Understanding radical chemistry in the marine boundary layer

Physics and Chemistry of the Earth, Part C: Solar, Terrestrial and Planetary Science

Volumn 25, Issue 3, 2000, Pages 235-243

  Carslaw, N ^a   Jacobs, P J ^a   Pilling, M J ^a  

^a UNIVERSITY OF LEEDS   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CHEMISTRY; BOUNDARY LAYER; MARINE ATMOSPHERE; RADICAL;

EID: 0034002713     PISSN: 14641917     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1464-1917(00)00011-8     Document Type: Article

References (23)

1. Atkinson R., A structure-activity relationship for the estimation of rate constants for the gas-phase reactions of OH radicals with organic compounds, Int. J. Chem. Kinetics, 19, 799-828, 1987.
2. Cantrell C.A., Stedman D.H., and Wendel G.J., Measurement of atmospheric peroxy radicals by chemical amplification, Anal. Chem., 56, 1496-1502, 1984.
3. 2 radicals in the marine boundary layer: 1. Model construction and comparison with measurements, in press J. Geophys. Res., 1999a.
4. 2 radicals in the marine boundary layer: 2. Mechanism reduction and uncertainty analysis, in press J. Geophys. Res., 1999b.
5. 2 in the troposphere by laser-induced fluorescence, J. Chem. Soc., Faraday Trans., 93, 2907-2913, 1997.
6. Curtis A.R. and Sweetenham W.P., FACSIMILE/CHEKMAT Users Manual. AERER12805. London: HMSO, 1987.
7. DeMore, W.B., Sander S.P., Golden D.M., Hampson R.F., Kurylo M.J., Howard C.J., Ravishankara A.R., Kolb C.E., and Molina M.J., Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling: Eval. 11, Jet Propul. Lab., Pasadena, Calif., 1994.
8. Derwent R.G., The influence of human activities on the distribution of hydroxyl radicals in the troposphere, Phil. Trans. R. Soc. Lond. A, 354, 501-531, 1996.
9. Eisele F.L., Mount G.H., Fehsenfeld F.C., Harder J., Marovich E., Parrish D.D., Roberts J., and Trainer M., Intercomparison of tropospheric OH and ancillary trace gas measurements at Fritz Peak Observatory, Colorado, J. Geophys. Res., 99, 18605-18626, 1994.
10. Eisele F.L., Tanner D.J., Cantrell C.A., and Calvert J.G., Measurements and steady state calculations of OH concentrations at Mauna Loa Observatory, J. Geophys. Res., 101, 14665-14679, 1996.
11. Fischbeck H.J. and Fischbeck K.H., Formulas, Facts and Constants, Springer Verlag, 1987.
12. Jenkin M.E., Saunders S.M., and Pilling M.J., The tropospheric degradation of volatile organic compounds: A protocol for mechanism development, Atmos. Environ., 31, 81-104, 1997a.
13. Jenkin M.E., Hayman G.D., Derwent R.G., Saunders S.M., and Pilling M.J., Tropospheric chemistry modelling: Improvements to current models and application to policy issues, AEAT Report, AEA/RAMP/20150/R001, 1997b.
14. Kwok E.S.C. and Atkinson R., Estimation of hydroxyl radical reaction rate constants for gas-phase organic compounds using a structure-reactivity relationship: An update, Atmos. Environ., 29, 1685-1695, 1995.
15. Logan J.A., Prather M.J., Wofsy S.C., and McElroy M.B., Tropospheric chemistry: A global perspective, J. Geophys. Res., 86, 7210-7254, 1981.
16. McKeen S.A., Liu S.C., Mount G. Eisele F., Williams E., Harder J., Goldan P., Kuster W., Tanner D., Fried A., Sewell S., Cantrell C., and Shetter R., Photochemical modeling of hydroxyl and its relationship to other species during the tropospheric OH photochemistry experiment,J. Geophys. Res., 102, 6467-6493, 1997.
17. Penkett S.A., Monks P.S., Carpenter L.J., Clemitshaw K.C., Ayers G.P., Gillett R.W., Galbally I.E., and Meyer C.P., Relationships between ozone photolysis rates and peroxy radical concentrations in clean marine air over the Southern Ocean, J. Geophys. Res., 102, 12805-12817, 1997.
18. Poppe D., Zimmermann J., Bauer R., Brauers T., Brüning D., Callies J., Dorn H.-P., Hofzumahaus A., Johnen F.-J., Khedim A., Koch H., Koppmann R., London H., Müller K.-P., Neuroth R., Plass-Dülmer C., Platt U., Rohrer F., Röth E.-P., Rudolph J., Schmidt U., Wallasch M., and Ehhalt D.H., Comparison of measured OH concentrations with model calculations, J. Geophys. Res., 99, 16633-16642, 1994.
19. Press W.H., Teukolsky S.A., Vetterling W.T., and Flannery B.P., Numerical Recipes in Fortran, The Art of Scientific Computing, Second Edition, Cambridge University Press, 1994.
20. Turanyi T., Berces T. and Vajda S., Reaction rate analysis of complex kinetic systems, Int. J. Chem. Kin., 21, 83-99, 1989.
21. Zeng G., Pilling M.J. and Saunders S.M., Mechanism reduction for tropospheric chemistry: Butane oxidation,J. Chem. Soc, Faraday Trans., 93, 2937-2946, 1997.
22. Yin F., Grosjean D., and Seinfeld J.H., Photooxidation of dimethyl sulfide and dimethyl disulfide: I mechanism development, J. Atmos. Chem. 11, 309-364, 1990a.
23. Yin F., Grosjean D., and Seinfeld J.H., Photooxidation of dimethyl sulfide and dimethyl disulfide: 2 mechanism evaluation, J. Atmos. Chem., 11, 365-399, 1990b.