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0042801640
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note
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12b involving the imino-oxime at the 6- and 5-positions, respectively.
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23
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84981810550
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85085719920
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note
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3 be added to the reaction mixture to force the reactant 4 to react completely to avoid a very difficult Chromatographic separation.
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25
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0016384899
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26
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0041799373
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note
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The reaction was performed at 0 and 50°C, but no noticeable change was observed.
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27
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0041298840
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note
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The debenzoylation of 8a in methanolic sodium methoxide was very slow and the 5′-mono-O-benzoate of 8a was isolated as a major product. Prolonged treatment of 8a with sodium methoxide in methanol led to partial deglycosylation. The debenzoylation of 9a was complete within 3 h. Details of the successful debenzoylation procedure are provided in the Supporting Information.
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29
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