Physical electrochemistry of strong electrolytes based on partial dissociation and hydration: Quantitative interpretation of the thermodynamic properties of NaCl(aq) from "zero to saturation"

Journal of the Electrochemical Society

Volumn 143, Issue 6, 1996, Pages 1789-1793

  Heyrovska R ^a,b  

^a J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

^b ELECTROCHEMICAL SOCIETY

Author keywords

[No Author keywords available]

Indexed keywords

DISSOCIATION; ELECTROCHEMISTRY; HYDRATION; IONS; SODIUM CHLORIDE; THERMODYNAMIC PROPERTIES;

MOLALITY; NONIDEALITY; OSMOTIC COEFFICIENTS; STRONG ELECTROLYTES;

ELECTROLYTES;

EID: 0030173575     PISSN: 00134651     EISSN: None     Source Type: Journal    
DOI: 10.1149/1.1836905     Document Type: Article

References (33)

1. R. A. Robinson and R. H. Stokes, Electrolyte Solutions, Butter-worths, London (1955, 1970).
2. R. Heyrovská, in Electrochemistry, Past and Present, ACS Symp. Series 390, J. T. Stock and M. V. Orna, Editors, Chap. 6, ACS, Washington, DC (1989); and references therein.
3. B. W. Darvell and V. W-H. Leung, Chem. Br., 27, 29 (1991).
4. F. Franks, ibid., 27, 315 (1991).
5. R. Heyrovská, ibid., 27, 1114 (1991).
6. S. Arrhenius, Z. Phys. Chem., 1, 631 (1887).
7. W. R. Bousfield, Trans. Faraday Soc., 13, 141 (1917).
8. (a) R. Heyrovská, Coll. Czechosl. Chem. Commun., 53, 686 (1988);
9. (b) ibid., 57, 2209 (1992); and
10. (c) Unpublished results.
11. D. G. Archer, J. Phys. Chem. Ref. Data, 21, 793 (1992).
12. R. Heyrovská, (a) Abstracts, International Symposium on Molecular and Dynamic Approaches to Electrolyte Solutions, Tokyo, Japan, 1988; (b) Posters of XII International Symposium on Futures in Marine Chemistry, Brijuni, Croatia, 1993.
13. R. Heyrovská, (a) Abstracts, International Symposium on Molecular and Dynamic Approaches to Electrolyte Solutions, Tokyo, Japan, 1988; (b) Posters of XII International Symposium on Futures in Marine Chemistry, Brijuni, Croatia, 1993.
14. H. Ohtaki and N. Fukushima, J. Soln. Chem., 21, 23 (1992).
15. H. Ohtaki, Pure Appl. Chem., 65, 203 (1993).
16. R. Heyrovská, (a) Abstract 662, p. 999, The Electrochemical Society Extended Abstracts, Vol. 95-1 Reno, NV, May 21-26, 1995; (b) Abstract 425, p. 584, Abstract 426 p. 586, The Electrochemical Society Extended Abstracts, Vol. 84-1, Cincinnati, OH, May 6-11, 1984; (c) Abstract 652, p. 951, Abstract 653, p. 953, The Electrochemical Society Extended Abstracts, Vol. 84-2, New Orleans, LA, Oct. 7-12, 1984; (d) Abstract 442, p.660, Abstract 443, p. 662, Abstract 444, p. 664, The Electrochemical Society Extended Abstracts, Vol. 85-2, Las Vegas, NV, Oct. 13-18, 1985; (e) Abstract 463, p. 664, Abstract 472, p. 677, The Electrochemical Society Extended Abstracts, Vol. 87-1, Philadelphia, PA, May 10-15, 1987; (f) Abstract 1454, p. 1985, The Electrochemical Society Extended Abstracts, Vol. 87-2, Honolulu, HI, Oct. 18-23, 1987.
17. R. Heyrovská, (a) Abstract 662, p. 999, The Electrochemical Society Extended Abstracts, Vol. 95-1 Reno, NV, May 21-26, 1995; (b) Abstract 425, p. 584, Abstract 426 p. 586, The Electrochemical Society Extended Abstracts, Vol. 84-1, Cincinnati, OH, May 6-11, 1984; (c) Abstract 652, p. 951, Abstract 653, p. 953, The Electrochemical Society Extended Abstracts, Vol. 84-2, New Orleans, LA, Oct. 7-12, 1984; (d) Abstract 442, p.660, Abstract 443, p. 662, Abstract 444, p. 664, The Electrochemical Society Extended Abstracts, Vol. 85-2, Las Vegas, NV, Oct. 13-18, 1985; (e) Abstract 463, p. 664, Abstract 472, p. 677, The Electrochemical Society Extended Abstracts, Vol. 87-1, Philadelphia, PA, May 10-15, 1987; (f) Abstract 1454, p. 1985, The Electrochemical Society Extended Abstracts, Vol. 87-2, Honolulu, HI, Oct. 18-23, 1987.
18. R. Heyrovská, (a) Abstract 662, p. 999, The Electrochemical Society Extended Abstracts, Vol. 95-1 Reno, NV, May 21-26, 1995; (b) Abstract 425, p. 584, Abstract 426 p. 586, The Electrochemical Society Extended Abstracts, Vol. 84-1, Cincinnati, OH, May 6-11, 1984; (c) Abstract 652, p. 951, Abstract 653, p. 953, The Electrochemical Society Extended Abstracts, Vol. 84-2, New Orleans, LA, Oct. 7-12, 1984; (d) Abstract 442, p.660, Abstract 443, p. 662, Abstract 444, p. 664, The Electrochemical Society Extended Abstracts, Vol. 85-2, Las Vegas, NV, Oct. 13-18, 1985; (e) Abstract 463, p. 664, Abstract 472, p. 677, The Electrochemical Society Extended Abstracts, Vol. 87-1, Philadelphia, PA, May 10-15, 1987; (f) Abstract 1454, p. 1985, The Electrochemical Society Extended Abstracts, Vol. 87-2, Honolulu, HI, Oct. 18-23, 1987.
19. R. Heyrovská, (a) Abstract 662, p. 999, The Electrochemical Society Extended Abstracts, Vol. 95-1 Reno, NV, May 21-26, 1995; (b) Abstract 425, p. 584, Abstract 426 p. 586, The Electrochemical Society Extended Abstracts, Vol. 84-1, Cincinnati, OH, May 6-11, 1984; (c) Abstract 652, p. 951, Abstract 653, p. 953, The Electrochemical Society Extended Abstracts, Vol. 84-2, New Orleans, LA, Oct. 7-12, 1984; (d) Abstract 442, p.660, Abstract 443, p. 662, Abstract 444, p. 664, The Electrochemical Society Extended Abstracts, Vol. 85-2, Las Vegas, NV, Oct. 13-18, 1985; (e) Abstract 463, p. 664, Abstract 472, p. 677, The Electrochemical Society Extended Abstracts, Vol. 87-1, Philadelphia, PA, May 10-15, 1987; (f) Abstract 1454, p. 1985, The Electrochemical Society Extended Abstracts, Vol. 87-2, Honolulu, HI, Oct. 18-23, 1987.
20. R. Heyrovská, (a) Abstract 662, p. 999, The Electrochemical Society Extended Abstracts, Vol. 95-1 Reno, NV, May 21-26, 1995; (b) Abstract 425, p. 584, Abstract 426 p. 586, The Electrochemical Society Extended Abstracts, Vol. 84-1, Cincinnati, OH, May 6-11, 1984; (c) Abstract 652, p. 951, Abstract 653, p. 953, The Electrochemical Society Extended Abstracts, Vol. 84-2, New Orleans, LA, Oct. 7-12, 1984; (d) Abstract 442, p.660, Abstract 443, p. 662, Abstract 444, p. 664, The Electrochemical Society Extended Abstracts, Vol. 85-2, Las Vegas, NV, Oct. 13-18, 1985; (e) Abstract 463, p. 664, Abstract 472, p. 677, The Electrochemical Society Extended Abstracts, Vol. 87-1, Philadelphia, PA, May 10-15, 1987; (f) Abstract 1454, p. 1985, The Electrochemical Society Extended Abstracts, Vol. 87-2, Honolulu, HI, Oct. 18-23, 1987.
21. R. Heyrovská, (a) Abstract 662, p. 999, The Electrochemical Society Extended Abstracts, Vol. 95-1 Reno, NV, May 21-26, 1995; (b) Abstract 425, p. 584, Abstract 426 p. 586, The Electrochemical Society Extended Abstracts, Vol. 84-1, Cincinnati, OH, May 6-11, 1984; (c) Abstract 652, p. 951, Abstract 653, p. 953, The Electrochemical Society Extended Abstracts, Vol. 84-2, New Orleans, LA, Oct. 7-12, 1984; (d) Abstract 442, p.660, Abstract 443, p. 662, Abstract 444, p. 664, The Electrochemical Society Extended Abstracts, Vol. 85-2, Las Vegas, NV, Oct. 13-18, 1985; (e) Abstract 463, p. 664, Abstract 472, p. 677, The Electrochemical Society Extended Abstracts, Vol. 87-1, Philadelphia, PA, May 10-15, 1987; (f) Abstract 1454, p. 1985, The Electrochemical Society Extended Abstracts, Vol. 87-2, Honolulu, HI, Oct. 18-23, 1987.
22. W. J. Hamer and Y-C. Wu, J. Phys. Chem. Ref. Data, 1, 1067 (1972).
23. C. W. Davies, Ion Association, Butterworths, London (1962).
24. G. N. Lewis and M. Randall, J. Am. Chem. Soc., 43, 1112 (1921).
25. R. Bates, in Electrochemistry, Past and Present ACS Symposium Series 390, J. T. Stock and M. V. Orna, Editors, Chap. 10, ACS, Washington, DC (1989).
26. K. S. Pitzer, J. C. Peiper, and R. H. Busey, J. Phys. Chem. Ref. Data, 13, 1 (1984).
27. A. Heydweiller, Z. Phys. Chem., 70, 128 (1910).
28. R. W. Gurney, Ionic Processes in Solution, Dover, New York (1953).
29. F. J. Millero, Chem. Rev., 71, 147 (1971).
30. B. E. Conway, Ionic Hydration in Chemistry and Biophysics, Elsevier, Amsterdam (1981).
31. H. S. Harned and B. B. Owens, The Physical Chemistry of Electrolytic Solutions, Reinhold, New York (1958).
32. R. Heyrovská, Chem. Phys. Lett., 163, 207 (1989).
33. International Critical Tables; Section III, McGraw-Hill, New York (1928).