Photochemistry of (η5-C5H5)(η5-C4H4N)Fe and (η5-C5H5)(η1-N-C4H4N)Fe(CO)2 in low-temperature matrixes and room-temperature solution. Evidence for a photoinduced haptotropic shift of the π-coordinated pyrrolyl ligand

Organometallics

Volumn 19, Issue 19, 2000, Pages 3867-3873

  Heenan, Davnat P ^a   Long, Conor ^a   Montiel Palma, Virginia ^b   Perutz, Robin N ^b   Pryce, Mary T ^a  

^a DUBLIN CITY UNIVERSITY   (Ireland)

^b UNIVERSITY OF YORK   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; COMPOSITION EFFECTS; DOPING (ADDITIVES); INFRARED SPECTROSCOPY; IRON COMPOUNDS; ISOMERS; LASER APPLICATIONS; ORGANIC SOLVENTS; PARAFFINS; PHOTOLYSIS; TOLUENE;

CYCLOHEXANE; HAPTOTROPIC SHIFT; LASER FLASH PHOTOLYSIS; LIGANDS;

ORGANOMETALLICS;

EID: 0034683255     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0002632     Document Type: Article

References (39)

1. Basolo, F. New J. Chem. 1994, 18, 19.
2. O'Connor, J. M.; Casey, C. D. Chem. Rev. 1987, 87, 307.
3. (a) Trayler, T. G.; Stewart, K. J.; Goldberg, M. J. J. Am. Chem. Soc. 1984, 106, 4445.
4. (b) Trayler, T. G.; Stewart, K. J.; Goldberg, M. J. Organometallics 1986, 5, 2062.
5. (c) Trayler, T. G.; Stewart, K. J. J. Am. Chem. Soc. 1986, 108, 6977.
6. (d) Trayler, T. G.; Goldberg, M. J. Organometallics 1987, 6, 2413.
7. (e) Trayler, T. G.; Goldberg, M. J. Organometallics 1987, 6, 2531.
8. (a) Strohmeier, S.; von Hobe, D. Z. Naturforsch. 1963, 18B, 770.
9. (b) Wrighton, M. S.; Haverty, J. L. Z. Naturforsch. 1973, 30B, 254.
10. (c) Nasielski, J.; Denishoff, O. J. Organomet. Chem. 1975, 102, 65.
11. (d) Gilbert, A.; Kelly, J. M.; Budzwait, M.; Koerner von Gustorf, E. Z. Naturforsch. 1976, 31B, 1091.
12. (e) Rest, A. J.; Sodeau, J. R.; Taylor, D. J. J. Chem. Soc., Dalton Trans. 1978, 651.
13. Breheny, C. J.; Draper, S. M.; Grevels, F.-W.; Klotzbücher, W. E.; Long, C.; Pryce, M. T.; Russell, G. Organometallics 1996, 15, 3679.
14. Traverse, O.; Scandola, F. Inorg. Chim. Acta 1970, 4, 493.
15. (b) Tarr, A. M.; Wiles, D. M. Can. J. Chem. 1968, 46, 2725.
16. (c) von Gustorf, E. K.; Koller, H.; Jun, M.-J.; Schenck, G. O. Chem.-Ing-Tech. 1963, 35, 591.
17. (a) Ali, L. H.; Cox, A.; Kemp, T. S. J. Chem. Soc., Dalton Trans. 1973, 1468.
18. (b) Traverse, O.; Rossi, R.; Sostero, S.; Carassiti, V. Mol. Photochem. 1973, 5, 457.
19. Davis, J.; Vaughan, D. H.; Cardosi, M. F. Electroanalysis 1997, 9, 650.
20. 2 was formed under these conditions.
21. (b) Martin, K. F.; Hanks, T. W. Organometallics 1997, 16, 4857.
22. Pan, X.; Philbin, C. E.; Castellani, M. P.; Tyler, D. R. Inorg. Chem. 1988, 27, 671.
23. Green, M. L. H.; Nagy, P. L. I. J. Chem. Soc. 1963, 189.
24. -1, possibly indicating the formation of further carbonyl-containing species.
25. 2 quoted in the literature are incorrect. We have confirmed our values by correlating our infrared spectral data obtained from a single sample of the compound with the results of high-resolution mass spectrometry and single-crystal X-ray diffraction techniques.
26. Powell, M. A.; Bailey, R. D.; Eagle, C. T.; Schimel, G. L.; Hanks, T. W.; Pennington, W. T. Acta Crystallogr. 1997, C53, 1611.
27. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, M. R.; Zakrzewski, V. G.; Montgomery, J. A., Jr.; Stratmann, R. E.; Burant, J. C.; Dapprich, S.; Millam, J. M.; Daniels, A. D.; Kudin, K. N.; Strain, M. C.; Farkas, O.; Tomasi, J.; Barone, V.; Cossi, M.; Cammi, R.; Mennucci, B.; Pomelli, C.; Adamo, C.; Clifford, S.; Ochterski, J.; Petersson, G. A.; Ayala, P. Y.; Cui, Q.; Morokuma, K.; Malick, D. K.; Abuck, A. D.; Raghavachari, K.; Foresman, J. B.; Cioslowski, J.; Ortiz, J. V.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Gomperts, R.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Gonzalez, C.; Challacombe, M.; Gill, P. M. W.; Johnson, B.; Chen, W.; Wong, M. W.; Andres, J. L.; Gonzalez, C.; Head-Gordon, M.; Replogle, E. S.; Pople, J. A. Gaussian 98, Revision A.3; Gaussian, Inc.: Pittsburgh, PA, 1998.
28. CO region.
29. Hooker, R. H.; Mahmoud, K. A.; Rest, A. J. J. Chem. Soc., Dalton Trans. 1990, 1231.
30. Alway, D. G.; Barnett, K. W. Inorg. Chem. 1978, 17, 2826.
31. Belmont, J. A.; Wrighton, M. S. Organometallics 1986, 5, 1421.
32. Fish, R. W.; Giering, W. P.; Marten, D.; Rosenblum, M. J. Organomet. Chem. 1976, 105, 101.
33. Farrell, G. Ph.D. Thesis, Dublin City University, 1992.
34. Breheny, C. J.; Kelly, J. M.; Long, C.; O'Keeffe, S.; Pryce, M. T.; Russell, G.; Walsh, M. M. Organometallics 1998, 17, 3690.
35. Pauson, P. L.; Qazi, A. R.; Rockett, B. J. Organomet. Chem. 1967, 7, 325.
36. Zakrzewski, J. J. Organomet. Chem. 1987, 327, C41-C42.
37. Boese, W. T.; Ford, P. C. Organometallics 1994, 13, 3525.
38. Makranczy, J.; Megyery-Balog, K.; Rosz, L.; Rosz, L.; Patyt, D. Hung. J. Ind. Chem. 1976, 4, 269.
39. Haddleton, D. M.; McCamley, A.; Perutz, R. N. J. Am. Chem. Soc. 1988, 110, 1810.