First overtone helium nanodroplet isolation spectroscopy of molecules bearing the acetylenic CH chromophore

Journal of Chemical Physics

Volumn 113, Issue 23, 2000, Pages 10535-10550

  Callegari, C ^a   Conjusteau, A ^a   Reinhard, I ^a,b   Lehmann, K K ^a   Scoles, G ^a  

^a PRINCETON UNIVERSITY   (United States)

^b GSI HELMHOLTZZENTRUM FÜR SCHWERIONENFORSCHUNG GMBH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLENE; LASERS; MOLECULES; NANOSTRUCTURED MATERIALS; SPECTROSCOPY;

HYDROGEN CYANIDE; PROPYNE;

HELIUM;

EID: 0034508072     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1324003     Document Type: Article

References (77)

1. S. Goyal, D. Schutt, and G. Scoles, Phys. Rev. Lett. 69, 933 (1992).
2. F. Stienkemeier, J. Higgins, W. E. Ernst, and G. Scoles, Phys. Rev. Lett. 74, 3592 (1995).
3. J. Higgins et al., Science 273, 629 (1996).
4. K. Nauta and R. Miller, Science 283, 1895 (1999).
5. K. Nauta and R. E. Miller, Science 287, 293 (2000).
6. M. Hartmann et al., Phys. Rev. Lett. 76, 4560 (1996).
7. J. Reho et al., Faraday Discuss, Chem. Soc. 108, 161 (1997).
8. S. Grebenev, J. P. Toennies, and A. F. Vilesov, Science 279, 2083 (1998).
9. C. Callegari et al., Phys. Rev. Lett. 83, 5058 (1999); 84, 1848 (E) (2000).
10. C. Callegari et al., Phys. Rev. Lett. 83, 5058 (1999); 84, 1848 (E) (2000).
11. F. Stienkemeier et al., Phys. Rev. Lett. 82, 2320 (1999).
12. M. Quack and W. Kutzelnigg, Ber. Bunsenges. Phys. Chem. 99, 231 (1995).
13. M. Gruebele and R. Bigwood, Int. Rev. Phys. Chem. 17, 91 (1998).
14. M. Hartmann, R. Miller, J. P. Toennies, and A. Vilesov, Phys. Rev. Lett. 75, 1566 (1995).
15. J. Harms et al., J. Mol. Spectrosc. 185, 204 (1997).
16. I. Reinhard et al., Phys. Rev. Lett. 82, 5036 (1999).
17. C. Callegari et al., J. Chem. Phys. 113, 4636 (2000).
18. K. Lehmann, Mol. Phys. 97, 645 (1999).
19. K. Nauta and R. Miller, J. Chem. Phys. 111, 3426 (1999).
20. C. Callegari, I. Reinhard, A. Conjusteau, K.K. Lehmann, and G. Scoles, 53rd Ohio State University International Symposium on Molecular Spectroscopy. 1998; A. Conjusteau, C. Callegari, I. Reinhard, K. K. Lehmann, and G. Scoles, ibid, 1998; I. Reinhard, C. Callegari, K. K. Lehmann, and G. Scoles, ibid, 1998.
21. C. Callegari, I. Reinhard, A. Conjusteau, K.K. Lehmann, and G. Scoles, 53rd Ohio State University International Symposium on Molecular Spectroscopy. 1998; A. Conjusteau, C. Callegari, I. Reinhard, K. K. Lehmann, and G. Scoles, ibid, 1998; I. Reinhard, C. Callegari, K. K. Lehmann, and G. Scoles, ibid, 1998.
22. C. Callegari, I. Reinhard, A. Conjusteau, K.K. Lehmann, and G. Scoles, 53rd Ohio State University International Symposium on Molecular Spectroscopy. 1998; A. Conjusteau, C. Callegari, I. Reinhard, K. K. Lehmann, and G. Scoles, ibid, 1998; I. Reinhard, C. Callegari, K. K. Lehmann, and G. Scoles, ibid, 1998.
23. K. K. Lehmann, B. H. Pate, and G. Scoles, in Mode Selective Chemistry, Jerusalem Symposium on Quantum Chemistry and Biochemistry, Jerusalem, Israel, edited by J. Jortner, R. D. Levine, and B. Pullman (Kluwer Academic, Dordrecht, Boston, 1991), Vol. 24, pp. 17-23.
24. E. Kerstel et al., J. Phys. Chem. 95, 8282 (1991).
25. B. Pate, K. Lehmann, and G. Scoles, J. Chem. Phys. 95, 3891 (1991).
26. J. Gambogi, J. Timmermans, K. Lehmann, and G. Scoles, J. Chem. Phys. 99, 9314 (1993).
27. J. Gambogi, E. Kerstel, K. Lehmann, and G. Scoles, J. Chem. Phys. 100, 2612 (1994).
28. A. Kerstel, K. Lehmann, B. Pate, and G. Scoles, J. Chem. Phys. 100, 2588 (1994).
29. A. McIlroy et al., J. Chem. Phys. 100, 2596 (1994).
30. J. Gambogi et al., Ber. Bunsenges. Phys. Chem. 99, 548 (1995).
31. J. Gambogi et al., J. Mol. Spectrosc. 175, 198 (1996).
32. G. Herzberg, Molecular Spectra and Molecular Structure (Krieger, Malabar, Florida, 1991), Vol. 2: Infrared and Raman Spectra of Polyatomic Molecules.
33. Propyne was obtained from Lancaster Synthesis, Inc.; DCCH from ICON (Isotope) Services, Inc.; trifluoropropyne from PCR, Inc; tertbutylacetylene and trimethylsilylacetylene from Aldrich Chemical Company, Inc.
34. F. A. Miller and D. H. Lemmon, Spectrochim. Acta, Part A 23, 1415 (1967).
35. E. L. Knuth, B. Schilling, and J. P. Toennies, in International Symposium on Rarefied Gas Dynamics (19th: 1994 University of Oxford), edited by J. Harvey and G. Lord (Oxford University Press, Oxford, 1995), Vol. 19, pp. 270-276, (N) was calculated according to the scaling law given in this reference; since no explicit dependence of 〈N〉 on the scaling parameter Γ is given, the data in Fig. 1 were fitted to a line obtaining ln(〈N〉)=2.44 + 2.25 ln(Γ).
36. M. Hartmann et al., J. Chem. Phys. 110, 5109 (1999).
37. K. Whaley, Int. Rev. Phys. Chem. 13, 41 (1994).
38. R. J. Donnelly and C. F. Barenghi, J. Phys. Chem. Ref. Data 27, 1217 (1998).
39. S. Goyal, D. Schutt, and G. Scoles, J. Phys. Chem. 97, 2236 (1993).
40. T. Gough, M. Mengel, P. Rowntree, and G. Scoles, J. Chem. Phys. 83, 4958 (1985).
41. M. Lewerenz, B. Schilling, and J. Toennies, J. Chem. Phys. 102, 8191 (1995).
42. -2/3.
43. Burleigh FCL-130. Burleigh Instruments Inc.
44. G. Guelachvili and K. N. Rao, Handbook of Infrared Standards (Academic, Boston, 1993), Vol. II.
45. Silicon Bolometer, composite type, Infrared Laboratories, Tucson, AZ.
46. D. R. Miller, in Atomic and Molecular Beam Methods, edited by G. Scoles (Oxford University Press, New York, 1988), Vol. 1, Chap. 2, pp. 14-53.
47. LN-6C cold module, Infrared Laboratories, Tucson, AZ.
48. C. Chapados and G. Birnbaum, J. Mol. Spectrosc. 132, 323 (1988).
49. A. M. Smith, S. L. Coy, W. Klemperer, and K. K. Lehmann, J. Mol. Spectrosc. 134, 134 (1989).
50. E. Manousakis and V. R. Pandharipande, Phys. Rev. B 33, 150 (1986).
51. A. Maki et al., J. Mol. Spectrosc. 180, 323 (1996).
52. K. Nauta and R. Miller, Phys. Rev. Lett. 82, 4480 (1999).
53. A. Conjusteau et al., J. Chem. Phys. 113, 4840 (2000).
54. E. Lee, D. Farrelly. and K. Whaley, Phys. Rev. Lett. 83, 3812 (1999).
55. M. Lewerenz, B. Schilling, and J. Toennies, Chem. Phys. Lett. 206, 381 (1993).
56. K. Nauta and R. E. Miller, Acetylene solvated in superfluid helium nano-droplets: Spectroscopic evidence for near resonant coupling between molecular rotation and rotons, 2000.
57. K. Nauta und R. E. Miller (private communication).
58. P. L. Chapowsky and L. J. F. Hermans, Annu. Rev. Phys. Chem. 50, 315 (1999).
59. F. Frayer and G. Ewing, J. Chem. Phys. 48, 781 (1968).
60. K. Nauta, D. Moore, and R. Miller, Faraday Discuss. Chem. Soc. 113, 261 (1999).
61. K. Lehmann and B. Pate, J. Mol. Spectrosc. 144, 443 (1990).
62. D. Eichenauer and R. L. Roy, J. Chem. Phys. 88, 2898 (1988).
63. J. Jortner and N. Ben-Horin, J. Chem. Phys. 98, 9346 (1993).
64. K. M. Atkins and J. M. Hutson, J. Chem. Phys. 105, 440 (1996).
65. A. M. Smith, W. Klemperer, and K. K. Lehmann, J. Chem. Phys. 94, 5040 (1991).
66. C. M. Dion, A. Keller, O. Atabek, and A. D. Bandrauk, Phys. Rev. A 59, 1382 (1999).
67. nHF (n = 1 -3, v = 1 -3), which show that, at a given n, the total shift of the HF stretch frequency scales linearly with v.
68. nHF (n = 1 -3, v = 1 -3), which show that, at a given n, the total shift of the HF stretch frequency scales linearly with v.
69. E. Hudspeth, D. A. McWhorter, and B. H. Pate, J. Chem. Phys. 109, 4316 (1998).
70. C. O'Brien, Senior thesis, Princeton University, 1994.
71. P. Mallinson and A. Fayt, Mol. Phys. 32, 473 (1976).
72. K. Yamada, A. Moravec, and G. Winnewisser, Z. Naturforsch. A 50, 1179 (1995).
73. V. Horneman, G. Graner, H. Fakour, and G. Tarrago, J. Mol. Spectrosc. 137, 1 (1989).
74. H. Harder et al., J. Mol. Spectrosc. 167, 24 (1994).
75. A. J. Alexander, S. Firth, H. W. Kroto, and D. R. M. Walton, J. Chem. Soc., Faraday Trans. 88, 531 (1992).
76. L. Pierce and D. H. Petersen, J. Chem. Phys. 33, 907 (1960).
77. J. Liévin, M. A. Temsamani, P. Gaspard, and M. Herman, Chem. Phys. 190, 419 (1995).