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Volumn 121, Issue 8, 1999, Pages 1760-1761

Electronic communication between metal centers across unsaturated alkylidyne ligands [7]

Author keywords

[No Author keywords available]

Indexed keywords

4 (4 ISOCYANOETHYNYLBENZENE)BENZYLIDYNE; 4 ISOCYANOBENZYLIDYNE; UNCLASSIFIED DRUG;

EID: 0344507093     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja982324h     Document Type: Letter
Times cited : (47)

References (57)
  • 6
    • 0001894667 scopus 로고
    • Williams, A. F., Floriani, C., Merbach, A. S., Eds.; VCH Publishers: New York
    • (a) Lehn, J.-M. In Perspertives in Coordination Chemistry; Williams, A. F., Floriani, C., Merbach, A. S., Eds.; VCH Publishers: New York, 1992; p 447.
    • (1992) Perspertives in Coordination Chemistry , pp. 447
    • Lehn, J.-M.1
  • 9
    • 2542570395 scopus 로고
    • (a) Beck, W.; Niemer, B.; Wieser, M. Angew. Chem. 1993, 105, 969; Angew. Chem., Int. Ed. Engl. 1993, 33, 547.
    • (1993) Angew. Chem., Int. Ed. Engl. , vol.33 , pp. 547
  • 20
    • 0001057344 scopus 로고
    • (a) Fischer, E. O. Angew. Chem. 1974, 86, 651; Fischer, E. O. Adv. Organomet. Chem. 1976, 14, 1.
    • (1974) Angew. Chem. , vol.86 , pp. 651
    • Fischer, E.O.1
  • 43
    • 0344088538 scopus 로고    scopus 로고
    • note
    • Complexes were isolated in yields of 20-73% and characterized by NMR and IR spectroscopy and elemental analysis. Complete experimental details are provided as Supporting Information.
  • 47
    • 0344950579 scopus 로고    scopus 로고
    • note
    • 2/hexane. Yield: 43-73%.
  • 50
    • 0344950577 scopus 로고    scopus 로고
    • note
    • -1); 11: 344(4290 sh), 326 (8410 sh), 310 (10500 sh); 12: 320 (1350), 284 (6440 sh); 13: 500 (60 sh), 402 (1390 sh), 354 (10700), 262 (72300); 14: 422 (100 sh), 352 (2000), 292 (30600).
  • 51
    • 0344950575 scopus 로고    scopus 로고
    • note
    • pc (THF, V vs SCE): 11: -1.866; 12: -1.150; 13: -1.143; 14: -1.503.
  • 53
    • 0344088532 scopus 로고    scopus 로고
    • note
    • +/W*), whereby Ox denotes the metal complex fragments 11-14. For the palladium complexes. ΔE > 0. However, for the rhenium and platinum complexes, ΔE < 0.
  • 56
    • 0344950574 scopus 로고    scopus 로고
    • note
    • The symbols α and ω refer to the metal centers bound to the terminal positions of the unsaturated alkylidyne ligands. Thus, the central metal center in 4-10 simultaneously serves as terminus for two heterodimetalla-π-systems.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.