메뉴 건너뛰기




Volumn 104, Issue 46, 2000, Pages 10595-10599

Direct observation of non-RRKM behavior in femtosecond photophysically activated reactions

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; MOLECULAR STRUCTURE; MOLECULAR VIBRATIONS; PHOTODISSOCIATION; PHOTONS; ULTRAFAST PHENOMENA;

EID: 0034324485     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp003047f     Document Type: Article
Times cited : (21)

References (34)
  • 20
    • 0343153721 scopus 로고    scopus 로고
    • note
    • CO) configuration to form the adiabatic pathway leading to "CN(X) + R-CO(Ã)" products.
  • 21
    • 0342719187 scopus 로고    scopus 로고
    • note
    • CH3-C along the two dissociation coordinates. Strictly speaking, they form conical intersections, and the crossings are avoided only when the plane of symmetry is distorted. Our ab initio calculations at the UB3LYP/ 6-31G(d) level of theory indeed showed that both transition states are nonplanar.
  • 22
    • 0343153723 scopus 로고    scopus 로고
    • note
    • a is the measured time constant for the fast component, the rate constant for the D1 step can be determined.
  • 25
    • 33750614386 scopus 로고
    • Gonzalez, C.; Schlegel, H. B. J. Chem. Phys. 1989, 90, 2154; J. Phys. Chem. 1990, 94, 5523.
    • (1990) J. Phys. Chem. , vol.94 , pp. 5523
  • 27
    • 0342719188 scopus 로고    scopus 로고
    • note
    • therm was estimated by ab initio electronic structure calculations.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.