Molecular analysis of interpolymer complexation in graft copolymer networks

Polymer

Volumn 41, Issue 1, 2000, Pages 73-80

  Lowman, A M ^a   Peppas, N A ^a  

^a PURDUE UNIVERSITY   (United States)

Author keywords

Complexation; Graft copolymers; Poly(ethylene glycol)

Indexed keywords

ACRYLICS; COMPLEXATION; FREE RADICAL POLYMERIZATION; GELS; HYDROGEN BONDS; MOLECULAR DYNAMICS; MOLECULAR STRUCTURE; MOLECULAR WEIGHT; MONOMERS; PH EFFECTS; POLYETHYLENE GLYCOLS; VAN DER WAALS FORCES;

EQUILIBRIUM COMPLEXATION THEORY; INTERPOLYMER COMPLEXATION; POLYMETHACRYLIC ACID;

GRAFT COPOLYMERS;

COPOLYMER; FREE RADICAL; MACROGOL; METHACRYLIC ACID; POLYMETHACRYLIC ACID;

ARTICLE; COMPLEX FORMATION; CROSS LINKING; HYDROGEN BOND; MOLECULAR WEIGHT; PH; STRUCTURE ANALYSIS;

EID: 0033990425     PISSN: 00323861     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0032-3861(99)00159-7     Document Type: Article

References (46)

1. Bailey F.E., Lundberg R.D., Callard R.W. Some factors affecting the molecular association of poly(ethylene glycol) and poly(acrylic acid) in aqueous solution. J Polym Sci. 2:1964;845-851.
2. Kabanov V.A., Papisov I.M. Formation of complexes between complementary synthetic polymers and oligomers in dilute solution. Vysokomol Soedin. A21:1979;243-281.
3. Osada Y. Equilibrium study of polymer-polymer complexation of poly(methacrylic acid) and poly(acrylic acid) with complementary polymers through cooperative hydrogen bonding. J Polym Sci: Polym Chem Ed. 17:1979;3485-3498.
4. Bekturov E.A., Bimendina L.A. Interpolymer complexes. Adv Polym Sci. 43:1981;100-147.
5. Tsuchida E., Abe K. Interactions between macromolecules in solution and intermacromolecular complexes. Adv Polym Sci. 45:1982;1-119.
6. Scranton A.B., Klier J., Peppas N.A. Complexation thermodynamics of free and graft oligomers with complementary polymers. J Polym Sci: Polym Phys Ed. 29:1991;211-224.
7. Bell C.L., Peppas N.A. Biomedical membranes from hydrogels and interpolymer complexes. Adv Polym Sci. 122:1995;125-175.
8. Osada Y. Effects of polymers and their chain lengths on the contraction of poly(methacrylic acid) network. J Polym Sci: Polym Lett Ed. 18:1980;281-286.
9. Moharram M.A., Balloomal L.S., El-gendy H.M. Infrared study of the complexation of polyl(acrylic acid) with poly(acrylamide). J Appl Polym Sci. 59:1996;987-990.
10. Bel'nikevich N.G., Budtova T.V., Ivanova N.P., Panarin Ye.F., Panov Yu.N., Frenkel S.Ya. Complex-formation in aqueous solutions of mixtures of poly(acrylic acid) and poly(vinyl alcohol) and its copolymers. Vysokomol Soedin. A31:1989;1691-1696.
11. Lee Y.M., Kim S.H., Cho C.S. Synthesis and swelling characteristics of pH and thermoresponsive interpenetrating polymer network hydrogel composed of poly(vinyl alcohol) and poly(acrylic acid). J Appl Polym Sci. 62:1996;301-311.
12. Byun J., Lee Y.M., Cho C.S. Swelling of thermosensitive interpenetrating polymer networks composed of poly(vinyl alcohol) and poly(acrylic acid). J Appl Polym Sci. 61:1996;697-702.
13. Shin H.S., Kim S.Y., Lee Y.M. Indomethacin release behaviors from pH and thermoresponsive poly(vinyl alcohol) and poly(acrylic acid) in hydrogels for site-specific drug delivery. J Appl Polym Sci. 65:1997;685-693.
14. Wang Q., He L., Huang J. Supermolecular structure and mechanical properties of P(AN-AM-A)/PVA intermacromolecular complex formed through hydrogen bonding. J Appl Polym Sci. 64:1997;2089-2096.
15. Antipina A.D., Baranovsky V.Yu., Papisov I.M., Kabanov V.A. Equilibrium peculiarities in the complexing of polymeric acids with poly(ethylene glycol). Vysokomol Soyed. A14:1972;941-949.
16. Osada Y., Sato M. Thermal equilibrium of the intermacromolecular complexes of polycarboxylic acids realized by cooperative hydrogen bonding. J Polym Sci: Polym Lett Ed. 14:1976;129-134.
17. Nishi S., Kotaka T. Complex-forming poly(oxyethylene):poly(acrylic acid) interpenetrating polymer networks. 1. Preparation, structure, and viscoelastic properties. Macromolecules. 18:1985;1519-1525.
18. Nishi S., Kotaka T. Complex-forming poly(oxyethylene):poly(acrylic acid) interpenetrating polymer networks. 2. Function as a chemical valve. Macromolecules. 19:1986;978-984.
19. Krupers M.J., Van der Gaag F.J., Feijen J. Complexation of poly(ethylene oxide) with poly(acrylic acid-co-hydroxyethyl methacrylate)s. Eur Polym J. 32:1996;785-790.
20. Papisov I.M., Baranovsky V.Yu., Sergieva Y.I., Antipina A.D., Kabanov V.A. Thermodynamics of complex formation between poly(methacrylic acid) and polyethylene glycols. Calculation of temperatures of breakdown of complexes of oligomers and matrices. Vysokomol Soedin. A16:1974;1133-1141.
21. Osada Y., Honda K., Ohta M. Control of water permeability by mechanochemical contraction of poly(methacrylic acid)-grafted membranes. J Membr Sci. 27:1986;339-347.
22. Hemker D.J., Frank C.W. Dynamic light scattering studies of the fractal aggregation of poly(methacrylic acid) and poly(ethylene glycol). Macromolecules. 23:1987;4404-4410.
23. Osada Y. Conversion of chemical energy into mechanical energy by synthetic polymers (chemomechanical systems). Adv Polym Sci. 82:1987;1-46.
24. Klier J., Peppas N.A. Structure and swelling behavior of poly(ethylene glycol)/poly(methacrylic acid) complexes. Brannon-Peppas L., Harland R.S. Absorbent Polymer Technology. 1990;147-169 Elsevier, Amsterdam.
25. Klier J., Scranton A.B., Peppas N.A. Self-associating networks of poly(methacrylic acid-g-ethylene glycol). Macromolecules. 23:1990;4944-4949.
26. Peppas N.A., Klier J. Controlled release by using poly(methacrylic acid-g-ethylene glycol) hydrogels. J Controlled Release. 16:1991;203-214.
27. Eagland D., Crowther N.J., Butler C.J. Complexation between polyoxyethylene and polymethacrylic acid - the importance of the molar mass of polyoxyethylene. Eur Polym J. 30:1994;767-773.
28. Philippova O.E., Starodubtzev S.G. Intermacromolecular complexation between poly(methacrylic acid) hydrogels and poly(ethylene glycol). J Membr Sci: Pure Appl Chem. A32:1995;1893-1902.
29. Baranovsky V.Yu., Shenkov S. Competitive complex forming reactions between monosubstituted and nonsubstituted poly(ethylene glycol)s with poly(methacrylic) acid. J Polym Sci: Polym Chem Ed. 34:1996;163-167.
30. Bell C.L., Peppas N.A. Swelling/syneresis phenomena in gel-forming interpolymer complexes. J Biomater Sci: Polym Ed. 7:1996;671-683.
31. Bell C.L., Peppas N.A. Water, solute and protein diffusion in physiologically responsive hydrogels of poly(methacrylic acid-g-ethylene glycol. Biomaterials. 17:1996;1203-1218.
32. Karybiants N.S., Phillippova O.E., Starodubtzev S.G., Khoklov A.R. Conformational transitions in poly(methacrylic acid) gel/poly(ethylene glycol) complexes. Effect of the gel cross-linking density. Macromol Chem Phys. 197:1996;2373-2378.
33. Bell C.L., Peppas N.A. Modulation of drug permeation through interpolymer complexed hydrogels for drug delivery applications. J Controlled Release. 39:1997;201-207.
34. Lowman A.M., Peppas N.A. Analysis of the complexation/decomplexation phenomena in graft copolymer networks. Macromolecules. 30:1997;4959-4965.
35. Lowman A.M., Peppas N.A. Pulsatile drug delivery based on a complexation/decomplexation mechanism. DeNuzzio J., Dinh S. Intelligent Materials and Novel Concepts for Controlled Release Technologies. 1999;American Chemical Society, Washington, DC. in press.
36. Lowman A.M., Peppas N.A., Morishita M., Nagai T. Novel bioadhesive complexation networks for oral protein delivery. McCullough I., Shalay S. Materials for Controlled Release Applications. 1999;American Chemical Society, Washington, DC. in press.
37. Bimendina L.A., Roganov V.V., Bekturov E.A. Hydrodynamic properties of polymethacrylic acid-polyvinylpyrrolidone complexes in solution. Vysokomol Soedin. A16:1974;2810-2814.
38. Ohno H., Abe K., Tsuchida E. Solvent effect on the formation of poly(methacrylic acid)-poly(N-vinyl pyrrolidone) complex through hydrogen bonding. Makromol Chem. 179:1978;755-763.
39. Usaitis A., Maunu S.L., Tenhu H. Aggregation of the interpolymer complex of poly(methacrylic acid) and poly(vinyl pyrrolidone) in aqueous solutions. Eur Polym J. 33:(2):1997;219-223.
40. Samsonov G.V. Polymeric complexes on synthetic polyelectrolytes and physiologically active components. Vysokomol Soedin. A21:1979;723-733.
41. Papisov I.M., Litmanovich A.A. Molecular "recognition" in interpolymer interactions and matrix polymerization. Adv Polym Sci. 90:1988;139-179.
42. Brannon-Peppas L. Preparation and characterization of crosslinked hydrophilic networks. Brannon-Peppas L., Harland R.S. Absorbent Polymer Technology. 1990;45-66 Elsevier, Amsterdam.
43. Flory P.J. Principles of Polymer Chemistry. 1953;Cornell University Press, Ithaca, New York.
44. Treloar R.G. The Physics of Rubber Elasticity. 2nd ed :1958;Oxford University Press, Oxford.
45. Peppas N.A., Merrill E.W. Crosslinked poly(vinyl alcohol) hydrogels as swollen elastic networks. J Appl Polym Sci. 21:1977;1763-1770.
46. Odian G. Principles of Polymerization. 2nd ed :1970;Wiley, New York.