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Volumn 39, Issue 1, 2000, Pages 37-43

Structure, bonding, and dipole moment of (CH3)3N-SO3. A microwave study

Author keywords

[No Author keywords available]

Indexed keywords

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; MICROWAVE RADIATION; SOLID STATE; SPECTROSCOPY; STRUCTURE ANALYSIS;

EID: 0034627665     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic990925j     Document Type: Article
Times cited : (28)

References (54)
  • 1
    • 0001670793 scopus 로고    scopus 로고
    • Hargittai, M., Hargittai, I., Eds.: JAI Press: Greenwich, CT
    • Leopold, K. R. In Advances in Molecular Structure Research; Hargittai, M., Hargittai, I., Eds.: JAI Press: Greenwich, CT, 1996; Vol. 2, p 103.
    • (1996) Advances in Molecular Structure Research , vol.2 , pp. 103
    • Leopold, K.R.1
  • 25
    • 0343363672 scopus 로고    scopus 로고
    • Phillips, J. A. Ph.D. Thesis, University of Minnesota, 1996
    • Phillips, J. A. Ph.D. Thesis, University of Minnesota, 1996.
  • 35
    • 0004150487 scopus 로고
    • Wiley: New York, Collect.
    • (a) Organic Synthesis, 2nd ed.; Wiley: New York, 1964; Collect. Vol. 1.
    • (1964) Organic Synthesis, 2nd Ed. , vol.1
  • 36
    • 0343363675 scopus 로고    scopus 로고
    • Clippard, P. H. Ph.D. Thesis, University of Michigan, 1969.
    • (b) Clippard, P. H. Ph.D. Thesis, University of Michigan, 1969.
  • 38
    • 0343363676 scopus 로고    scopus 로고
    • note
    • It might be argued that, in view of the similarity of the N-S bond length to that in the solid, the fit employing the crystal-phase parameters gives the more reasonable numbers. However, it is likely that the changes in monomer structure which occur as the dative bond forms take place at short distances where the orbital overlap is most substantial. Thus, even at the gas-phase structure of the complex, the changes in the TMA structure and SO bond length may not yet be those observed in the crystal. Moreover, it is likely that these changes result, to some degree, from forces acting in the crystal, in which case, again, the crystal-phase parameters are not necessarily more valid than the free monomer values.
  • 48
    • 0343363673 scopus 로고
    • Liebman, J. F., Greenberg, A., Eds.; VCH Publishers: Deerfield Beach, FL
    • (a) Hargittai, I.; Hargittai, M. In Molecular Structure and Energetics: Liebman, J. F., Greenberg, A., Eds.; VCH Publishers: Deerfield Beach, FL, 1987; Vol. 2, p 1.
    • (1987) Molecular Structure and Energetics , vol.2 , pp. 1
    • Hargittai, I.1    Hargittai, M.2
  • 52
    • 0343363674 scopus 로고    scopus 로고
    • note
    • 3, we regenerated the structure from available crystal data and found agreement with the value cited in ref 18.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.