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-1). The crystals were not only quite small (maximum dimension 0.26 mm) but also invariably twinned. Several crystals were examined before a relatively single one was found which was used for subsequent data collection. A total of 2353 independent reflections having 2θ(Cu Kα) < 95.04° (the equivalent of 0.4 limiting Cu Kα sphere) were collected on a computer-controlled Syntex P single-crystal diffractometer using θ/2θ scans with fixed scan rates of 6 or 3%min and Ni-filtered Cu Kα radiation. "Direct methods" techniques were used to solve the structure, and the resulting structural parameters have been refined to convergence (R1(unweighted, based on F) = 0.105 for 1117 independent reflections having 2θ(Cu Kα) < 95.04° and I > 2σ(I)) using counterweighted full-matrix least-squares techniques and a structural model which incorporated anisotropic thermal parameters for all non-hydrogen atoms and isotropic thermal parameters for all included hydrogen atoms. Selected bond distances: Ni1-O1 = 1.901(10) Å; Ni1-O1′ = 1.912(12) Å; Ni1-P1 = 2.116(6) Å; Ni1-C21 = 1.91(2) Å; Ni1 ⋯Ni1′ = 2.723(5) Å. Selected bond angles: O1-Ni1-O1′ = 78.1(5)°; C21-N1-O1′ = 99.7(6)°; O1-Ni1-P1 = 88.4(4)°; C21-Ni1-P1 = 94.1-(5)°.
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