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This two-step route avoids the use of the explosive 2-azidoethanol as the glycosyl acceptor. Glycosylations using 2-hydoxyethyl carbamic acid esters as glycosyl acceptors led to the predominant formation of the undesired α anomer
-
This two-step route avoids the use of the explosive 2-azidoethanol as the glycosyl acceptor. Glycosylations using 2-hydoxyethyl carbamic acid esters as glycosyl acceptors led to the predominant formation of the undesired α anomer.
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27
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When soluble base conditions were used, the product underwent base-induced decomposition during purification, resulting in lowered yields
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When soluble base conditions were used, the product underwent base-induced decomposition during purification, resulting in lowered yields.
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37
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85037512163
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3
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3.
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38
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85037521559
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Our observed line broadening and temperature dependence of the spectra is similar to that observed in Vasella's cyclic hybrids of 2.2′-bipyridine and acetylenosaccharides (ref 8a)
-
Our observed line broadening and temperature dependence of the spectra is similar to that observed in Vasella's cyclic hybrids of 2.2′-bipyridine and acetylenosaccharides (ref 8a).
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-
39
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85037502991
-
-
The uncyclized oligomers have molecular weights 26 units lower than their cyclic counterparts because the p-nitrophenyl carbamate is hydrolyzed on workup to the amines
-
The uncyclized oligomers have molecular weights 26 units lower than their cyclic counterparts because the p-nitrophenyl carbamate is hydrolyzed on workup to the amines.
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