Ethylene, styrene, and α-methylstyrene polymerization by mono(pentamethylcyclopentadienyl) (Cp*) complexes of titanium, zirconium, and hafnium: Roles of cationic complexes of the type [Cp*MR2]+ (R = alkyl) as both coordination polymerization catalysts and carbocationic polymerization initiators

Organometallics

Volumn 15, Issue 2, 1996, Pages 693-703

  Wang, Qinyan ^a   Quyoum, Ruhksana ^a,b   Gillis, Daniel J ^a,c   Tudoret, Marie José ^a   Jeremic, Dusan ^a   Hunter, Brian K ^a   Baird, Michael C ^a  

^a QUEEN S UNIVERSITY   (Canada)

^b UNIVERSITY OF SHEFFIELD   (United Kingdom)

^c Uniroyal   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0038049969     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9501945     Document Type: Article

References (93)

1. See, for instance: (a) Kaminsky, W., Sinn, H., Eds. Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Springer-Verlag: Berlin, 1988. (b) Quirk, R. P., Ed. Transition Metal Catalyzed Polymerizations; Ziegler-Natta and Metathesis Polymerizations; Cambridge University Press: Cambridge, U.K., 1988. (c) Mohring, P. C.; Coville, N. J. J. Organomet. Chem. 1994, 479, 1. (d) Gupta, V. K.; Satish, S.; Bhardway, I. S. J. Macromol. Sci. 1994, C34, 439. (e) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143. For recent theoretical considerations at the density functional level, see: (f) Woo, T. K.; Fan, L.; Ziegler, T. Organometallics 1994, 13, 2252. (g) Weiss, H.; Ehrig, M.; Ahlrichs, R. J. Am. Chem. Soc. 1994, 116, 4919. For counterion effects, see: (h) Chien, J. C. W.; Song, Y.; Rausch, M. D. J. Polym. Sci.: Part A 1994, 32, 2387.
2. See, for instance: (a) Kaminsky, W., Sinn, H., Eds. Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Springer-Verlag: Berlin, 1988. (b) Quirk, R. P., Ed. Transition Metal Catalyzed Polymerizations; Ziegler-Natta and Metathesis Polymerizations; Cambridge University Press: Cambridge, U.K., 1988. (c) Mohring, P. C.; Coville, N. J. J. Organomet. Chem. 1994, 479, 1. (d) Gupta, V. K.; Satish, S.; Bhardway, I. S. J. Macromol. Sci. 1994, C34, 439. (e) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143. For recent theoretical considerations at the density functional level, see: (f) Woo, T. K.; Fan, L.; Ziegler, T. Organometallics 1994, 13, 2252. (g) Weiss, H.; Ehrig, M.; Ahlrichs, R. J. Am. Chem. Soc. 1994, 116, 4919. For counterion effects, see: (h) Chien, J. C. W.; Song, Y.; Rausch, M. D. J. Polym. Sci.: Part A 1994, 32, 2387.
3. See, for instance: (a) Kaminsky, W., Sinn, H., Eds. Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Springer-Verlag: Berlin, 1988. (b) Quirk, R. P., Ed. Transition Metal Catalyzed Polymerizations; Ziegler-Natta and Metathesis Polymerizations; Cambridge University Press: Cambridge, U.K., 1988. (c) Mohring, P. C.; Coville, N. J. J. Organomet. Chem. 1994, 479, 1. (d) Gupta, V. K.; Satish, S.; Bhardway, I. S. J. Macromol. Sci. 1994, C34, 439. (e) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143. For recent theoretical considerations at the density functional level, see: (f) Woo, T. K.; Fan, L.; Ziegler, T. Organometallics 1994, 13, 2252. (g) Weiss, H.; Ehrig, M.; Ahlrichs, R. J. Am. Chem. Soc. 1994, 116, 4919. For counterion effects, see: (h) Chien, J. C. W.; Song, Y.; Rausch, M. D. J. Polym. Sci.: Part A 1994, 32, 2387.
4. See, for instance: (a) Kaminsky, W., Sinn, H., Eds. Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Springer-Verlag: Berlin, 1988. (b) Quirk, R. P., Ed. Transition Metal Catalyzed Polymerizations; Ziegler-Natta and Metathesis Polymerizations; Cambridge University Press: Cambridge, U.K., 1988. (c) Mohring, P. C.; Coville, N. J. J. Organomet. Chem. 1994, 479, 1. (d) Gupta, V. K.; Satish, S.; Bhardway, I. S. J. Macromol. Sci. 1994, C34, 439. (e) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143. For recent theoretical considerations at the density functional level, see: (f) Woo, T. K.; Fan, L.; Ziegler, T. Organometallics 1994, 13, 2252. (g) Weiss, H.; Ehrig, M.; Ahlrichs, R. J. Am. Chem. Soc. 1994, 116, 4919. For counterion effects, see: (h) Chien, J. C. W.; Song, Y.; Rausch, M. D. J. Polym. Sci.: Part A 1994, 32, 2387.
5. See, for instance: (a) Kaminsky, W., Sinn, H., Eds. Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Springer-Verlag: Berlin, 1988. (b) Quirk, R. P., Ed. Transition Metal Catalyzed Polymerizations; Ziegler-Natta and Metathesis Polymerizations; Cambridge University Press: Cambridge, U.K., 1988. (c) Mohring, P. C.; Coville, N. J. J. Organomet. Chem. 1994, 479, 1. (d) Gupta, V. K.; Satish, S.; Bhardway, I. S. J. Macromol. Sci. 1994, C34, 439. (e) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143. For recent theoretical considerations at the density functional level, see: (f) Woo, T. K.; Fan, L.; Ziegler, T. Organometallics 1994, 13, 2252. (g) Weiss, H.; Ehrig, M.; Ahlrichs, R. J. Am. Chem. Soc. 1994, 116, 4919. For counterion effects, see: (h) Chien, J. C. W.; Song, Y.; Rausch, M. D. J. Polym. Sci.: Part A 1994, 32, 2387.
6. See, for instance: (a) Kaminsky, W., Sinn, H., Eds. Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Springer-Verlag: Berlin, 1988. (b) Quirk, R. P., Ed. Transition Metal Catalyzed Polymerizations; Ziegler-Natta and Metathesis Polymerizations; Cambridge University Press: Cambridge, U.K., 1988. (c) Mohring, P. C.; Coville, N. J. J. Organomet. Chem. 1994, 479, 1. (d) Gupta, V. K.; Satish, S.; Bhardway, I. S. J. Macromol. Sci. 1994, C34, 439. (e) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143. For recent theoretical considerations at the density functional level, see: (f) Woo, T. K.; Fan, L.; Ziegler, T. Organometallics 1994, 13, 2252. (g) Weiss, H.; Ehrig, M.; Ahlrichs, R. J. Am. Chem. Soc. 1994, 116, 4919. For counterion effects, see: (h) Chien, J. C. W.; Song, Y.; Rausch, M. D. J. Polym. Sci.: Part A 1994, 32, 2387.
7. See, for instance: (a) Kaminsky, W., Sinn, H., Eds. Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Springer-Verlag: Berlin, 1988. (b) Quirk, R. P., Ed. Transition Metal Catalyzed Polymerizations; Ziegler-Natta and Metathesis Polymerizations; Cambridge University Press: Cambridge, U.K., 1988. (c) Mohring, P. C.; Coville, N. J. J. Organomet. Chem. 1994, 479, 1. (d) Gupta, V. K.; Satish, S.; Bhardway, I. S. J. Macromol. Sci. 1994, C34, 439. (e) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143. For recent theoretical considerations at the density functional level, see: (f) Woo, T. K.; Fan, L.; Ziegler, T. Organometallics 1994, 13, 2252. (g) Weiss, H.; Ehrig, M.; Ahlrichs, R. J. Am. Chem. Soc. 1994, 116, 4919. For counterion effects, see: (h) Chien, J. C. W.; Song, Y.; Rausch, M. D. J. Polym. Sci.: Part A 1994, 32, 2387.
8. See, for instance: (a) Kaminsky, W., Sinn, H., Eds. Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Springer-Verlag: Berlin, 1988. (b) Quirk, R. P., Ed. Transition Metal Catalyzed Polymerizations; Ziegler-Natta and Metathesis Polymerizations; Cambridge University Press: Cambridge, U.K., 1988. (c) Mohring, P. C.; Coville, N. J. J. Organomet. Chem. 1994, 479, 1. (d) Gupta, V. K.; Satish, S.; Bhardway, I. S. J. Macromol. Sci. 1994, C34, 439. (e) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143. For recent theoretical considerations at the density functional level, see: (f) Woo, T. K.; Fan, L.; Ziegler, T. Organometallics 1994, 13, 2252. (g) Weiss, H.; Ehrig, M.; Ahlrichs, R. J. Am. Chem. Soc. 1994, 116, 4919. For counterion effects, see: (h) Chien, J. C. W.; Song, Y.; Rausch, M. D. J. Polym. Sci.: Part A 1994, 32, 2387.
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