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43
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0344088538
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note
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Complexes were isolated in yields of 20-73% and characterized by NMR and IR spectroscopy and elemental analysis. Complete experimental details are provided as Supporting Information.
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44
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33749436309
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47
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0344950579
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note
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2/hexane. Yield: 43-73%.
-
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49
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0000618477
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50
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0344950577
-
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note
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-1); 11: 344(4290 sh), 326 (8410 sh), 310 (10500 sh); 12: 320 (1350), 284 (6440 sh); 13: 500 (60 sh), 402 (1390 sh), 354 (10700), 262 (72300); 14: 422 (100 sh), 352 (2000), 292 (30600).
-
-
-
-
51
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0344950575
-
-
note
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pc (THF, V vs SCE): 11: -1.866; 12: -1.150; 13: -1.143; 14: -1.503.
-
-
-
-
53
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0344088532
-
-
note
-
+/W*), whereby Ox denotes the metal complex fragments 11-14. For the palladium complexes. ΔE > 0. However, for the rhenium and platinum complexes, ΔE < 0.
-
-
-
-
55
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0004186505
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Photoinduced Electron Transfer, Part A. Conceptual Basis
-
-
Fox, M.A.1
Chanon, M.2
-
56
-
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0344950574
-
-
note
-
The symbols α and ω refer to the metal centers bound to the terminal positions of the unsaturated alkylidyne ligands. Thus, the central metal center in 4-10 simultaneously serves as terminus for two heterodimetalla-π-systems.
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