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Volumn 19, Issue 14, 2000, Pages 2684-2689

Palladium-catalyzed head-to-head telomerization of isoprene with amines

Author keywords

[No Author keywords available]

Indexed keywords

AMINES; CATALYST SELECTIVITY; ISOMERS; ORGANOMETALLICS; PALLADIUM; REACTION KINETICS;

EID: 0034226755     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000286g     Document Type: Article
Times cited : (54)

References (47)
  • 23
    • 0343924072 scopus 로고    scopus 로고
    • See Experimental Section for details
    • See Experimental Section for details.
  • 24
    • 0343924073 scopus 로고    scopus 로고
    • 3c,d
    • 3c,d.
  • 29
    • 0343052412 scopus 로고    scopus 로고
    • In this case, as in all others examined, raising the temperature to 60 °C gave increasing amounts of other unidentified products, without substantial change in selectivity of the telomerization reaction
    • In this case, as in all others examined, raising the temperature to 60 °C gave increasing amounts of other unidentified products, without substantial change in selectivity of the telomerization reaction.
  • 30
    • 0033570981 scopus 로고    scopus 로고
    • Note that interesting tail-to-tail selectivity has been achieved in a multicomponent diene coupling process
    • Note that interesting tail-to-tail selectivity has been achieved in a multicomponent diene coupling process: Kimura, M.; Matsuo, S.; Shibata, K.; Tamara, Y. Angew. Chem., Int. Ed. 1999, 38, 3386-3388.
    • (1999) Angew. Chem., Int. Ed. , vol.38 , pp. 3386-3388
    • Kimura, M.1    Matsuo, S.2    Shibata, K.3    Tamara, Y.4
  • 33
    • 0342618169 scopus 로고    scopus 로고
    • The ligand is now commercially available
    • (c) The ligand is now commercially available.
  • 34
    • 0342618165 scopus 로고    scopus 로고
    • 3 system is not completely homogeneous, requiring the use of the soluble cationic allylpalladium starting material for kinetics
    • 3 system is not completely homogeneous, requiring the use of the soluble cationic allylpalladium starting material for kinetics.
  • 35
    • 0343924069 scopus 로고    scopus 로고
    • note
    • 1H NMR spectroscopy. Graphs of the amount of isoprene remaining vs time provided straight lines through more than 50% completion, consistent with zero-order (saturated) kinetics, and the rates were calculated from the measured slopes of these lines.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.