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35
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12944336001
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note
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For the detailed preparation and NMR data of 3 and 4, see the Supporting Information.
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-
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36
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12944336022
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note
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w = 0.1440, GOF = 0.990.
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-
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37
-
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12944269651
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note
-
The oxidation state of the ruthenium atoms is considered to be 3+, based on the Ru-P bond lengths in 3 and 4 (see Supporting Information and ref 3).
-
-
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39
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12944261345
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note
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w = 0.104, GOF = 1.69.
-
-
-
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40
-
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12944313636
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-
note
-
3, and a double bond (see the Supporting Information). A bridging sulfur atom coordinated to the silver ion causes a decrease of the torsion angle of Ru(1)-S(1)-S(2)-Ru(2) (130.3°) in 4 compared to that in 3 (-157.15°).
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-
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41
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12944271231
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note
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The reaction of 2 with 1-pentene in the presence of 4 or 5 equiv of silver salt in MeCN gave a mixture of ruthenium dinuclear complexes, none of which contained a silver atom. The details of identification of the mixture will be submitted soon.
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42
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0000627599
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Moll, M.4
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43
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0021098261
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45
-
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12944259847
-
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note
-
In this step, precoordination of the double bond of 1-pentene to the ruthenium atom by replacement of an MeCN ligand may be taking place to facilitate the C-H bond activation.
-
-
-
-
46
-
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12944335967
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note
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The results of the reaction of 1 with dienes, such as isoprene and 2,3-dimethylbutadiene, will be submitted soon.
-
-
-
-
47
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0033238893
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and references therein
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