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1842350441
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note
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The expressions "wide" and "narrow" rim are preferred to the somewhat ambiguous "upper" and "lower" rim.
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22
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23
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0029831996
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Urea functions have been also attached to the wider rim in order to obtain host molecules for anions: (a) Scheerder, J.; van Duynhoven, J. P. M.; Engbersen, J. F. J.; Reinhoudt, D. N. Angew. Chem., Int. Ed. Engl. 1996, 35, 1090-1093. (b) Scheerder, J.; Engbersen, J. F. J.; Casnati, A.; Ungaro, R.; Reinhoudt, D. N. J. Org. Chem. 1995, 60, 6448-6454. (c) Casnati, A.; Fochi, M.; Minari, P.; Pochini, A.; Reggiani, R.; Ungaro, R.; Reinhoudt, D. N. Gazz. Chim. Ital. 1996, 126, 99-106.
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Urea functions have been also attached to the wider rim in order to obtain host molecules for anions: (a) Scheerder, J.; van Duynhoven, J. P. M.; Engbersen, J. F. J.; Reinhoudt, D. N. Angew. Chem., Int. Ed. Engl. 1996, 35, 1090-1093. (b) Scheerder, J.; Engbersen, J. F. J.; Casnati, A.; Ungaro, R.; Reinhoudt, D. N. J. Org. Chem. 1995, 60, 6448-6454. (c) Casnati, A.; Fochi, M.; Minari, P.; Pochini, A.; Reggiani, R.; Ungaro, R.; Reinhoudt, D. N. Gazz. Chim. Ital. 1996, 126, 99-106.
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25
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0002271243
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Urea functions have been also attached to the wider rim in order to obtain host molecules for anions: (a) Scheerder, J.; van Duynhoven, J. P. M.; Engbersen, J. F. J.; Reinhoudt, D. N. Angew. Chem., Int. Ed. Engl. 1996, 35, 1090-1093. (b) Scheerder, J.; Engbersen, J. F. J.; Casnati, A.; Ungaro, R.; Reinhoudt, D. N. J. Org. Chem. 1995, 60, 6448-6454. (c) Casnati, A.; Fochi, M.; Minari, P.; Pochini, A.; Reggiani, R.; Ungaro, R.; Reinhoudt, D. N. Gazz. Chim. Ital. 1996, 126, 99-106.
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27
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0000750315
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Cavitands derived from resorcarenes, which are widely used as building blocks for the synthesis of covalently linked carcerands may be also assembled via hydrogen bonds to carcerand-like capsules: Chapman, R. G.; Sherman, J. C. J Am. Chem. Soc. 1995, 117, 9081-9082.
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Dimerization has also been reported for some calix[4]arenes substituted by two urea residues at the wider rim. Scheerder, J.; Vreekamp, R. H.; Engbersen, J. F. J.; Verboom, W.; van Duynhoven, J. P. M.; Reinhoudt, D. N. J. Org. Chem. 1996, 61, 3476-3481.
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The addition of small amounts of polar solvents to solutions in apolar solvents leads to the formation of monomeric species.
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34
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0029859437
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Under similar conditions, also the monomeric form of the tetramethoxy urea derivative 1c exists only in the cone conformation, and a recently described "conformational control through self-assembly" could not be observed as such in our experiments. Compare: Castellano, R. K.; Rudkevich, D. M.; Rebek, Jr., J. J. Am. Chem. Soc. 1996, 118, 10002-10003.
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Recently a similar observation was reported; see Meissner, R.; Garcias, X.; Mecozzi, S.; Rebek, Jr., J. J. Am. Chem. Soc. 1997, 119, 77-85.
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