Photodissociation of CF2=CFCl at 193 nm by translational spectroscopy

Journal of Chemical Physics

Volumn 113, Issue 15, 2000, Pages 6107-6112

  Lee, Y R ^a,b   Wang, L D ^a,b   Lee, Y T ^a,b   Lin, S M ^a,b  

^a INSTITUTE OF ATOMIC AND MOLECULAR SCIENCES   (Taiwan)

^b NATIONAL TAIWAN UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; COMPUTER SIMULATION; CURVE FITTING; ELECTRON ENERGY LEVELS; FLUORINE COMPOUNDS; LASER APPLICATIONS; MOLECULAR SPECTROSCOPY; MOLECULAR STRUCTURE; PHOTODISSOCIATION; PHOTOLYSIS; PHOTONS;

BOND DISSOCIATION ENERGY; EXCITED POTENTIAL ENERGY SURFACE; FLUOROCARBENE;

MOLECULAR DYNAMICS;

EID: 0034294304     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1308558     Document Type: Article

References (30)

1. T. K. Minton, P. Felder, R. C. Scales, and J. R. Huber, Chem. Phys. Lett. 164, 113 (1989).
2. C. A. Longfellow, L. A. Smoliar, Y. T. Lee, Y. R. Lee, C. Y. Yeh, and S. M. Lin, Chem. Phys. Lett. 271, 33 (1997).
3. C. A. Longfellow, L. A. Smoliar, Y. T. Lee, Y. R. Lee, C. Y. Yeh, and S. M. Lin, J. Phys. Chem. A 101, 338 (1997).
4. M. Umemoto, K. Seki, H. Shinohara, U. Nagashima, N. Nishi, M. Kinoshita, and R. Shimada, J. Chem. Phys. 83, 1657 (1985).
5. Y. Huang, Y. Yang, G. He, S. Hashimoto, and R. J. Gordon, J. Chem. Phys. 103, 5476 (1995).
6. D. A. Blank, W. Sun, A. G. Suits, Y. T. Lee, S. W. North, and G. E. Hall, J. Chem. Phys. 108, 5414 (1998), and references therein.
7. B. A. Balko, J. Zhang, and Y. T. Lee, J. Phys. Chem. A 101, 6611 (1997).
8. J. J. Lin, T. C. Hsu, D. W. Hwang, Y. T. Lee, and X. Yang, J. Chem. Phys. 109, 10719 (1998).
9. J. J. Lin, S. M. Wu, D. W. Hwang, Y. T. Lee, and X. Yang, J. Chem. Phys. 109, 10838 (1998).
10. J. D. Scott and B. R. Russell, J. Am. Chem. Soc. 94, 2634 (1972).
11. J. C. Stephenson and D. S. King, J. Chem. Phys. 72, 1161 (1980).
12. G. R. Long, L. D. Prentice, and S. E. Bialkowski, Appl. Phys. B: Photophys. Laser Chem. 34, 97 (1984).
13. M. Rossberg, J. Wolbrandt, W. Strube, and E. Linke, J. Mol. Struct. 348, 421 (1995).
14. A. M. Wodtke and Y. T. Lee, J. Phys. Chem. 89, 4744 (1985).
15. Y. R. Lee, C. L. Chiu, and S. M. Lin, J. Chem. Phys. 100, 7376 (1994).
16. R. K. Sparks, K. Shobatake, L. R. Carlson, and Y. T. Lee, J. Chem. Phys. 75, 3838 (1981).
17. D. Krajnovich, Z. Zhang, L. Butler, and Y. T. Lee, J. Phys. Chem. 88, 4561 (1984).
18. E. J. Hintsa, X. Zhao, W. M. Jackson, W. B. Miller, A. M. Wodtke, and Y. T. Lee, J. Phys. Chem. 95, 2799 (1991).
19. R. N. Zare, Mol. Photochem. 4, 1 (1972).
20. D. Krajnovich, F. Huisken, Z. Zhang, Y. R. Shen, and Y. T. Lee, J. Chem. Phys. 77, 5977 (1982).
21. L. J. Butler, E. J. Hintsa, S. F. Shane, and Y. T. Lee, J. Chem. Phys. 86, 2051 (1987).
22. S. G. Lias, J. E. Bartmess, J. F. Liebman, J. L. Holmes, R. D. Levine, and W. G. Mallard, J. Phys. Chem. Ref. Data 17, Suppl. 1 (1988).
23. M. R. Zachariah, P. R. Westmoreland, D. R. Burgess, Jr., W. Tsang, and C. F. Melius, J. Phys. Chem. 100, 8737 (1996).
24. If we assumed no vibrational relaxation in the nozzle beam expansion, an internal energy of 8.5 kcal/mol was calculated for the reactant at 190 °C. The vibrational frequencies were taken from D. E. Mann, N. Acquista, and R. K. Plyler, J. Chem. Phys. 21, 1949 (1953).
25. R. Atkinson, D. L. Baulch, R. A. Cox, R. E. Hampson, Jr., A. Kerr, M. J. Rossi, and J. Troe, J. Phys. Chem. Ref. Data 26, 521 (1997).
26. E. A. Carter and W. A. Goddard III, J. Phys. Chem. 90, 998 (1986).
27. S. Koda, Chem. Phys. Lett. 55, 353 (1978).
28. D. S. King, P. K. Schenck, and J. C. Stephenson, J. Mol. Spectrosc. 78, 1 (1979).
29. S. Yang and R. Bersohn, J. Chem. Phys. 61, 4400 (1974).
30. M. B. Robin, Higher Excited States of Polyatomic Molecules (Academic, New York, 1975), Vol. 2.