Cadmium in zinc deposits: Economic geology of a polluting element

International Geology Review

Volumn 42, Issue 5, 2000, Pages 445-469

  Schwartz, Michael O ^a  

^a FEDERAL INSTITUTE FOR GEOSCIENCES AND NATURAL RESOURCES BGR   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CADMIUM; ECONOMIC GEOLOGY; ENVIRONMENTAL GEOLOGY; MISSISSIPPI VALLEY TYPE DEPOSIT; ORE DEPOSIT; POLLUTANT; SPHALERITE; ZINC;

EID: 0034113665     PISSN: 00206814     EISSN: 19382839     Source Type: Journal    
DOI: 10.1080/00206810009465091     Document Type: Article

References (157)

1. Alfaro, G., and Collao, S., 1990. “ Massive sulfides in the greenstone belt of south-central Chile—an overview ”. In Stratabound ore deposits in the Andes, Edited by:Amstutz, G. C., Cardozo, M., Cedillo, E., and Frutos, J., 199–208. Berlin:Springer.
2. Amcoff, O., Jeppson, M., and Selkaman, S., 1985. Distribution and zoning of silver and associated elements in the complex sulfide deposit at Saxberget, central Sweden. Econ. Geol., 80:614–626.
3. Arias, D., Suárez, O., Corretgé, L. G., Fernández-Jardón, L., and Pérez-Cerdán, F., 1991. Structure, hydrothermal alteration and composition of the Rubiales Pb-Zn orebody (Lugo, Spain):Genetic model. Mineral. Deposita, 26:199–210.
4. Arribas, A., and Moro, C., 1981. Distribucion de elementos trazas en las esfaleritas y galenas de los yacimientos filonianos españoles del tipo B.G.P. C. Tecniterrae, 8 (44):10–43.
5. Badalov, S. T., and Enikeev, M. P., 1959. Geochemistry of cadmium in the Almalyk and Altyn-Topkan mineralized areas of the Karamazar region. Geochemistry, 4:406–415.
6. Barrett, T. J., Anderson, G. M., and Lugowski, J., 1988. The solubility of hydrogen sulphide in 0-5 m NaCl solutions at 25–95°C. Geochim. et Cosmochim. Acta, 52:807–811.
7. Beaudoin, G., and Sangster, D. F., 1992. A descriptive model for silver-lead-zinc veins in clastic metasedimentary terranes. Econ. Geol., 87:1005–1021.
8. Beck, R., 1909. Lehre von den Erzlagerstatten, v. 1, Berlin:Borntraeger. 540 p.
9. Bethke, P. M., and Barton, P. B., Jr. 1971. Distribution of some minor elements between coexisting sulfide minerals. Econ. Geol., 66:140–163.
10. Bjørlykke, A., and Sangster, D. F., 1981. An overview of sandstone lead deposits and their relation to red-bed copper and carbonate-hosted lead-zinc deposits. Econ. Geol. 75th Anniv.,:179–213.
11. Bortnikov, N. S., Dobrovol'skaya, M. G., Genkin, A. D., Naumov, V. B., and Shapenko, V. V., 1995. Sphaleritegalena geothermometers:Distribution of cadmium, manganese, and the fractionation of sulfur isotopes. Econ. Geol., 90:155–180.
12. Both, R. A., 1978. “ Remobilization of mineralization during retrograde metamorphism, Broken Hill, New South Wales, Australia ”. In Mineralization in metamorphic terranes, Edited by:Verwoerd, W. J., 481–489. Pretoria:Van Schaik.
13. Bourcier, W. L., and Barnes, H. L., 1987. Ore solution chemistry—VII. Stabilities of chloride and bisulfide complexes of zinc to 350°C. Econ. Geol., 82:1839–1863.
14. Bowie, S. H. U., Kvalheim, A., and Haslam, H. W., 1978. Mineral deposits of Europe, Volume 1:Northwest Europe, London:Inst. Mining Metallurg. 362 p.
15. Boyle, R. W., 1969. “ The geochemistry of cadmium in the lead-zinc-silver deposits of the Keno Hill area, Yukon, Canada ”. In Problems of geochemistry, Edited by:Khitarov, N. I., 234–246. Jerusalem:Israel Program for Scientific Translations.
16. Bradbury, J. C., 1961. Mineralogy and the question of zoning, northwestern Illinois zinc-lead district. Econ. Geol., 56:132–148.
17. Bussel, M. A., Alpers, C. N., Petersen, U., Shepherd, T. J., Bermudez, C., and Baxter, A. N., 1990. The Ag-Mn-Pb-Zn vein, replacement, and skarn deposits of Uchucchacua, Peru:Studies of structure, mineralogy, metal zoning, Sr isotopes, and fluid inclusions. Econ. Geol., 85:1348–1383.
18. Cabri, L. J., Campbell, J. L., Laflamme, J. H. G., Leigh, R. G., Maxwell, J. A., and Scott, J. D., 1985. Proton-microprobe analysis of trace elements in sulfides from massive-sulfide deposits. Can. Mineral., 23:133–148.
19. Cerny, I., 1989. Die karbonatgebundenen Blei-Zink-Lagerstatten des alpinen and aussralpinen Mesozoikums—Die Bedeutung ihrer Geologie, Stratigraphie und Faziesgebundenheit für Prospektion und Bewertung. Archiv für Lagerstättenforschung der Geologischen Bundesanstalt, Wien, 11:5–125.
20. Charbonnier, M., and Murat, M., 1974. Sur la determination des diagrammes de phases a temperature ambiante des sulfures mixtes appartenant aux systèmes Zn-Cd-S, Zn-Hg-S, Cd-Hg-S. Comptes Rendus Acad. Sci. Paris, 278:259–261. ser. C
21. Chen, T. T., and Dutrizac, J. E., 1978. Lautite and cadmium-rich sphalerite from the Ross mine, Hislop township, Ontario. Can. Mineral., 16:665–669.
22. Cherin, P., Lind, E. L., and Davis, E. A., 1970. The preparation and crystallography of cadmium zinc sulfide solid solutions. Jour. Electrochem. Soc., 117 (10):233–236.
23. Coudrain-Ribstein, A., Gouze, P., and de Masily, G., 1998. Temperature-carbon dioxide partial pressure trends in confined aquifers. Chem. Geol., 145:73–89.
24. Cox, D. P., and Singer, D. A., 1986. Mineral deposit models. U.S. Geol. Surv. Bull., 1693 379 p.
25. Craig, J. R., Ljokjell, P., and Vokes, F. M., 1984. Sphalerite compositional variations in sulfide ores of the Norwegian Caledonides. Econ. Geol., 79:1727–1735.
26. Craig, J. R., Solberg, T. N., and Vaughan, D. J., 1983. Growth characteristics of sphalerites in Appalachian zinc deposits, Proc. Int. Conf. on Mississippi Valley type lead-zinc deposits 317–327. Univ. Missouri-Rolla.
27. Cygan, G. L., Hemley, J. J., and D'Angelo, W. M., 1994. An experimental study of zinc chloride speciation from 300 to 600°C and 0.5 to 2.0 kbar in buffered hydrothermal solutions. Geochim. et Cosmochim. Acta, 58:4841–4855.
28. Dangic, A., 1985. Minor element distribution between galena and sphalerite as a geothermometer—application to two lead-zinc areas in Yugoslavia. Econ. Geol., 80:180–183.
29. Daskalakis, K., 1990. The solubility of zinc and cadmium sulfides in sulfidic waters at 25°C:Complexation of zinc and cadmium with sulfide, University of Maryland. Unpubl. Ph.D. dissertation, 184 p.
30. deLoraine, W. F., and Dill, D. B., 1982. Structure, stratigraphic controls, and genesis of the Balmat zinc deposits, northwest Adirondacks, 571–596. New York:Geol. Assoc. Can. Spec. Paper 25.
31. Diaz Rodriguez, L. A., and Fernandez, C. J., 1988. Structure, mineralogy, and geochemistry of the Grupo Cantabria Pb-Zn deposit, Caranga de Arriba, Asturias, northwestern Spain. Econ. Geol., 83:1453–1461.
32. Dunham, K. C., 1948. Geology of the Northern Pennine orefield, Vol. 1, 1–357. Great Britain Geol. Surv. Memoirs, 1948.
33. El Shazly, E. M., Webb, J. S., and Williams, D., 1957. Trace elements in sphalerite, galena and associated minerals from the British Isles. Trans. Inst. Mining Metallurg., 66:241–271.
34. Enjoji, M., and Kim, G. S., 1992. Gold mineralization of the Taechang deposits, Chungcheong-Buk-Do, Korea. Ann. Rep. Inst. Geosci., Univ. Tsukuba, 18:73–78.
35. Ensslin, F., 1952. Der Kadmiumgehalt in den Zinkblenden der Harzer Gruben. Erzmetall, 5:141–142.
36. Eskola, P., 1914. On the petrology of the Orijärvi region in southwestern Finland. Bulletin Commiss. géol. Finlande, 40:1–277.
37. Evans, T. L., Campbell, F. A., and Krouse, H. R., 1968. A reconnaissance study of some western Canadian leadzinc deposits. Econ. Geol., 63:349–359.
38. Foslie, S., 1946. Melkedalen grube i Ofoten. Norges Geol. Undersok., 169:1–108.
39. Franklin, J. M., Lydon, J. W., and Sangster, D. F., 1981. Volcanic-associated massive sulfide deposits. Econ. Geol., 75th Anniversary:485–627.
40. Frietsch, R., Papunen, H., and Vokes, F. M., 1979. The ore deposits of Finland, Norway, and Sweden—a review. Econ. Geol., 74:975–1001.
41. Fruth, I., and Maucher, A., 1966. Spurenelemente and Schwefel-Isotope in Zinkblenden der Blei-Zink-Lagerstätte von Gorno. Mineral. Deposita, 1:238–250.
42. Fryklund, V. C., Jr. and Fletcher, J. D., 1956. Geochemistry of sphalerite from the Star mine, Coeur d'Alene district, Idaho. Econ. Geol., 51:223–247.
43. Gabrielson, O., 1945. Studier over elementfordelningen i zinkbländen fran Svenska fyndorter. Sveriges Geol. Undersök. Arsbok, 39 (468):1–52. ser. C.
44. Gardner, H. D., and Hutcheon, I., 1985. Geochemistry, mineralogy, and geology of the Jason Pb-Zn deposits, Macmillan Pass, Yukon, Canada. Econ. Geol., 80:1257–1276.
45. Geldron, A., 1983. Le germanium:Un élément valorisant des gisements hydrothermaux a Zn-Cu-(Pb). Chron. Rech. Min., 470:25–32.
46. Geletii, V. F., Chernishev, F., and Pastushkova, T. M., 1979. Distribution of cadmium and manganese between galena and sphalerite. Geologiya rudnykh mestorozhdeniy, 21 (6):66–75 in Russian
47. Gemmell, J. B., Simmons, S. F., and Zantop, H., 1988. The Santo Nino silver-lead-zinc vein, Fresnillo district, Zacatecas, Mexico:Part I. Structure, vein stratigraphy, and mineralogy. Econ. Geol., 83:1597–1618.
48. Goldschmidt, V. M., 1911. Die Kontaktmetamorphose im Kristianiagebiet. Videnskapsselskapets Skrifter. I. Mat.-Naturv. Klasse, 1 483 p.
49. Gong, H., Rose, A. W., and Suhr, N. H., 1977. The geochemistry of cadmium in some sedimentary rocks. Geochim. el Cosmochim. Acta, 41:1687–1692.
50. Graeser, S., 1969. Minor elements in sphalerite and galena from Binnatal. Contrib. Mineral. Petrol., 24:156–163.
51. Groves, D. I., and Loftus-Hills, G., 1968. Cadmium in Tasmanian sphalerites. Proc. Aust. Inst. Min. Met., 228:43–51.
52. Hagni, R. D., 1983. “ Minor elements in Mississippi Valley-type ore deposits ”. In Cameron volume on unconventional mineral deposits, Edited by:Shanks, W. C., 71–88. New York:AIME.
53. Hall, G., and Solomon, M., 1962. Metallic mineral deposits. Jour. Geol. Soc. Austral., 9:285–309. part 2
54. Hall, W. E., and Czamanske, G. K., 1972. Mineralogy and trace element content of the Wood River lead-silver deposits, Blaine County, Idaho. Econ. Geol., 67:350–361.
55. Hall, W. E., and Heyl, A. V., 1968. Distribution of minor elements in ore and host rock, Illinois-Kentucky fluorite district and upper Mississippi Valley zinc-lead district. Econ. Geol., 63:655–670.
56. Hall, W. E., Rose, H. J., Jr. and Simons, F., 1971. Fractionation of minor elements between galena and sphalerite, Darwin lead-silver-zinc mine, Inyo County, California, and its significance in geothermometry. Econ. Geol., 66:602–606.
57. Hannak, W. W., 1981. “ Genesis of the Rammelsberg ore deposit near Goslar/upper Harz, Federal Republic of Germany ”. In Handbook of stratabound and stratiform ore deposits, part 3, Edited by:Wolff, K. H., Vol. v. 9, 551–642. Amsterdam:Elsevier.
58. Haranczyk, C., 1957. Trace elements in ore-minerals from Silesian-Cracovian zinc-lead deposits. Instytut Geol. (Warsaw) Bull., 4:63–126.
59. Haranczyk, C., 1979. Metallogenic evolution of the Silesia-Cracow region. Prace Instytutu Geol., 45:109–132.
60. Hayashi, K., Sugaki, A., and Kitakaze, A., 1990. Solubility of sphalerite in aqueous sulfide solutions at temperatures between 25 and 240°C. Geochim. et Cosmochim. Acta, 54:715–725.
61. 34S values and implications for the source of sulfur in volcanogenic hydrothermal systems. Econ. Geol., 90:1167–1196.
62. Indorf, C. P., 1981. The Silver-Hill zinc deposit and associated deposits, central North Carolina. Econ. Geol., 76:1170–1185.
63. Innes, J., and Chaplin, R. C., 1986. “ Ore bodies of the Kombat mine, South West Africa/Namibia ”. In Mineral deposits of southern Africa, Edited by:Anhaeusser, C. R., and Maske, S., 1789–1805. Johannesburg:Geol. Soc. South Africa.
64. Ivanitskiy, T. V., and Gvaramadze, N. D., 1960. Content and distribution of certain dispersed elements in the principal sulfides of the lead-zinc and polymetallic deposits of Georgia. Geochemistry, 2:167–177.
65. Ivanitskiy, T. V., Kaviladze, M. S., and Rubinshteyn, M. M., 1975. Sulfur isotopic composition in the hydrothermal lead-zinc and copper deposits of Georgia. Geochem. Int., 12 (4):26–33.
66. Ivanov, V. V., 1964. Distribution of cadmium in ore deposits. Geochem. Int., 1964:757–768.
67. James, R. H., Elderfield, H., and Palmer, M. R., 1995. The chemistry of hydrothermal fluids from the Broken Spur site, 29°N Mid-Atlantic Ridge. Geochim. et Cosmochim. Acta, 59:651–659.
68. Jankovic, S., 1982. “ Yugoslavia ”. In Mineral deposits of Europe, v. 2:Southeast Europe, Edited by:Dunning, F. W., Mykura, W., and Slater, D., 143–202. London:Inst. Mining Metallurg.
69. Jansen, K., 1995. Erzmikroskopische und geochemische Untersuchungen an Massivsulfiden vom ostpazifischen Rücken bei 7°24'S and 16°43'S, Univ. Hannover. Unpubl. doctoral thesis, 151 p.
70. Johnson, J. W., Oelkers, E. H., and Helgeson, H. C., 1992. SUPCRT92:A software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0 to 1000°C. Computers & Geosci., 18:899–947.
71. Jolly, J. L., and Heyl, A. V., 1964. Mineral paragenesis and zoning in the central Kentucky mineral district. Econ. Geol., 59:596–624.
72. Jolly, J. L., and Heyl, A. V., 1968. Mercury and other trace elements in sphalerite and wallrocks from central Kentucky, Tennessee and Appalachian zinc districts, U.S. Geol. Surv. Bulletin 1252-F, 29 p.
73. Jonasson, I. R., and Sangster, D. F., 1978. Zn:Cd ratios for sphalerites separated from some Canadian sulphide ore samples. Geol. Surv. Can. Pap., 78-1B:195–201.
74. Kalogeropoulos, S. I., Kilias, S. P., and Arvanitidis, N. D., 1996. Physicochemical conditions of deposition and origin of carbonate-hosted base metal sulfide mineralization, Thermes ore-field, Rhodope Massif, northeastern Greece. Mineral. Deposita, 31:407–418.
75. Khamrabayev, I. K., Babajanov, A. A., and Khamrabayeva, Z. I., 1995. High cadmium concentrations in polymetallic ores superimposed on a tungstenmolybdenum skarn mineralization, western Uzbekistan. Global Tectonics and Metallog., 4 (4):195–198.
76. Kharaka, Y. K., Origin and evolution of water and solutes in sedimentary basins. Proc. 3rd Can./Amer. Conf. on Hydrogeology. June22–261986, Banff, Canada. pp. 173–195.
77. Kharaka, Y. K., Gunter, W. D., Aggarwal, P. K., Perkins, E. H., and DeBraal, J. D., 1988. SOLMINEQ88:A computer program for geochemical modeling of water-rock interactions, Rep. 88-4227 U.S. Geol. Surv. Water Resource Invest. 207 p.
78. Kharaka, Y. K., Maest, A. S., Carothers, W. W., Law, L. M., Lamothe, P. J., and Fries, T. L., 1987. Geochemistry of metal-rich brines from central Mississippi Salt Dome basin, U.S.A. Applied Geochem., 2:543–561.
79. Koch, G. S., Jr. and Link, R. F., 1970. Statistical analysis of geological data, New York:John Wiley. 375 p.
80. Kojonen, K., Johanson, B., and Törnroos, R., 1989. Ore mineralogy of the Rauhala Zn-Cu-Pb sulphide deposit, Spec. Paper 11 19–42. Geol. Surv. Finland.
81. Kollwentz, W., 1995. Metallpreisaspekte bei der Lagerstättenbewertung. Ges. Deutsch. Metallhütten-und Bergleute (GDMB) Schriften., 76:87–100.
82. Krahn, L., Friedrich, G., Gussone, R., and Scheps, V., 1986. Zur Blei-Zink-Vererzung in Carbonatgesteinen des Aachen-Stolberger Raums. Fortschr. Geol. Rheinland und Westfalen, 34:133–157.
83. Krause, H., 1961. Analytische und röntgenographische Untersuchungen natürlicher Zinkblenden. Neues Jahrb. Miner. Abh., 97 (2):143–164.
84. Kulikova, M. F., 1962. Trace elements in the oxidized zone of polymetallic deposits of eastern Transbaikaliya. Geochemistry, 2:176–185.
85. Kulikova, M. F., 1963. Cadmium in the oxidized zones of the Nerchinskii Zavod and Klichkin lead-zinc deposits (eastern Transbaikaliya). Geochemistry, 9:897–902.
86. Kullerud, G., 1953. The FeS-ZnS system—a geological thermometer. Norsk Geologisk Tidsskrift, 32:61–147.
87. Kulms, M., 1970. Die Verteilung der Elemente Pb, Zn, Cd, Hg, Cu, Co, Ni, Mn und Fe in den Böden der Lagerstättengebiete Maubach und Bleialf sowie in den Flusswässern und Flussedimenten des Triasdreiecks von Maubach-Mechernich-Kall, Eifel—Ein Beitrag zur geochemischen Erzlagerstättenprospektion, Germany:Univ. of Aachen. Unpubl. doctoral thesis, 195 p.
88. Lange, I. M., Nokleberg, W. J., Plahuta, J. T., Krouse, H. R., and Doe, B. R., 1985. Geologic setting, petrology, and geochemistry of stratiform sphaleritegalenabarite deposits, Red Dog Creek and Drenchwater Creek areas, northwestern Brooks Range, Alaska. Econ. Geol., 80:1896–1926.
89. Latvalahti, U., 1979. Cu-Zn-Pb ores in the Aijala-Orijarvi area, southwest Finland. Econ. Geol., 74:1035–1059.
90. Lippmann, F., 1973. Sedimentary carbonate minerals, New York:Springer. 228 p.
91. Lippmann, F., 1980. Phase diagrams depicting aqueous solubil ity of binary mineral systems. Neues Jahrb. Miner. Abh., 139:1–25.
92. Maher, S. W., and Fagan, J. M., 1970. Trace element conlent of some ore deposits in the southeastern states. Tennessee Div. Geol. Inform. Circular, 16 1 p.
93. Maurel, C., 1978. Stabilité de la blende dans le système Zn-Cd-S. Bull. Minéral., 101:406–411.
94. McKibben, M. A., and Hardie, L. A., 1997. “ Ore forming brines in active continental rifts ”. In Geochemistry of hydrothermal ore deposits, Edited by:Barnes, H. L., 877–935. New York:John Wiley.
95. McKibben, M. A., and Williams, A. E., 1989. Metal speciation and solubility in saline hydrothermal fluids:An empirical approach based on geothermal brine data. Econ. Geol., 84:1996–2007.
96. McKnight, E. T., and Fischer, R. P., 1970. Geology and ore deposits of the Picher field, Oklahoma and Kansas, Prof. Pap. 588 U.S. Geol. Surv. 165 p.
97. McLimans, R. K., Barnes, H. L., and Ohmoto, H., 1980. Sphalerite stratigraphy of the upper Mississippi Valley zinc-lead district, southwest Wisconsin. Econ. Geol., 75:351–361.
98. Meituv, G. M., 1962. Geochemistry of rare elements in the lead-zinc deposit of the Klichkinskii region (eastern Transbaikaliya). Geochemistry, 7:694–706.
99. Mishra, B., and Mookherjee, A., 1988. Geothermometry based on fractionation of Mn and Cd between coexisting sphalerite and galena from some carbonate-hosted sulfide deposits in India. Mineral. Deposita, 23:179–185.
100. Mookherjee, A., 1962. Certain aspects of the geochemistry of cadmium. Geochim. et Cosmochim. Acta, 26:351–360.
101. Narayanaswami, S., Shashikumar, K. T., Sivadas, K. M., and Gopalkrishnan, K. P., 1977. Lead and copper deposits of Agnigundala, Guntur district, Andhra Pradesh. Geol. Surv. India Misc. Publ., 27:391–407.
102. Nishiyama, T., 1974. Minor elements in some sulfide minerals from the Kuroko deposits of the Shakanai mine. Mining Geol. Spec. Iss., 6:371–376.
103. Oftedal, I., 1941. Untersuchungen über die Nebenbestandteile von Erzmineralien Norwegischer zinkblendeführender Vorkommen. Skrifter utgit av Det Norske Videnskaps-Akademi i Oslo, I. Mat.-Naturv. Klasse, 8 103 p.
104. 3ZnS-CdS at 850° and 700°C. Neues Jahrb. Mineral. Abh., 155 (1):23–38.
105. Ozerova, N. A., Rusinov, V. L., and Ozerov, Y. K., 1975. The mercury in sulfide deposits emplaced in volcanic suites. Mineral. Deposita, 10:228–233.
106. Page, D. C., and Watson, M. D., 1976. The Pb-Zn deposit of Rosh Pinah mine, South West Afrika. Econ. Geol., 71:306–327.
107. Pagel, H., 1975. Zur Erzführung und Geochemie in den neuerschlossenen Teilen der Blei-Zinkerzlagerstatte Schneeberg/Monteneve in Südtirol/Alto Adige (N-Italien), Freie Universität Berlin. Unpubl. doctoral thesis, 166 p.
108. Palache, C., 1935. The minerals of Franklin and Sterling Hill, Sussex County, New Jersey, Prof. Paper 180 U.S. Geol. Surv. 135 p.
109. Papunen, H., Kopperoinen, T., and Tuokko, I., 1989. The Taivaljärvi Ag-Zn deposit in the Archean greenstone belt, eastern Finland. Econ. Geol., 84:1262–1276.
110. Patterson, D. J., 1985. Zincian greenockite in stratiform lead-zinc-silver mineralization at Lady Loreta, northwest Queensland. Can. Mineral., 23:89–94.
111. Plumlee, G. S., Leach, D. L., Hofstra, A. H., Landis, G. P., Rowan, E. L., and Viets, J. G., 1994. Chemical reaction path modeling of ore deposition in Mississippi Valley-type Pb-Zn deposits in Ozark region, U.S. midcontinent. Econ. Geol., 89:1361–1383.
112. Riedel, D., 1977. Zur Geochemie und Genese der Lagerstätte Tynagh, Ireland, Univ. of Aachen. Unpubl. doctoral thesis, 153 p.
113. 5 pascals) pressure and at higher temperatures. U.S. Geol. Surv. Bull., 2131:461P
114. Sachan, H. K., 1991. Minor elements geochemistry and ore genesis of Zawar lead-zinc deposit, district Udaipur, Rajasthan (India). Acta Geol. Geograph. Univ. Comenianae Geol. (Bratislava), 46:215–231.
115. Sangster, D. F., 1986. Classification, distribution, and grade-tonnage summaries of Canadian lead-zinc deposits. Can. Geol. Surv. Econ. Geol. Report, 37 68 p.
116. Sangster, D. F., 1990. Mississippi Valley–type and sedex leadzinc deposits:A comparative examination. Trans. Inst. Mining Metall., 99:B21–B42.
117. Sarkar, S. C., Bhattacharyya, P. K., and Mukherjee, A. D., 1980. Evolution of the sulfide ores of Saladipura, Rajasthan, India. Econ. Geol., 75:1152–1167.
118. Schneider, A., and Toloza, R., 1990. “ The mining district of the General Carrera Lake and the Rosillo Manto deposit, Aysén province, southern Chile ”. In Stratabound ore deposits in the Andes, Edited by:Fontboté, L., Amstutz, G. C., Cardozo, M., Cedillo, E., and Frutos, J., 485–494. Berlin:Springer.
119. Schneider, G. I. C., 1991. Mineral resource series—cadmium, Open File Report MRS40 Geol. Surv. Namibia. 9 p.
120. Schroll, E., 1953. Über Unterschiede im Spurengehalt bei Wurtziten, Schalenblenden und Zinkblenden. Sitzungsberichte der mathem.-naturw. Kl., Abt. I, 162 (5):21–332.
121. Schwartz, M. O., 1995. Arsenic in porphyry copper deposits:Economic geology of a polluting element. INT. GEOL. REV., 37:9–25.
122. Schwartz, M. O., 1997. Mercury in zinc deposits:Economic geol ogy of a polluting element. INT. GEOL. REV., 39:905–923.
123. Seal, R. R., II, Cooper, B. J., and Craig, J. R., 1985. Anisotropic sphalerite of the Elmwood-Gordonsville deposits, Tennessee. Can. Mineral., 23:83–88.
124. Sharps, J. A., Brown, G. E., Jr. and Stebbins, J. F., 1993. Kinetics and mechanism of ligand exchange of Au(II), Zn(II), and Cd(II) chlorides in aqueous solutions:An NMR study form 28-98°C. Geochim. et Cosmochim. Acta, 57:721–731.
125. Shock, E. L., Sassani, D. C., Willis, M., and Sverjensky, D. A., 1997. Inorganic species in geologic fluids:Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes. Geochim. et Cosmochim. Acta, 61:907–950.
126. Sims, P. K., and Barton, P. B., Jr. 1961. Some aspects of the geochemistry of sphalerite, Central City district, Colorado. Econ. Geol., 56:1211–1237.
127. Skinner, B. J., 1961. Unit-cell edges of natural and synthetic sphalerites. Amer. Mineral., 46:1399–1411.
128. Smirnov, V. I., 1977. Ore deposits of the USSR, v. 3, London:Pitman. 424 p.
129. Song, X. X., 1984. Minor elements and ore genesis of the Fankou lead-zinc deposit, China. Mineral. Deposita, 19:95–104.
130. Ste-Marie, J., Torma, A. E., and Gübeli, A. O., 1964. The stability of thiocomplexes and solubility products of metal sulphides. Can. Jour. Chem., 42:662–668.
131. 2O system. Geochim. et Cosmochim. Acta, 57:2699–2713.
132. Sverjensky, D. A., 1984. Oil field brines as ore-forming solutions. Econ. Geol., 79:23–37.
133. Sverjensky, D. A., 1985. The distribution of divalent trace elements between sulfides, oxides, silicates and hydrothermal solutions:I. Thermodynamic basis. Geochim. et Cosmochim. Acta, 49:853–864.
134. Sverjensky, D. A., Shock, E. L., and Helgeson, H. C., 1997. Prediction of the thermodynamic properties of aqueous metal complexes to 1000°C and 5 kbar. Geochim. et Cosmochim. Acta, 61:1359–1412.
135. Swaine, D. J., 1990. Trace elements in coal, London:Butterworths. 278 p.
136. Tatsumi, T., 1965. Sulfur isotopic fractionation between co-existing sulfide minerals from some Japanese ore deposits. Econ. Geol., 60:1645–1659.
137. Tauson, V. L., and Chernyshev, L. V., 1977. Phase relationships and structural features of ZnS-CdS mixed crystals. Geochem. Int., 14 (5):11–22.
138. Tikkanen, G. D., 1986. “ World resources and supply of lead and zinc ”. In Economics of internationally traded minerals, Edited by:Bush, W. R., 242–250. Golden, CO:Colorado Soc. Mining Eng.
139. 2+ with calcite between 50 and 250°C. Geochim. et Cosmochim. Acta, 30:439–453.
140. Urabe, T., 1977. Partition of cadmium and manganese between coexisting sphalerite and galena from some Japanese epithermal deposits. Mineral. Deposita, 12:319–330.
141. Van't Dack, L., Blommaert, W., Vandelannoote, R., Gijbels, R., and Van Grieken, R., 1983. Equilibrium constants for trace elements in natural waters. Rev. Analyt. Chem., 7 (1-2):297–401.
142. Västi, K. J., 1989. Geology of the Rauhala stratiform massive Zn-Cu-Pb sulphide deposit, 5–18. Geol. Surv. Finland Spec. Paper 11.
143. Viets, J. G., Hopkins, R. T., and Miller, B. M., 1992. Variations in minor and trace metals in sphalerite from Mississippi Valley-type deposits of the Ozark region:Genetic implications. Econ. Geol., 87:1897–1905.
144. Vlasov, K. A., 1966. Geochemistry and mineralogy of rare elements and genetic types of their deposits, v. 1, Jerusalem:Israel Program for Scientific Translations. 688 p.
145. Von Damm, K. L., 1990. Seafloor hydrothermal activity:Black smoker chemistry and chimneys. Ann. Rev. Earth Planet. Sci., 18:173–204.
146. Von Damm, K. L., 1995. Controls on the chemistry and temporal variability of seafloor hydrothermal fluids. Amer. Geophys. Union Geophys. Monog., 91:222–247.
147. Warren, H. V., and Thompson, R. M., 1945. Sphalerites from western Canada. Econ. Geol., 40:309–335.
148. Watling, R. J., 1976. Trace element distribution in primary sulphide minerals from the Keel prospect, County Longford. Proc. Roy. Irish Acad., 76 (17):241–261. sect. B
149. Webber, B. S., Moss, J. M., and Rutledge, F. A., 1946. Exploration of Sedanka zinc deposit, Sedanka Island, Alaska. U.S. Bureau of Mines Rep. Invest., 3967:1–15.
150. Wedepohl, K. H., ed. 1972. Handbook of geochemistry, Berlin:Springer.
151. Weiner, K. L., and Hochleitner, R., 1989. Greenockit. Lapis, 12:6–9.
152. Whelan, J. F., Rye, R. O., and DeLoraine, W., 1984. The Balmat-Edwards zinc-lead deposits—synsedimentary ore from Mississippi Valley-type fluids. Econ. Geol., 79:239–265.
153. 1999. Metal statistics 1988-1998, Ware, UK:World Bureau of Metal Statistics.
154. Wood, S. A., Crerar, D. A., Brantley, S. L., and Borcsik, M., 1984. Mean molal stochiometric activity coefficients of alkali halides and related electrolytes in hydrothermal solutions. Amer. Jour. Sci., 284:668–705.
155. Yamaoka, K., 1962. Studies of the bedded cupriferous iron sulfide deposits occurring in the Sambagawa metamorphic zone. Sci. Rep. Tohoku University (Japan), ser. 3, v. 8 (1):1–137.
156. Young, B., Bridges, T. F., and Ineson, P. R., 1987. Supergene cadmium mineralisation in the Northern Pennine orefield. Proc. Yorkshire Geol. Soc., 46:275–278. part 3
157. Yushkin, N. P., Yeremin, N. I., and Khoroshilova, L. A., 1975. New manganiferous variety of sphalerite. Doklady Akad. Nauk SSSR, 216:166–169.