Role of cation size in the energy of electron transfer to 1:1 polyoxometalate ion pairs {(M+)(X(n+)VW11O40)}((8-n)-)) (M = Li, Na, K) [12]

Journal of the American Chemical Society

Volumn 122, Issue 14, 2000, Pages 3544-3545

  Grigoriev, Vladimir A ^a   Hill, Craig L ^b   Weinstock, Ira A ^a  

^a EMORY UNIVERSITY   (United States)

^b FOREST PRODUCTS LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

LITHIUM; POLYOXOMETALATE; POTASSIUM; SODIUM; UNCLASSIFIED DRUG;

CATION TRANSPORT; DIFFUSION; ELECTRON TRANSPORT; LETTER; MOLECULAR INTERACTION; OXIDATION; REDUCTION; STOICHIOMETRY;

EID: 0034640057     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja993862c     Document Type: Letter

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19. 40.
20. + forms of Amberlite IR-120 (plus) ion-exchange resin).
21. POM at low |MCl| (ΔE values of 133 (X = P, Si) to 220 mV (X = Al).
22. +] from initially added MCl, POM countercations, and buffer.