,2′-dimethoxy-1,1′- binaphthalene, see: (a) Horiuchi, T.; Ohta, T.; Stephan, M.; Takaya, H. Tetrahedron: Asymmetry 1994, 5, 325. One application of this compound has been reported: (b) Murahashi, S. Japanese Kokai Patent JP 11255726, 1999 (Chem. Abstr. 1999, 131, 214090b).
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0028198270
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One application of this compound has been reported: (b) Japanese Kokai Patent JP 11255726, 1999
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For a report on the synthesis of (R)- and (S)-7,7′-bis(diphenylphosphino)-2,2′-dimethoxy-1,1′- binaphthalene, see: (a) Horiuchi, T.; Ohta, T.; Stephan, M.; Takaya, H. Tetrahedron: Asymmetry 1994, 5, 325. One application of this compound has been reported: (b) Murahashi, S. Japanese Kokai Patent JP 11255726, 1999 (Chem. Abstr. 1999, 131, 214090b).
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Compound 6a was prepared by treatment of 2a with phosphorus oxychloride followed by (S)-1-(1-naphthyl)ethylamine. See
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Compound 6a was prepared by treatment of 2a with phosphorus oxychloride followed by (S)-1-(1-naphthyl)ethylamine. See: Sollewijn Gelpke, A. E.; Frannje, J.; Goubitz, K.; Schenk, H.; Hiemstra, H. Tetrahedron 1997, 53, 5899.
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This procedure allowed us to avoid using diphenylphosphine: (b) and Ref. 4
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This procedure allowed us to avoid using diphenylphosphine: (b) Cai, D.; Payack, J. F.; Bender, D. R.; Hughes, D. L.; Verhoeven, T. R.; Reider, P. J. J. Org. Chem. 1994, 59, 7180, and Ref. 4.
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23
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0343521197
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Note
-
w=0.1926; S=1.16 and the Flack parameter=1.02(2) and was therefore rejected as the absolute configuration present in the crystal.
-
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