Solid and solution state structures of a reversible molecular oxygen-carrying molybdenum porphyrin dioxygen complex

Chemistry Letters

Volumn , Issue 2, 2000, Pages 102-103

  Fujihara, Tetsuaki ^a   Rees, Nicholas H ^b,c   Umakoshi, Keisuke ^a,d   Tachibana, Junichi ^a   Sasaki, Yoichi ^a   McFarlane, William ^b   Imamura, Taira ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

^b NEWCASTLE UNIVERSITY   (United Kingdom)

^c UNIVERSITY OF OXFORD   (United Kingdom)

^d NAGASAKI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0034354689     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2000.102     Document Type: Article

References (23)

1. M. Momenteau and C. A. Reed, Chem. Rev., 94, 659 (1994); N. Kitajima and Y. Moro-oka, Chem. Rev., 94, 737 (1994); A. L. Leig and S. J. Lippard, Chem. Rev., 94, 759 (1994); J. P. Collman, P. S. Wagenknecht, and J. K. Hutchison, Angew. Chem. Int. Ed. Engl., 33, 1537 (1994).
2. M. Momenteau and C. A. Reed, Chem. Rev., 94, 659 (1994); N. Kitajima and Y. Moro-oka, Chem. Rev., 94, 737 (1994); A. L. Leig and S. J. Lippard, Chem. Rev., 94, 759 (1994); J. P. Collman, P. S. Wagenknecht, and J. K. Hutchison, Angew. Chem. Int. Ed. Engl., 33, 1537 (1994).
3. M. Momenteau and C. A. Reed, Chem. Rev., 94, 659 (1994); N. Kitajima and Y. Moro-oka, Chem. Rev., 94, 737 (1994); A. L. Leig and S. J. Lippard, Chem. Rev., 94, 759 (1994); J. P. Collman, P. S. Wagenknecht, and J. K. Hutchison, Angew. Chem. Int. Ed. Engl., 33, 1537 (1994).
4. M. Momenteau and C. A. Reed, Chem. Rev., 94, 659 (1994); N. Kitajima and Y. Moro-oka, Chem. Rev., 94, 737 (1994); A. L. Leig and S. J. Lippard, Chem. Rev., 94, 759 (1994); J. P. Collman, P. S. Wagenknecht, and J. K. Hutchison, Angew. Chem. Int. Ed. Engl., 33, 1537 (1994).
5. L. D. Brown and K. N. Raymond, J. Chem. Soc., Chem. Commun., 1974, 470; J. P. Collman, R. R. Gagne, C. A. Reed, T. R. Halbert, G. Lang, and W. T. Robinson, J. Am. Chem. Soc., 97, 1427 (1975); R. R. Jacobson, Z. Tyeklar, A. Farooq, K. D. Karlin, S. Liu, and J. Zubieta, J. Am. Chem. Soc., 110, 3690 (1988); T. Ookubo, H. Sugimoto, T. Nagayama, H. Masuda, T. Sato, K. Tanaka, Y. Maeda, H. Okawa, Y. Hayashi, A. Uehara, and M. Suzuki, J. Am. Chem. Soc., 118, 701 (1996).
6. L. D. Brown and K. N. Raymond, J. Chem. Soc., Chem. Commun., 1974, 470; J. P. Collman, R. R. Gagne, C. A. Reed, T. R. Halbert, G. Lang, and W. T. Robinson, J. Am. Chem. Soc., 97, 1427 (1975); R. R. Jacobson, Z. Tyeklar, A. Farooq, K. D. Karlin, S. Liu, and J. Zubieta, J. Am. Chem. Soc., 110, 3690 (1988); T. Ookubo, H. Sugimoto, T. Nagayama, H. Masuda, T. Sato, K. Tanaka, Y. Maeda, H. Okawa, Y. Hayashi, A. Uehara, and M. Suzuki, J. Am. Chem. Soc., 118, 701 (1996).
7. L. D. Brown and K. N. Raymond, J. Chem. Soc., Chem. Commun., 1974, 470; J. P. Collman, R. R. Gagne, C. A. Reed, T. R. Halbert, G. Lang, and W. T. Robinson, J. Am. Chem. Soc., 97, 1427 (1975); R. R. Jacobson, Z. Tyeklar, A. Farooq, K. D. Karlin, S. Liu, and J. Zubieta, J. Am. Chem. Soc., 110, 3690 (1988); T. Ookubo, H. Sugimoto, T. Nagayama, H. Masuda, T. Sato, K. Tanaka, Y. Maeda, H. Okawa, Y. Hayashi, A. Uehara, and M. Suzuki, J. Am. Chem. Soc., 118, 701 (1996).
8. L. D. Brown and K. N. Raymond, J. Chem. Soc., Chem. Commun., 1974, 470; J. P. Collman, R. R. Gagne, C. A. Reed, T. R. Halbert, G. Lang, and W. T. Robinson, J. Am. Chem. Soc., 97, 1427 (1975); R. R. Jacobson, Z. Tyeklar, A. Farooq, K. D. Karlin, S. Liu, and J. Zubieta, J. Am. Chem. Soc., 110, 3690 (1988); T. Ookubo, H. Sugimoto, T. Nagayama, H. Masuda, T. Sato, K. Tanaka, Y. Maeda, H. Okawa, Y. Hayashi, A. Uehara, and M. Suzuki, J. Am. Chem. Soc., 118, 701 (1996).
9. J. Tachibana, T. Imamura, and Y. Sasaki, J. Chem. Soc., Chem. Commun., 1993, 1436; J. Tachibana, T. Imumura, and Y. Sasaki, Bull. Chem. Soc. Jpn., 71, 363 (1998).
10. J. Tachibana, T. Imamura, and Y. Sasaki, J. Chem. Soc., Chem. Commun., 1993, 1436; J. Tachibana, T. Imumura, and Y. Sasaki, Bull. Chem. Soc. Jpn., 71, 363 (1998).
11. Abbreviations; tmp = 5,10,15,20-tetramesitylporphyrinato dianion, tpp = 5,10,15,20-tetraphenylporphyrinato dianion, ttp = 5,10,15,20-tetra(p-tolyl)porphyrinato dianion.
12. M. Osada, J. Tachibana, T. Imamura, and Y. Sasaki, Chem. Lett., 1996, 713; K. Hoshiba, N. Nishimura, K. Shimazu, T. Imamura, and Y. Sasaki, Chem. Lett. 1997, 853.
13. M. Osada, J. Tachibana, T. Imamura, and Y. Sasaki, Chem. Lett., 1996, 713; K. Hoshiba, N. Nishimura, K. Shimazu, T. Imamura, and Y. Sasaki, Chem. Lett. 1997, 853.
14. Crystallographic data have been deposited at the CCDC, UK. The deposition number is CSD 410412. NMR data were deposited at the office of the Editor of Chemistry Letters.
15. w = 7.1. 12132 measured reflections, 9577 independent reflections, 6814 observed reflection [I>2.0σ(I)]. The crystal structure was solved by a standard direct method (SIR92). The hydrogen atoms except for the methyl hydrogens of mesityl groups were included at calculated positions with fixed displacement parameters (1.2 times the displacement parameters of the host atom).
16. Oxo and peroxo groups showed 0.24:0.76 disorder. Figure 1 illustrates the structure having high occupancy.
17. C-H. Yang, S. J. Dzugan, and V. L. Goedken, J. Chem. Soc., Chem. Commun., 1985, 1425.
18. 9 The complex does not show reversible dioxygenation behavior and decomposes irreversibly on photoirradiation.
19. B. F. Mentzen, M. C. Bonnet, and H. J. Ledon, Inorg. Chem., 19, 2061 (1980).
20. M. H. Dickman and M. T. Pope, Chem. Rev., 94, 569 (1994).
21. A. A. Bothner-by, R. L. Stephens, J. Lee, C. D. Warren, and R. W. Jeanloz, J. Am. Chem. Soc., 106, 811 (1984).
22. G. Bodenhousen and D. J. Ruben, Chem. Phys. Lett., 69, 185 (1980).
23. A. Box and M. F. Summer, J. Am. Chem. Soc., 108, 2093 (1986).