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15844396575
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note
-
so is used. Similarly for the ammonia, an average bond length and bond angle are used. The S-O distances are taken from X-ray diffraction and the ammonia parameters are taken from neutron diffraction.
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51
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0001003624
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15844382110
-
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note
-
2(22°). The vibrationally averaged structure of the complex is still axially symmetric, with <θ> = 0.
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0001641271
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11B) = 3.002(13) MHz: (a) Dreizler, H. Z. Naturforsch. 1992, 47a, 342. (b) Vormann, K. Dissertation, Kiel, 1991.
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15844391804
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57
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60
-
-
15844402835
-
-
note
-
3, the predicted N-S bond distance is 2.85 Å.
-
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61
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34247886413
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63
-
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15844381720
-
-
note
-
Interestingly, examination of the abundant structural data given in ref 47 indicates that nominally single bonded N-S distances most often lie in the 1.6-1.7-Å range. The apparent shortening relative to the sum of single bond covalent radii may be attributable to contributions from multiply bonded resonance structures.
-
-
-
-
65
-
-
15844378557
-
-
note
-
3, which also exhibits a significant (0.093 Å) contraction of the dative bond upon crystallization. For this system, 60% of the change in bond length between the gas phase and solid state is realized upon the conglomeration of only four monomer units! See ref 4.
-
-
-
-
66
-
-
0000482301
-
-
14N) has a value of -2.77 MHz (which is much closer to that of a weakly bound complex than the -1.688-MHz value determined here), yet the measured increase in dipole moment upon complexation is 4.14 D! See: (a) Ruoff, R. S.; Emilsson, T.; Jaman, A. I.; Germann, T. C.; Gutowsky, H. S. J. Chem. Phys. 1992, 96, 3441. (b) Keith, T. A.; Bader, R. F. W. J. Chem. Phys. 1992, 96, 3447.
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Ruoff, R.S.1
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Germann, T.C.4
Gutowsky, H.S.5
-
67
-
-
0000572046
-
-
14N) has a value of -2.77 MHz (which is much closer to that of a weakly bound complex than the -1.688-MHz value determined here), yet the measured increase in dipole moment upon complexation is 4.14 D! See: (a) Ruoff, R. S.; Emilsson, T.; Jaman, A. I.; Germann, T. C.; Gutowsky, H. S. J. Chem. Phys. 1992, 96, 3441. (b) Keith, T. A.; Bader, R. F. W. J. Chem. Phys. 1992, 96, 3447.
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Keith, T.A.1
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0003899196
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Schuster, P., Ed.; Springer-Verlag: Berlin
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