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Volumn , Issue 6, 2000, Pages 1155-1159

Synthesis and structure of cyclotrigermenium salts of tetrakis{3,5- bis(trifluoromethyl)phenyl}borate, tetrakis(pentafluorophenyl)borate and tetrakis{4-[tert-butyl(dimethyl)silyl]-2,3,5,6-tetrafluorophenyl}borate: A stable free germyl cation in the condensed phase

Author keywords

Cations; Electron transfer; Germanium; Small ring systems

Indexed keywords

DICHLOROMETHANE; GERMANIUM; NEGATIVE IONS; ORGANIC SOLVENTS;

EID: 0034129314     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0682(200006)2000:6<1155::AID-EJIC1155>3.3.CO;2-3     Document Type: Article
Times cited : (50)

References (57)
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  • 42
    • 85153308113 scopus 로고    scopus 로고
    • note
    • 3C radical.
  • 52
    • 84947010250 scopus 로고
    • Electropositive substituents such as the silyl group prefers planar Ge=Ge double bonds to trans-bent structures. In addition, remarkable relief of the strain of three-membered rings comprising of the Group 14 elements by the electropositive substituent is predicted by theoretical calculations, see: [18a] S. Nagase, Pure Appl. Chem. 1993, 65, 675.
    • (1993) Pure Appl. Chem. , vol.65 , pp. 675
    • Nagase, S.1
  • 53
    • 0003670973 scopus 로고    scopus 로고
    • (Eds.: Z. Rappoport, Y. Apeloig), John Wiley & Sons Ltd. Chapter 3
    • [18b] A. Sekiguchi, S. Nagase, in The Chemistry of Organic Silicon Compounds, Vol. 2, Part 1, (Eds.: Z. Rappoport, Y. Apeloig), John Wiley & Sons Ltd. 1998, Chapter 3.
    • (1998) The Chemistry of Organic Silicon Compounds , vol.2 , Issue.1 PART
    • Sekiguchi, A.1    Nagase, S.2
  • 54
    • 0000056251 scopus 로고
    • 3 (Mes = 2,4,6- trimethylphenyl), which are isoelectronic with cyclotrigermenium ion, have been synthesized, see: [19a] X.-W. Li, W. T. Pennington, G. H. Robinson, J. Am. Chem. Soc. 1995, 117, 7578.
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 7578
    • Li, X.-W.1    Pennington, W.T.2    Robinson, G.H.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.