Synthesis of n-butyl phenyl ether by tri-liquid-phase catalysis using poly(ethylene glycol)-600 as a catalyst. 1. Analysis of factors affecting the formation of a third liquid phase

Industrial and Engineering Chemistry Research

Volumn 39, Issue 8, 2000, Pages 2772-2778

  Hsiao, Hsu Chin ^a   Kao, Shue Ming ^a   Weng, Hung Shan ^a  

^a NATIONAL CHENG KUNG UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYSTS; COMPOSITION EFFECTS; MOLECULAR WEIGHT; ORGANIC SOLVENTS; PHASE COMPOSITION; POLYETHYLENE GLYCOLS; SALTS; SODIUM COMPOUNDS; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL); THERMAL EFFECTS;

BUTYL PHENYL ETHER; MOLE FRACTIONS; NUCLEOPHILIC SUBSTITUTION REACTION; PHASE TRANSFER CATALYST; SODIUM PHENOLATE; TRI-LIQUID PHASE CATALYSIS;

ETHERS;

ACETIC ACID DERIVATIVE; BROMINE DERIVATIVE; DIPHENYL ETHER; MACROGOL; ORGANIC SOLVENT; PHENOL DERIVATIVE; POTASSIUM BROMIDE; SODIUM BROMIDE; SODIUM CARBONATE; SODIUM HYDROXIDE; SODIUM IODIDE;

ARTICLE; CATALYSIS; LIQUID; MOLECULAR WEIGHT; REACTION ANALYSIS; SYNTHESIS; TEMPERATURE;

EID: 0034254118     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie990824t     Document Type: Article

References (17)

1. Correia, J. A Triphasic Brominating/Oxidizing System. J. Org. Chem. 1992, 57, 4555-4557.
2. Hsiao, H. C.; Weng, H. S. Synthesis of 2-Phenoxyisobutyric Acid Ethyl Ester by Tri-Liquid-Phase Phase Transfer Catalysis. 1. Analysis of Factors Affecting on the Formation of a Third Liquid Phase. Ind. Eng. Chem. Res. 1999, 38, 2911-2918.
3. Ido, T.; Yamamoto, T.; Jin, G.; Goto, S. Third-phase Catalytic Activity of Halogen Exchange reactions in Phase Transfer Catalytic System. Chem. Eng. Sci. 1997, 52, 3511-3520.
4. Ido, T.; Saiki, M.; Goto, S. Repeated use of polyethylene glycol) as phase-transfer catalyst. Kagaku Kogaku Ronbunshu 1989, 15 (2), 403-410.
5. Jin, G. J.; Ido, T.; Goto, S. Relation between Third-Phase properties and Rate of Dehydrohalogenation of 2-Bromoocation in Phase Transfer Catalytic System. J. Chem. Eng. Jpn. 1998, 31, 741-748.
6. Mason, D.; Magdasi, S.; Sasson, Y. Role of a Third Phase in Phase-Transfer Catalysis. J. Org. Chem. 1991, 56, 7229-7232.
7. Neumann, R.; Sasson, Y. Mechanism of Base-Catalyzed Reactions in Phase-Transfer Systems with Poly(ethylene glycols) as Catalysts. The Isomerization of Allylanisol. J. Org. Chem. 1984, 49, 3448-3451.
8. Nouguier, R.; Mchich, M. Alkylation of Pentaerythritol by Phase-Transfer Catalysis. 2. Crucial Effect of the Aqueous Sodium Hydroxide Solution. Tetrahedron 1988, 44, 2477-2481.
9. Starks, C. M.; Liotta, C.; Halpern, M. Phase-Transfer Catalysis, Fundamentals, Applications and Industrial Perspectives; Chapman & Hall: New York, 1994.
10. Yadav, G. D.; Reddy, C. A. Kinetics of the n-Butoxylation of p-Chloronitrobenzene under Liquid-Liquid-Liquid-Phase Transfer Catalysis. Ind. Eng. Chem. Res. 1999, 38, 2245-2253.
11. Wang, D. H.; Weng, H. S. Preliminary Study on the Role Played by the Third Liquid Phase in Phase Transfer Catalysis. Chem. Eng. Sci. 1988, 43, 2019-2024.
12. Wang, D. H.; Weng, H. S. Phase Transfer Catalytic Reaction between n-Butyl Bromide and Sodium Phenolate-Formation of the Third Liquid Phase and Its Effects. J. Chin. Inst. Chem. Eng. 1995, 26, 147-156.
13. Wang, D. H.; Weng, H. S. Solvent and Salt Effects on the Reaction Mechanisms in the Phase Transfer Catalysis System-Reaction between n-Butyl Bromide and Sodium Phenolate. Chem. Eng. Sci. 1995, 50, 3477-3486. .
14. Wang, D. H.; Weng, H. S. Phase Transfer Reaction between n-Butyl Bromide and Sodium Phenolate-Kinetics of Bi- and TriLiquid-Phase System. J. Chin. Inst. Chem. Eng. 1996, 27, 129-139.
15. Wang, D. H.; Weng, H. S. Tri-Liquid-Phase Phase Transfer Catalysis. J. Chin. Inst. Chem. Eng. 1996, 27, 419-426.
16. Weng, H. S.; Huang, W. G. Exploratory Study for the Preparation of Benzyl Bromide from Benzyl Chloride by Two- and Three-Phase Phase Transfer Catalysis. J. Chin. Inst. Chem. Eng. 1987, 18, 109-115.
17. Weng, H. S.; Wang, C. M.; Wang, D. H. A Preliminary Study on a Continuous Flow Stirred Vessel Reactor for Tri-Liquid-Phase Phase Transfer Catalysis. Ind. Eng. Chem. Res. 1997, 36, 3613-3618.