Three-, four-, and five-coordinate cyclic phosphites, phosphonates, and phosphonium salts containing sulfuryl groups

Phosphorus, Sulfur and Silicon and Related Elements

Volumn 160, Issue , 2000, Pages 1-27

  Chandrasekaran, A ^a   Day, Roberta O ^a   Sood, Paul ^a   Timosheva, Natalya V ^a   Sherlock, David J ^a   Holmes, Robert R ^a  

^a UNIVERSITY OF MASSACHUSETTS   (United States)

Author keywords

Crystal structures; Cyclic phosphites; Oxygen donor atom coordination; Phosphonium bromide; Sulfuryl groups

Indexed keywords

EID: 0034361457     PISSN: 10426507     EISSN: None     Source Type: Journal    
DOI: 10.1080/10426500008043667     Document Type: Article

References (37)

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5. (b) Sood, P.; Chandrasekaran, A.; Day, R.O.; Holmes, R.R. Inorg. Chem. 1998, 37, 6329.
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9. Sood, P.; Chandrasekaran, A.; Day, R.O.; Holmes, R.R. Inorg. Chem. 1998, 37, 3747.
10. Holmes, R.R. Phosphorus, Sulfur, and Silicon 1999, 144-146, 1.
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23. Prakasha, T.K.; Day, R.O.; Holmes, R.R. Inorg. Chem. 1992, 31, 3391.
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26. Kolodiazhnyi, O.I.; Golovatyi, O.R. Phosphorus, Sulfur, and Silicon 1995, 102, 133.
27. (a) Riddick, J.A.; Bunger, W.B. Organic Solvents: Physical Properties and Methods of Purification, 3rd ed.; Techniques of Chemistry Series; Wiley Interscience: New York, 1970; Vol II, Chapter V.
28. (b) Vogel, A.I. Textbook of Practical Organic Chemistry. Longman: London, 1978.
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32. McArdle, P. ORTEX 5e; Crystallography Centre. Chemistry Department, University College, Galway, Ireland, 1996.
33. See reference 17. In this method, the displacement of the phosphorus atom from the mean plane of the four basal ligands is calculated. This distance is 0.43Å for a regular square pyramid for main group elements based on trans basal angles of 150°. See Holmes, R.R.; Deiters, J.A. J. Am. Chem. Soc. 1977, 99, 3318.
34. Bondi, A. J. Phys. Chem. 1964, 68, 441.
35. Huheey, J.E.; Keiter, E.A.; Keiter, R.L. Inorganic Chemistry, 4th ed.; Harper Collins College Publishers, 1993, Appendix E, Table E-1.
36. 30 toward the sum of the covalent radii (1.83Å). See Tables, of Interatomic Distances and Configuration in Molecules and Ions; Sutton, L., Ed.; Special Publication Nos. 11 and 18: The Chemical Society: London, 1958 and 1965.
37. Harper, S.D.; Arduengo, A.J. J. Am. Chem. Soc: 1982, 104, 2497.