Nickel(0)-catalyzed three-component connection reaction of dimethylzinc, 1,3-dienes, and carbonyl compounds

Angewandte Chemie - International Edition

Volumn 38, Issue 22, 1999, Pages 3386-3388

  Kimura, Masanari ^a   Matsuo, Shintaro ^a   Shibata, Kazufumi ^a   Tamaru, Yoshinao ^a  

^a NAGASAKI UNIVERSITY   (Japan)

Author keywords

Aldehydes; Homogeneous catalysis; Multicomponent reactions; Nickel; Zinc

Indexed keywords

ALDEHYDE; NICKEL; ZINC;

ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL REACTION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STEREOCHEMISTRY; SYNTHESIS;

EID: 0033570981     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19991115)38:22<3386::AID-ANIE3386>3.0.CO;2-W     Document Type: Article

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38. Chemical shifts were calculated with the program CS ChemNMR Pro (CambridgeSoft Corpration, Cambridge, MA).
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53. Chelation control of regioselectivity for Ni-catalyzed reactions: a) C. N. Farthing, P. Kocovsky, J. Am. Chem. Soc. 1998, 120, 6661-6662; b) M. T. Didiuk, J. P. Morken, A. H. Hoveyda, J. Am. Chem. Soc. 1995, 117, 7273-7274.
54. Under similar conditions, bis(phenylethynyl)zinc reacted only with benzaldehyde to provide 1,3-diphenyl-2-propyn-1-ol (98%).