Volumes of ions, ion pairs, and electrostriction of alkali halides in aqueous solutions at 25°C

Marine Chemistry

Volumn 70, Issue 1-3, 2000, Pages 49-59

  Heyrovska R ^a  

^a J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

Author keywords

Alkali halides; Electrostriction; Ionic volumes; Molal volumes; Partial dissociation; Partial molal volume; Solution densities

Indexed keywords

ELECTROCHEMISTRY; HALIDE; WATER CHEMISTRY;

EID: 0034076607     PISSN: 03044203     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0304-4203(00)00014-1     Document Type: Article

References (19)

1. Arrhenius S. Über die Dissociation der in Wasser gelösten Stoffe. Z. Phys. Chem. 1:1887;631-648.
2. Darvell B.W., Leung W.H. RIP ionic strength 1921-91. Chem. Br. 27:1991;29-30.
3. Franks F. Old habits die hard. Chem. Br. 27:1991;315.
4. Harned H.S., Owen B.B. The Physical Chemistry of Electrolytic Solutions. 1958;Rheinhold, New York.
5. Heydweiller A. Dichte und Konstitution wässeriger Salzlösungen. Z. Phys. Chem. 70:1910;128-133.
6. Heyrovská R. Interpretation of properties of aqueous electrolyte solutions in terms of hydration and incomplete dissociation. Collect. Czech. Chem. Commun. 53:1988;687-696.
7. Heyrovská R. A reappraisal of Arrhenius' theory of partial dissociation of electrolytes. Stock J.T., Orna M.V. Electrochemistry, Past and Present. ACS Symposium Series 390, ACS, Washington. 1989;. Chapter 6, and the literature therein.
8. Heyrovská R. Effective radii of alkali halide ions in aqueous solutions, crystals and in the gas phase and the interpretation of Stokes radii. Chem. Phys. Lett. 163:1989;207-211.
9. Heyrovská R. Ionic concentration outlives ionic strength! Chem. Br. 27:1991;1114.
10. Heyrovská R. Physical electrochemistry of strong electrolytes based on partial dissociation and hydration: quantitative interpretation of the thermodynamic properties of NaCl(aq) at 25°C from "zero to saturation" J. Electrochem. Soc. 143:1996;1789-1793.
11. Heyrovská R. Equations for densities and dissociation constant of NaCl(aq) at 25°C from "zero to saturation" based on partial dissociation. J. Electrochem. Soc. 144:1997;2380-2384.
12. Heyrovská R. Degrees of dissociation and hydration numbers of alkali halides in aqueous solutions at 25°C (some up to saturation). Croat. Chem. Acta. 70:1997;39-54.
13. Heyrovská R. Physical electrochemistry of solutions of strong electrolytes (partial dissociation and hydration from "zero to saturation"). Chem. Listy. 92:1998a;157-166.
14. Heyrovská R. Notes on hydration theory. Butler J.N. Ionic Equilibrium. 1998;477-484 Wiley, New York.
15. Heyrovská R. Mean distance of closest approach of ions in NaCl(aq) at 25°C calculated from degrees of association using Bjerrum's theory. Curr. Sci. 78:1999;179-182.
16. Krumgalz B.S., Pogorelsky R., Pitzer K.S. Volumetric properties of single aqueous electrolytes from zero to saturation concentration at 298.15 K represented by Pitzer's ion-interaction equations. J. Phys. Chem. Ref. Data. 25:1996;663-689.
17. Millero F.J. The molal volumes of electrolytes. Chem. Rev. 71:1971;147-176.
18. Pauling L. The Nature of the Chemical Bond. 1960;Cornell Univ. Press, Ithaca.
19. Robinson R.A., Stokes R.H. Electrolyte Solutions. 1970;Butterworths, London.