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At room temperature the vinyl chloride reactant will contain 1 to 2 kcal/ mol of internal energy on average and will experience substantial cooling of the internal degrees of freedom following supersonic expansion.
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note
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2+HClCC were taken from estimates in Ref. 14. The isomerization energy for acetylene/vinylidene and the singlet/triplet splitting for vinylidene were taken from Ref. 35. The singlet/triplet splitting for chlorovinyldene was assumed to be the same as the singlet/triplet splitting in vinylidene.
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85034274615
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note
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Using ground-state equilibrium geometries and rigid fragment partitioning of the available energy.
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