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85037492236
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note
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3 confirmed that isoG 1 self-associates extensively, with aggregation factors ranging from 3.6 at 10 mM to 5.3 at 100 mM. We thank Drs. Kostas Kavallieratos and Bruce Moyer (ORNL) for communication of these results.
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14
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0032820242
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+ can be viewed as an ion-templated process, or as an example of dynamic combinatorial chemistry, wherein the cation selects for a small amount of the preformed macrocycle: Lehn, J.-M. Chem. Eur. J. 1999, 9, 2455-2463.
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Lehn, J.-M.1
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15
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85037495059
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note
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n.
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16
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85037494447
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note
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+ were determined by comparing experimental and simulated spectra using a nonlinear least squares program, gNMR-4 (Cherwell Scientific, Palo Alto, CA, 94303).
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17
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0000615752
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+ line width, indicating that the dominant exchange mechanism is bimolecular. For more quantitative details, see: (a) Strasser, O. B.; Shamsipur, M.; Popov, I. A. J. Phys. Chem. 1985, 89, 4822-4824.
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Strasser, O.B.1
Shamsipur, M.2
Popov, I.A.3
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