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0042690613
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note
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(c) We have recently carried out a kinetic study on the formation of isocyanates from carbamates with a variety of chlorosilanes.
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32
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0043191676
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note
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3N (5 equiv) in dry THF. The reaction flask is sealed under nitrogen and heated to 60°C. When the starting material is consumed, the reaction is diluted (3×-20× reaction volume) with water or 1:1 THF-water and allowed to stir until the isocyanate is hydrolyzed as determined by TLC. The free amine can then be purified or directly acetylated.
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33
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0033474891
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Wawer, I.4
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34
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0043192825
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note
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We are currently exploring the preparation of other ureido glycosides with this methodology.
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35
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0030446219
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Schmidt, R.R.4
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