Metalation as a termination step in polymerization reactions involving α-olefins and ethylene as detected by field desorption mass spectrometry

Organometallics

Volumn 15, Issue 14, 1996, Pages 3210-3221

  Evans, William J ^a   DeCoster, Donna M ^a   Greaves, John ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001364438     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960298v     Document Type: Article

References (44)

1. Brintzinger, H. H.; Fischer, D.; Mülhapt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143-1170 and references therein.
2. Ballard, D. G. H.; Courtis, A.; Holton, J.; McMeeking, J.; Pearce, R. J. Chem. Soc., Chem. Commun. 1978, 994-995.
3. Evans, W. J.; Bloom, I.; Hunter, W. E.; Atwood, J. L. J. Am. Chem. Soc. 1981, 103, 6507-6508.
4. Watson, P. L.; Herskovitz, T. ACS Symp. Ser. 1983, No. 212, 459-479. Watson, P. L.; Parshall, G. W. Acc. Chem. Res. 1985, 18, 51-56.
5. Watson, P. L.; Herskovitz, T. ACS Symp. Ser. 1983, No. 212, 459-479. Watson, P. L.; Parshall, G. W. Acc. Chem. Res. 1985, 18, 51-56.
6. Jeske, G.; Lauke, H.; Mauermann, H.; Swepston, P. N.; Schumann, H.; Marks, T. J. J. Am. Chem. Soc. 1985, 107, 8091-8103.
7. Jeske, G.; Schock, L. E.; Swepston, P. N.; Schumann, H.; Marks, T. J. J. Am. Chem. Soc. 1985, 107, 8103-8110.
8. Mauermann, H.; Swepston, P. N.; Marks, T. J. Organometallics 1985, 4, 200-202.
9. Evans, W. J.; Chamberlain, L. R.; Ziller, J. W. J. Am. Chem. Soc. 1987, 109, 7209-7211.
10. Shen, Z.; Ouyang, J. In Handbook on the Physics and Chemistry of Rare Earths; Gschneidner, K. A., Jr., Eyring, L., Eds.; Elsevier Science: Amsterdam, 1987; Vol. 9, Chapter 61.
11. Evans, W. J.; Chamberlain, L. R.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1988, 110, 6423-6432.
12. Yamamoto, H.; Yasuda, H.; Yokota, K.; Nakamura, A.; Kai, Y.; Kasai, H. Chem. Lett. 1988, 1963-1966.
13. Evans, W. J.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1990, 112, 2314-2324.
14. Stern, D.; Sabat, M.; Marks, T. J. J. Am. Chem. Soc. 1990, 112, 9558-9575.
15. Olonde, X.; Mortreux, A.; Petit, F.; Bujadoux, K. Presented at the International Conference Rare Earths '92 in Kyoto, Japan, June 1992; paper PIK-16.
16. Furo, M.; Kibino, N.; Yasuda, H. Presented at the International Conference Rare Earths '92 in Kyoto, Japan, June 1992; Paper PIK-6.
17. Yasuda, H.; Tamai, H. Prog. Polym. Sci. 1993, 18, 1097-1139.
18. Pettijohn, T. M.; Hsieh, H. L. Abstracts of Papers, MetCon; Catalyst Consultants Inc.: Houston, TX, 1993; pp 97-109.
19. Yang, X.; Seyam, A. M.; Fu, P.-F.; Marks, T. J. Macromolecules 1994, 27, 4625-4626.
20. Evans, W. J.; DeCoster, D. M.; Greaves, J. Macromolecules 1995, 28, 7929-7936.
21. Pelletier, J. F.; Chenal, T.; Mortreux, A.; Olonde, X.; Bujadoux, K. Abstracts of Papers, Metallocenes Conference; Brussels, 1995; 361-373.
22. For examples of yttrium- and scandium-catalyzed systems see the following: Coughlin, E. B.; Bercaw, J. E. J. Am. Chem. Soc. 1992, 114, 7606-7607. Schaverien, C. J. Organometallics 1994, 13, 69-82. Parkin, G.; Bunel, E.; Burger, B. J.; Trimmer, M. S.; Van Asselt, A.; Bercaw, J. E. J. Mol. Catal. 1987, 41, 21-39. Shapiro, P. J.; Bunel, E.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1990, 9, 867-869. Burger, B. J.; Thompson, M. E.; Cotter, W. D.; Bercaw, J. E. J. Am. Chem. Soc. 1990, 112, 1566-1577.
23. For examples of yttrium- and scandium-catalyzed systems see the following: Coughlin, E. B.; Bercaw, J. E. J. Am. Chem. Soc. 1992, 114, 7606-7607. Schaverien, C. J. Organometallics 1994, 13, 69-82. Parkin, G.; Bunel, E.; Burger, B. J.; Trimmer, M. S.; Van Asselt, A.; Bercaw, J. E. J. Mol. Catal. 1987, 41, 21-39. Shapiro, P. J.; Bunel, E.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1990, 9, 867-869. Burger, B. J.; Thompson, M. E.; Cotter, W. D.; Bercaw, J. E. J. Am. Chem. Soc. 1990, 112, 1566-1577.
24. For examples of yttrium- and scandium-catalyzed systems see the following: Coughlin, E. B.; Bercaw, J. E. J. Am. Chem. Soc. 1992, 114, 7606-7607. Schaverien, C. J. Organometallics 1994, 13, 69-82. Parkin, G.; Bunel, E.; Burger, B. J.; Trimmer, M. S.; Van Asselt, A.; Bercaw, J. E. J. Mol. Catal. 1987, 41, 21-39. Shapiro, P. J.; Bunel, E.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1990, 9, 867-869. Burger, B. J.; Thompson, M. E.; Cotter, W. D.; Bercaw, J. E. J. Am. Chem. Soc. 1990, 112, 1566-1577.
25. For examples of yttrium- and scandium-catalyzed systems see the following: Coughlin, E. B.; Bercaw, J. E. J. Am. Chem. Soc. 1992, 114, 7606-7607. Schaverien, C. J. Organometallics 1994, 13, 69-82. Parkin, G.; Bunel, E.; Burger, B. J.; Trimmer, M. S.; Van Asselt, A.; Bercaw, J. E. J. Mol. Catal. 1987, 41, 21-39. Shapiro, P. J.; Bunel, E.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1990, 9, 867-869. Burger, B. J.; Thompson, M. E.; Cotter, W. D.; Bercaw, J. E. J. Am. Chem. Soc. 1990, 112, 1566-1577.
26. For examples of yttrium- and scandium-catalyzed systems see the following: Coughlin, E. B.; Bercaw, J. E. J. Am. Chem. Soc. 1992, 114, 7606-7607. Schaverien, C. J. Organometallics 1994, 13, 69-82. Parkin, G.; Bunel, E.; Burger, B. J.; Trimmer, M. S.; Van Asselt, A.; Bercaw, J. E. J. Mol. Catal. 1987, 41, 21-39. Shapiro, P. J.; Bunel, E.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1990, 9, 867-869. Burger, B. J.; Thompson, M. E.; Cotter, W. D.; Bercaw, J. E. J. Am. Chem. Soc. 1990, 112, 1566-1577.
27. Watson, P. L. J. Am. Chem. Soc. 1982, 104, 337-339. Schaverien, C. J. J. Chem. Soc., Chem. Commun. 1992, 11-13.
28. Watson, P. L. J. Am. Chem. Soc. 1982, 104, 337-339. Schaverien, C. J. J. Chem. Soc., Chem. Commun. 1992, 11-13.
29. Sinn, H.; Kaminsky, W.; Vollmer, H. J.; Woldt, R. Angew. Chem., Int. Ed. Engl. 1980, 19, 390-392. Sinn H.; Kaminsky, W. Adv. Organomet. Chem. 1980, 189, 137-149. Horton, A. D. TRIP 1994, 2, 158-166.
30. Sinn, H.; Kaminsky, W.; Vollmer, H. J.; Woldt, R. Angew. Chem., Int. Ed. Engl. 1980, 19, 390-392. Sinn H.; Kaminsky, W. Adv. Organomet. Chem. 1980, 189, 137-149. Horton, A. D. TRIP 1994, 2, 158-166.
31. Sinn, H.; Kaminsky, W.; Vollmer, H. J.; Woldt, R. Angew. Chem., Int. Ed. Engl. 1980, 19, 390-392. Sinn H.; Kaminsky, W. Adv. Organomet. Chem. 1980, 189, 137-149. Horton, A. D. TRIP 1994, 2, 158-166.
32. For recent extensive literature references, see: Giardello, M. A.; Eisen, M. S.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1995, 117, 12114-12129.
33. Evans, W. J.; Hughes, L. A.; Hanusa, T. P. J. Am. Chem. Soc. 1984, 106, 4270-4272. Evans, W. J.; Hughes, L. A.; Hanusa, T. P. Organometallics 1986, 5, 1285-1291.
34. Evans, W. J.; Hughes, L. A.; Hanusa, T. P. J. Am. Chem. Soc. 1984, 106, 4270-4272. Evans, W. J.; Hughes, L. A.; Hanusa, T. P. Organometallics 1986, 5, 1285-1291.
35. Evans, W. J.; Bloom, I.; Hunter, W. E.; Atwood, J. L. J. Am. Chem. Soc. 1981, 105, 1401-1403.
36. Evans, W. J.; Ulibarri, T. A.; Ziller, J. W. Organometallics 1991, 10, 134-142.
37. Yasuda, H.; Furo, H.; Yamamoto, H.; Nakamura, A.; Miayke, S.; Kibino, N. Macromolecules 1992, 25, 5115-5116. Boffa, L. S.; Novak, B. M. Macromolecules 1994, 27, 6993-6995.
38. Yasuda, H.; Furo, H.; Yamamoto, H.; Nakamura, A.; Miayke, S.; Kibino, N. Macromolecules 1992, 25, 5115-5116. Boffa, L. S.; Novak, B. M. Macromolecules 1994, 27, 6993-6995.
39. Brown, T. L.; Dickerhoof, D. W.; Bafus, D. A.; Morgan, G. L. Rev. Sci. Instr. 1962, 33, 491-492.
40. Evans W. J.; Grate, J. W.; Bloom, I.; Hunter, W. E.; Atwood, J. L. J. Am. Chem. Soc. 1985, 107, 405-409.
41. Evans, W. J.; DeCoster, D. M.; Greaves, J. Submitted for publication in J. Am. Soc. Mass Spectrom.
42. Heine, C. E.; Geddes, M. M. Organic Mass Spectrom. 1994, 29, 277-282.
43. For example see ref 7, p 8110.
44. The mole fraction solubility of ethylene is 0.0153 and the mole fraction solubility of hydrogen is 0.000 317 in toluene at 298.2 K and 1.013 bar: Fogg, P. G. T.; Gerrand, W. In Solubility of Gases in Liquids; John Wiley and Sons: New York, 1991; pp 133-138, 300-312.