Crystal structures of tris(8-dimethylaminonaphthyl)phosphane and its hydrochloride salt. The first seven-coordinate phosphorus compound

Inorganic Chemistry

Volumn 39, Issue 7, 2000, Pages 1338-1339

  Chandrasekaran, A ^a   Timosheva, Natalya V ^a   Day, Roberta O ^a   Holmes, Robert R ^a  

^a UNIVERSITY OF MASSACHUSETTS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

PHOSPHORUS DERIVATIVE; TRIS(8 DIMETHYLAMINONAPHTHYL)PHOSPHANE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0034599313     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic991295o     Document Type: Article

References (15)

1. (a) Holmes, R. R. Pentacoordinated Phosphorus - Structure and Spectroscopy, Vol. I; ACS Monograph 175; American Chemical Society: Washington, DC, 1980; 479 pp and references therein.
2. (b) Holmes, R. R. Pentacoordinated Phosphorus - Reaction Mechanisms, Vol. II; ACS Monograph 176; American Chemical Society: Washington, DC, 1980; 237 pp and references therein.
3. Holmes, R. R. Chem. Rev. 1996, 96, 927 and references therein.
4. Kawashima, T. In Chemistry of Hypervalent Compounds; Akiba, K.-y., Ed.; Wiley-VCH: New York, 1999; pp 171-210 and references therein.
5. Wong, C. Y.; Kennepohl, D. K.; Cavell, R. G. Chem. Rev. 1996, 96, 1917 and references therein.
6. Holmes, R. R. Acc. Chem. Res. 1998, 31, 535.
7. Chuit, C.; Corriu, R. J. P.; Monforte, P.; Reyé, C.; Declercq, J.-P.; Dubourg, A. Ang ew. Chem., Int. Ed. Engl. 1993, 32, 1430.
8. Light, R. W.; Hutchins, L. D.; Paine, R. T.; Campana, C. F. Inorg. Chem. 1980, 19, 3597.
9. PH = 691 Hz). Two types of N-Me protons are evident, i.e., those attached to C101, C201, and C301 and those attached to C102, C202, and C302.
10. w = 0.2122. The hydrogen atom attached to phosphorus in 2 was located from a difference Fourier and refined isotropically. In the crystal lattice of 2, there was a dichloromethane molecule with one of the chlorine atoms disordered. The disordered chlorine was refined in three positions with equal occupancies.
11. (b) Chandrasekaran, A.; Sood, P.; Day, R. O.; Holmes, R. R. Inorg. Chem. 1999, 38, 3369.
12. Sutton, L., Ed. Tables of Interatomic Distances and Configuration in Molecules and Ions: The Chemical Society: London, 1958 and 1965; Special Publications 11 and 18.
13. Bondi, A. J. Phys. Chem. 1964, 68, 441.
14. Fachinformations-Zentrum, Karlsruhe Gesellschaft für wissenschaftlichtechnische Information mbH, D-76344 Eggenstein-Leopoldshafen, Germany. Depository number CSD-57389 refers to the number reported in the article cited in ref 6.
15. ORTEX 5e, McArdle, P. Crystallography Centre, Chemistry Department, University College, Galway, Ireland.