A Preliminary Study on a Continuous Flow Stirred Vessel Reactor for Tri-Liquid-Phase Phase Transfer Catalysis

Industrial and Engineering Chemistry Research

Volumn 36, Issue 9, 1997, Pages 3613-3618

  Weng, Hung Shan ^a   Wang, Chu Ming ^a   Wang, Der Her ^a  

^a NATIONAL CHENG KUNG UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIUM COMPOUNDS; BROMINE COMPOUNDS; CATALYSIS; SODIUM COMPOUNDS;

BUTYL BROMIDE; CONTINUOUS FLOW STIRRED VESSEL REACTOR; SODIUM PHENOLATE; TETRABUTYL AMMONIUM BROMIDE;

CHEMICAL REACTORS;

CATALYST; STIRRED TANK;

EID: 0031229145     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie960561s     Document Type: Article

References (12)

1. Correia, J. A triphasic brominating/oxidizing system. J. Org. Chem. 1992, 57, 4555-4557.
2. Dehmlow, E. V.; Dehmlow, S. S. Phase Transfer Catalysis, 3rd ed.; VCH Publishers: New York, 1993.
3. Ido, T., Saiki, M.; Goto, S. Repeated use of polyethylene glycol as phase transfer catalyst. Kagaku Kogaku Ronbunshu 1989, 15 (2), 403-410.
4. Mason, D.; Magdassi, S.; Sasson, Y. Role of a third liquid phase in phase-transfer catalysis J. Org. Chem. 1991, 56, 7229-7232.
5. Neumann, R.; Sasson, Y. Mechanism of base catalyzed reactions in phase-transfer systems with poly(ethylene glycols) as catalysts. The isomerization of Allylanisloe. J. Org. Chem. 1984, 49, 3448-3451.
6. Nouguier, R.; Mchich, M. Alkylation of pentaerythritol by phase transfer catalysis. 2. Crucial effect of the aqueous sodium hydroxide solution. Tetrahedron 1988, 44, 2477-2481.
7. Starks, C. M., Liotta, C. L.; Halpern, M. Phase Transfer Catalysis, Fundamentals, Applications and Industrial Perspectives; Chapman & Hall: New York, 1994; pp 10, 252-258.
8. Wang, D. H.; Weng, H. S. Preliminary study on the role played by the third liquid phase in phase transfer catalysis. Chem. Eng. Sci. 1988, 43, 2019-2024.
9. Wang, D. H.; Weng, H. S. Phase transfer catalytic reaction between n-butyl bromide and sodium phenolateformation of the third liquid phase and its effect. J. Chin. Inst. Chem. Eng. 1995a, 26, 147-156.
10. Wang, D. H.; Weng, H. S. Solvent and salt effects on the formation of third liquid phase and the reaction mechanisms in the phase transfer catalysis system reaction between n-butyl bromide and sodium phenolate. Chem. Eng. Sci. 1995b, 50, 3477-3486.
11. Wang, D. H.; Weng, H. S. Phase transfer catalytic reaction between n-butyl bromide and sodium phenolate kinetics of bi-and tri-liquid-phase systems. J. Chin. Inst. Chem. Eng. 1996, 27, 129-139.
12. Weng, H. S.; Huang, W. C. Exploratory study for the preparation of benzyl bromide from benzyl chloride by two-and three-phase phase transfer catalysis, J. Chin. Inst. Chem. Eng. 1987, 18, 109-115.