Composite electrolytes comprising polytetramethylene/polypropylene glycol-based waterborne polyurethanes and polyethylene oxide via a mixture design approach

Industrial and Engineering Chemistry Research

Volumn 39, Issue 1, 2000, Pages 72-78

  Wen, Ten Chin ^a   Tseng, Hwang Shin ^a   Cheng, Tsung Tien ^a  

^a NATIONAL CHENG KUNG UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

COMPOSITE MATERIALS; DIFFERENTIAL SCANNING CALORIMETRY; IMPREGNATION; MATHEMATICAL MODELS; POLYETHYLENE OXIDES; POLYPROPYLENES; POLYURETHANES; REGRESSION ANALYSIS; SOLUBILITY;

COMPOSITE ELECTROLYTES (CE); POLARIZED MICROGRAPH (PM);

POLYELECTROLYTES;

GLYCOL; MACROGOL; POLYPROPYLENE; POLYURETHAN;

ARTICLE; CONDUCTANCE; DIFFERENTIAL SCANNING CALORIMETRY; MISCIBILITY; MOLECULAR INTERACTION; POLYMERIZATION; SYNTHESIS;

EID: 0033957952     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie990373c     Document Type: Article

References (37)

1. Weston, J. E.; Steele, B. C. H. Thermal History-Conductivity Relationship in Lithium Salt-Poly(ethylene oxide) Complex Poly-mer Electrolytes. Solid State Ionics 1981, 2, 347.
2. Berthier, C.; Gorecki, W.; Minier, M.; Armand, M. B.; Chabagno, J. M.; Rigaud, P. Microscopic Investigation of Ionic Conductivity in Alkali Metal Salts-Poly(ethylene oxide) Adducts. Solid State Ionics 1983, 11, 91.
3. 4 Polymer Electrolytes. Solid State Ionics 1986, 18-19, 265.
4. Robitalle, C. D.; Fauteux, D. Phase Diagrams and Conductivity Characterization of Some PEO-LiX Electrolytes. J. Electrochem. Soc. 1986, 733, 315.
5. Giles, J. R. M.; Gray, F. M.; MacCallum, J. R.; Vincent, C. A. Synthesis and Characterization of ABA Block Copolymer-Based Polymer Electrolytes. Polymer 1989, 28, 1977.
6. 4 Polymer Electrolytes. J. Electrochem. Soc. 1992, 139, 3046.
7. Tsutsumi, H.; Yamamoto, M.; Morita, M.; Matsuda, Y.; Nakamura, T.; Asai, H. Single-and Bouble-ion Type Cross-linked Polysiloxane Soild Electrolytes for Lithium Cells. J. Power Sources 1993, 41, 291.
8. Bischoff, H.; Rahnar, D.; Wiesener, K. Enhancement of the Ionic Conductivity and the Amorphous State of Solid Polymer Electrolytes for Rechargeable Lithium Batteries. J. Power Sources 1993, 43-44, 473.
9. Sun, X. G.; Lin, Y. Q.; Ding, L. M.; Jing, X. B. Ionic Conductivity of Polymer Gel Electrolytes Based on Poly(polyethylene glycol dimethacrylate). Electrochim. Acta 1996, 41, 1572.
10. Blonskey, P. M.; Shriver, D. F.; Austin, P.; Allcock, H. R. Polyphosphazene Solid Elecrolytes. J. Am. Chem. Soc. 1984, 706, 6854.
11. Blonskey, P. M.; Shriver, D. F.; Austin, P.; Allcock, H. R. Complex Formation and Ionic Conductivity of Polyphosphazene Soild Electrolytes. Solid State Ionics 1986, 78-79, 258.
12. Allcock, H. R.; Austin, P. E.; Neenan, T. X.; Sisko, J. T.; Blonsky, P. M.; Shriver, D. F. Polyphosphazenes with Etheric Side Groups: Prospective Biomedical and Solid Electrolyte Polymers. Macromolecules 1986, 79, 1508.
13. 3 Films. J. Electrochem. Soc. 1989, 736, 2565.
14. n. J. Electrochem. Soc. 1989, 736, 3576.
15. Li, J.; Khan, I. M. Highly Conductive Solid Polymer Electrolytes Prepared by Blending High Molecular Weight Poly-(ethylene oxide), Poly(2-or 4-vinylpyridine), and Lithium Perchlorate. Macromolecules 1993, 26, 4544.
16. MacCallum J. R.; Vincent C. A. Polymer Electrolyte Reviews I; Elsevier Applied Science: London, 1987.
17. MacCallum J. R.; Vincent C. A. Polymer Electrolyte Reviews II; Elsevier Applied Science: London, 1989.
18. Gray F. M. Solid Polymer Electrolytes; VCH Publischers, Inc.: New York, 1991.
19. +-Conductive Solid Polymer Electrolytes with Liquid-like Conductivity. J. Electrochem. Soc. 1990, 737, 1657.
20. Ohno, H.; Matsuda, H.; Mizoguchi, K.; Tsuchida, E. A Demonstration of Solid-State Cell Based on Poly(Vinylidene Fluoride) System Containing Lithium Perchlorate. Polym. Bull. 1982, 7, 271.
21. Tsuchida, E.; Ohno, H.; Tsunemi, T. Conduction of Lithium Ions in Polyvinylidene Fluoride and Its Derivatives-I. Electrochim. Acta 1983, 28, 591.
22. Nagatomo, T.; Ichikama, C.; Omoto, O. All-Plastic Batteries with Polyacetylene Electrodes. J. Electrochem. Soc. 1987, 134, 305.
23. Hong, H.; Liquan, C.; Xuejie, H.; Rongjian, X. Studies on PAN-based Lithium Salt Complex. Electrochim. Acta 1992, 37, 1671.
24. Croce, F.; Gerace, F.; Dautzemberg, G.; Passerini, S.; Appetecchi, G. B.; Scrosati, B. Synthesis and Characterization of Highly Conducting Gel Electrolytes. Electrochim. Acta 1994, 39, 2187.
25. Yang, C. H.; Lin, S. M.; Wen T. C. Application of Statistical Experimental Strategies to the Process Optimization of Waterborne Polyurethane. Polym. Eng. Sci. 1995, 8, 722.
26. Yang, C. H.; Li, Y. J.; Wen, T. C. A Mixture Design Approach to PEG-PPG-PTMG Ternary Polyol-Based Waterborne Polyurethanes. Ind. Eng. Chem. Res. 1997, 36, 1614.
27. 6XDI-XDI Ternary Diisocyanate-Based Waterborne Polyurethanes. Polymer 1998, 40, 871.
28. Cheng, T. T.; Wen, T. C. Novel Water-borne Polyurethane Based Electrolytes for Lithium Batteries-(I) Tailor-Made Polymer. J. Electroanal. Chem. 1998, 495, 99.
29. 3-PC. Solid State Ionics 1998, 107, 161.
30. Cheng, T. T.; Wen, T. C. Novel Waterborne Polyurethane Based Electrolytes for Lithium Batteries-(III) Interfacial Behavior between Electrolyte and Lithium. J. Chin. Inst. Chem. Eng. 1998, 29, 319.
31. Cheng, T. T.; Wen, T. C. Novel Waterborne Polyurethane Based Electrolytes for Lithium Batteries-(IV) The Influence of DMPA/PEG Ratios on Conductivity. J. Chin. Inst. Chem. Eng. 1998, 29, 327.
32. 3-PC on the Conductivity of H12MDI Based WPU Electrolytes J. Chin. Inst. Chem. Eng. 1998, 29, 239.
33. Wen, T. C.; Wang, Y. J. Application of Experimental Design to the Conductivity Optimization for Waterborne Polyurethane Electrolytes. Ind. Eng. Chem. Res. 1999, 38, 1415.
34. 4/PC. J. Electrochem. Soc. 1998, 145, 3450.
35. Gozdz, A. S.; Schmutz, C. N.; Tarascon, J. M.; Warren, P. C. U.S. Patent 5,456,000, 1995.
36. Wen, T. C.; Wu, M. S.; Yang, C. H. Spectroscopic Investigations of Poly(oxypropylene)glycol-Based Waterborne Polyurethane Doped with Lithium Perchlorate. Macromolecules 1999, 32, 2712.
37. Lin, S. M.; Wen, T. C. A Mixture Design Approach to the Service Life and the Oxygen Evolving Catalytic Activity of Ru-Sn-Ti Ternary Oxide Coated Electrodes. J. Appl. Electrochem. 1993, 23, 487.