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Volumn 102, Issue 50, 1998, Pages

Prompt and delayed dissociation of energy-rich larger molecules

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EID: 11744290619     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp981912e     Document Type: Article
Times cited : (8)

References (31)
  • 3
    • 11744348249 scopus 로고
    • Butler, J. N.; Kistiakowski, G. B. J. Am. Chem. Soc. 1961, 83, 1324. Oref, I.; Scheutzle, D.; Rabinovitch, B. S. J. Chem. Phys. 1971, 54, 575. Rynbrandt, J. D.; Rabinovitch, B. S. J. Chem. Phys. 1971, 54, 2275.
    • (1961) J. Am. Chem. Soc. , vol.83 , pp. 1324
    • Butler, J.N.1    Kistiakowski, G.B.2
  • 4
    • 11744348249 scopus 로고
    • Butler, J. N.; Kistiakowski, G. B. J. Am. Chem. Soc. 1961, 83, 1324. Oref, I.; Scheutzle, D.; Rabinovitch, B. S. J. Chem. Phys. 1971, 54, 575. Rynbrandt, J. D.; Rabinovitch, B. S. J. Chem. Phys. 1971, 54, 2275.
    • (1971) J. Chem. Phys. , vol.54 , pp. 575
    • Oref, I.1    Scheutzle, D.2    Rabinovitch, B.S.3
  • 5
    • 0012472343 scopus 로고
    • Butler, J. N.; Kistiakowski, G. B. J. Am. Chem. Soc. 1961, 83, 1324. Oref, I.; Scheutzle, D.; Rabinovitch, B. S. J. Chem. Phys. 1971, 54, 575. Rynbrandt, J. D.; Rabinovitch, B. S. J. Chem. Phys. 1971, 54, 2275.
    • (1971) J. Chem. Phys. , vol.54 , pp. 2275
    • Rynbrandt, J.D.1    Rabinovitch, B.S.2
  • 10
    • 0001526294 scopus 로고
    • Crim, F. F. Science 1990, 249, 1387.
    • (1990) Science , vol.249 , pp. 1387
    • Crim, F.F.1
  • 21
    • 11744250369 scopus 로고    scopus 로고
    • note
    • The ratio is all that is needed because the sum does not really matter. The kinetic equations are linear so that if one doubles the amount of starting material the solution is unchanged except that all concentrations double.
  • 22
    • 85088001436 scopus 로고    scopus 로고
    • note
    • 2 - 4k↑ k > 0, which means, in agreement with the spirit of RRKM, that the rate k↑ is small.
  • 23
    • 85088003499 scopus 로고    scopus 로고
    • note
    • ‡ increases by unity, shows that the energy of the states of the transition state is fairly well defined and hence that the rate of their dissipation is low.
  • 28
    • 11744357542 scopus 로고    scopus 로고
    • note
    • This is because such processes represent an average over very many initial conditions such as orientations, impact parameter, rotations, etc.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.