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0000002449
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6
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33645899202
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Ring system of 1 is numbered here as shown in Scheme 1 according to the numbering for humulene recommended by IUPAC
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Ring system of 1 is numbered here as shown in Scheme 1 according to the numbering for humulene recommended by IUPAC.
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7
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0011238203
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33645944584
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IR spectra of the crude mixture showed the presence of a hydroxy group
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IR spectra of the crude mixture showed the presence of a hydroxy group.
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18
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0001736827
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Y. Ito, H. Aoyama, T. Hirao, A. Mochizuki and T. Saegusa, J. Am. Chem. Soc., 1979, 101, 494.
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19
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33645945795
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note
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An NOE analysis indicated a cis-fused bicyclic structure. Thus, a large percentage increment (15%) in the area intensity of the angular proton was observed by irradiation at the angular methyl protons. Vicinal coupling (J = 9.6 Hz) between a proton a to a CN group and the angular proton indicated an α-cyano group in 8b.
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21
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0003567345
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The DIRDIF program system
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University of Nijmegen, The Netherlands
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P. T. Beurskens, G. Admiraal, G. Beurskens, W. P. Bosman, S. Garcia-Granda, R. O. Gould, J. M. M. Smits and C. Smykalla, The DIRDIF program system, Technical Report of the Crystallography Laboratory, University of Nijmegen, The Netherlands, 1992.
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Technical Report of the Crystallography Laboratory
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Beurskens, P.T.1
Admiraal, G.2
Beurskens, G.3
Bosman, W.P.4
Garcia-Granda, S.5
Gould, R.O.6
Smits, J.M.M.7
Smykalla, C.8
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22
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0027608975
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A. Altomare, G. Cascarano, C. Giacovazzo and A. Guagliardi, J. Appl. Crystallogr., 1993, 26, 343.
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Altomare, A.1
Cascarano, G.2
Giacovazzo, C.3
Guagliardi, A.4
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