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Prepared by the trans-halogenation of dichloroiodotoluene with aq. hydrofluoric acid and mercuric oxide in DCM;
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2S: 255.0855. Found: 255.0861.
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2S: 255.0855. Found: 255.0861.
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23
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85037968362
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Fluorination of lactone 8 with 1 equiv. of DFIT gave 3-syn-fluoro-4,5-dihydro-3-phenylsulfanyl-5-R-phenyl-2(3H)-furanone in 62% yield. The stereochemistry was established by X-ray crystallography and will be discussed in the full paper.
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Fluorination of lactone 8 with 1 equiv. of DFIT gave 3-syn-fluoro-4,5-dihydro-3-phenylsulfanyl-5-R-phenyl-2(3H)-furanone in 62% yield. The stereochemistry was established by X-ray crystallography and will be discussed in the full paper.
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24
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