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Volumn 2, Issue 20, 2000, Pages 3135-3138

The mild cleavage of 2-amino-2-deoxy-D-glucoside methoxycarbonyl derivatives

Author keywords

[No Author keywords available]

Indexed keywords

GLUCOSIDE; METHYLGLYCOSIDE;

EID: 0034609678     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol0063353     Document Type: Article
Times cited : (16)

References (36)
  • 25
    • 0028186224 scopus 로고
    • A mixture of anomers is commonly observed for this particular glycosyl donor with a C2-acetyl group. See: Schmidt, R. R.; Kinzy, W. Adv. Carbohydr. Chem. Biochem. 1994, 50, 21.
    • (1994) Adv. Carbohydr. Chem. Biochem. , vol.50 , pp. 21
    • Schmidt, R.R.1    Kinzy, W.2
  • 31
    • 0042690613 scopus 로고    scopus 로고
    • note
    • (c) We have recently carried out a kinetic study on the formation of isocyanates from carbamates with a variety of chlorosilanes.
  • 32
    • 0043191676 scopus 로고    scopus 로고
    • note
    • 3N (5 equiv) in dry THF. The reaction flask is sealed under nitrogen and heated to 60°C. When the starting material is consumed, the reaction is diluted (3×-20× reaction volume) with water or 1:1 THF-water and allowed to stir until the isocyanate is hydrolyzed as determined by TLC. The free amine can then be purified or directly acetylated.
  • 34
    • 0043192825 scopus 로고    scopus 로고
    • note
    • We are currently exploring the preparation of other ureido glycosides with this methodology.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.