Influence of electric field strength and emitter temperature on dehydrogenation and C-C cleavage in field desorption mass spectrometry of polyethylene oligomers

European Journal of Mass Spectrometry

Volumn 6, Issue 1, 2000, Pages 11-17

  Gross, Jürgen H ^a   Weidner, Steffen M ^b  

^a UNIVERSITY OF HEIDELBERG   (Germany)

^b BAM FEDERAL INSTITUTE FOR MATERIALS RESEARCH AND TESTING   (Germany)

Author keywords

C C cleavage; Dehydrogenation; Electric field strength; Emitter potential; Emitter temperature; Field desorption; Field ionization; Metastable ion; Oligomer; Polyethylene

Indexed keywords

EID: 0034413662     PISSN: 14690667     EISSN: None     Source Type: Journal    
DOI: 10.1255/ejms.300     Document Type: Article

References (39)

1. H.D. Beckey and H.-R. Schulten, Angew. Chem. 87, 425 (1975).
2. H.D. Beckey, Principles of Field Ionization and Field Desorption Mass Spectrometry. Pergamon, Oxford (1977).
3. R.P. Lattimer and H.-R. Schulten, Anal. Chem. 61, 1201A (1989).
4. L. Prokai, Field Desorption Mass Spectrometry. Marcel Decker, New York (1990).
5. H.D. Beckey, Z. Naturforschg. 17a, 1103 (1962).
6. H.D. Beckey and P. Schulze, Z. Naturforschg. 20a, 1329 (1965).
7. H.D. Beckey and P. Schulze, Z. Naturforschg. 20a, 1335 (1965).
8. K.G. Hippe and H.D. Beckey, Erdöl & Kohle 24, 620 (1971).
9. D. Severin, H. Henning and G. Bergmann, Erdöl & Kohle 25, 514 (1972).
10. D. Severin, Erdöl & Kohle 29, 13 (1976).
11. S. Pfeifer, H.D. Beckey and H.-R. Schulten, Z. Anal. Chem. 284, 193 (1977).
12. S.E. Scheppele, C.S. Hsu, T.D. Marriott, P.A. Benson, K.N. Detwiler and N.B. Perreira, Int. J. Mass Spectrom. Ion Phys. 28, 335 (1978).
13. T. Matsuo, H. Matsuda and I. Katakuse, Anal. Chem. 51, 1329 (1979).
14. G.M. Neumann, P.G. Cullis and P.J. Derrick, Z. Naturforsch. 35a, 1090 (1980).
15. K. Rollins, J.H. Scrivens, M.J. Taylor and H. Major, Rapid. Commun. Mass Spectrom. 4, 335 (1990).
16. A.T. Jackson, R.C.K. Jennings, J.H. Scrivens, M.R. Green and R.H. Bateman, Rapid. Commun. Mass Spectrom. 12, 1914 (1998).
17. R.H. Carr and A.T. Jackson, Rapid. Commun. Mass Spectrom. 12, 2047 (1998).
18. W.L. Mead, Anal. Chem. 40, 743 (1968).
19. R.P. Lattimer and H.-R. Schulten, Int. J. Mass Spectrom. Ion Phys. 52, 105 (1983).
20. W.J. Evans, D.M. DeCoster and J. Greaves, Macromolecules 28, 7929 (1995).
21. W.J. Evans, D.M. DeCoster and J. Greaves, Organometallics 15, 3210 (1996).
22. W.J. Evans, D.M. DeCoster and J. Greaves, J. Am. Soc. Mass Spectrom. 7, 1070 (1996).
23. M. Karas, U. Bahr, A. Ingendoh and F. Hillenkamp, Angew. Chem. 101, 805 (1989).
24. M. Karas, U. Bahr and U. Giessmann, Mass Spectrom. Rev. 10, 335 (1991).
25. R.C. Beavis, Org. Mass Spectrom. 27, 653 (1992).
26. J.S. Cottrell, M. Koerner and R. Gerhards, Rapid. Commun. Mass Spectrom. 9, 1562 (1995).
27. P.O. Danis, D.E. Karr, F. Mayer, A. Holle and C.H. Watson, Org. Mass Spectrom. 27, 843 (1992).
28. G. Montaudo, M.S. Montaudo, C, Puglisi and F. Samperi, Rapid. Commun. Mass Spectrom. 8, 1011 (1994).
29. I.A. Mowat and R.J. Donovan, Rapid. Commun. Mass Spectrom. 9, 82 (1995).
30. S. Weidner, G. Kühn and U. Just, Rapid. Commun. Mass Spectrom. 9, 697 (1995).
31. G. Kühn, S. Weidner, U. Just and S. Hohner, J. Chromatogr. A 732, 111 (1996).
32. S. Weidner, G. Kühn and J. Friedrich, Rapid. Commun. Mass Spectrom. 12, 1366 (1998).
33. The term "emitter potential" is used to describe the difference between the voltage that applied to the emitter and to the counter electrode.
34. F.W. Röllgen and H.D. Beckey, Z. Naturforsch. A 29, 230 (1974).
35. C.E. Heine and M.M. Geddes, Org. Mass Spectrom. 29, 277 (1994).
36. G. Klesper and F.W. Röllgen, J. Mass Spectrom. 31, 383 (1996).
37. C.E. McCrae and P.J. Derrick, Org. Mass Spectrom. 18, 321 (1983).
38. D. Kümmler and H.-R. Schulten, Org. Mass Spectrom. 10, 813 (1975).
39. H.U. Winkler and B. Linden, Org. Mass Spectrom. 11, 327 (1976).