Novel waterborne polyurethane based electrolytes for lithium batteries-(IV). The influence of DMPA/PEG ratios on conductivity

Journal of the Chinese Institute of Chemical Engineers

Volumn 29, Issue 5, 1998, Pages 327-335

  Cheng, Tsung Tien ^a   Wen, Ten Chin ^a  

^a NATIONAL CHENG KUNG UNIVERSITY   (Taiwan)

Author keywords

Gel electrolyte; Lithium ion polymer battery; Polymer electrolyte; Single ion conductor; Waterborne polyurethane

Indexed keywords

ELECTRIC CONDUCTIVITY MEASUREMENT; GELS; IONIC CONDUCTION IN SOLIDS; ORGANIC SOLVENTS; PLASTIC FILMS; POLYETHYLENE GLYCOLS; POLYURETHANES; SOLID ELECTROLYTES;

GEL FILMS; POLYMER ELECTROLYTES;

LITHIUM BATTERIES;

ELECTROLYTE;

EID: 0032173132     PISSN: 03681653     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (25)

1. Abraham, K. M., and M. Alamgir, "Ambient-temperature rechargeable polymer-electrolyte batteries," J. Power Sources, 43, 195(1993).
2. Allcock, H. R., P. E. Austin, T. X. Neeman, J. T. Sisko, P. M. Blonsky, and D. F. Shriver, "Polyphosphazenes with etheric side groups-prospective biomedical and electrolyte polymers," Macromolecules, 19, 1508(1986).
3. Barthel, J., R. Buestrich, E. Carl and H. J. Gores, "New class of electrochemically and thermally stable lithium salts for lithium batteries in dimethoxythane and propylene carbonate," J. Electrochem. Soc., 143, 3565(1996).
4. Blonsky, P. M., D. F. Shriver, P. E. Austin, and H. R. Allcock, J. Amer. Chem. Soc., 106, 6854(1984).
5. Blonsky, P. M., D. F. Shriver, P. E. Austin, and H. R. Allcock, "Complex-formation and ionic-conductivity of polyphosphazene solid electrolytes," Solid State Ionics, 18/19, 258(1986).
6. Cheng, T. T. and T. C. Wen, "Novel waterborne Polyurethane based electrolytes for lithium batteries-(I) tailor-made polymer," J. Electroanal. Chem., in revision (1998a).
7. Cheng, Y. T. and T. C. Wen, "Novel waterborne polyurethane based electrolytes for lithium batteries-(II) the effect of adding LiCF3SO3-PC," Solid State Ionics, in press (1998b).
8. Cheng, T. T. and T. C. Wen, "Mixing WPU(PEG)-WPU(PTMG)-PEO for gel electrolytes via a mixture design approach," J. of Electrochem. Soc., Submitted (1998c).
9. Choe, H. S., Giaccai, J., Alamgir, M., and Abraham, K. M., "Preparation and characterization of poly(vinyl sulfone)- and poly(vinylidene fluoride)-based electrolytes," Electrochim. Acta, 40, 2289(1995).
10. Croce, F., F. Gerace, G. Dautzemberg, S. Passerini, G. B. Appetecchi, and B. Scrosati, "Synthesis and characterization of highly conducting gel electrolytes," Electrochim. Acta, 39, 2187(1994).
11. Fauteux, D., A. Massucco, M. Mclin, M. van Buren and J. Shi, "Lithium polymer electrolyte rechargeable battery," Electrochim. Acta, 40, 2185(1995).
12. Giles, J. R. M., F. M. Gray, J. R. MacCallum, and C. A. Vincent, "Synthesis and characterization of ABA block copolymer-based polymer electrolytes," Polymer, 28, 1977(1987).
13. Giles, J. R. M., "Electrolytic conduction in amorphous salt complexed polyethers," Solid State Ionics, 24, 155 (1987).
14. Gray, F. M., J. R. MacCallum, J. R. M. Giles, and C. A. Vincent, "Novel polymer electrolytes based on ABA block copolymers," Macromolecules, 21, 392 (1988).
15. Hong, H., C. Liquan, H. Xuejie, and X. Rongjian, "Studies on PAN-based lithium salt complex," Electrochim. Acta, 37, 1671(1992).
16. Lee, H. S., X. Q. Yang, J. McBreen, Z. S. Xu, T. A. Skotheim and Y. Okamoto, "Ionic conductivity of a polymer electrolyte with modified carbonate as a plasticizer for poly ( ethylene oxide )," J. Electrochem. Soc., 141, 886(1994).
17. Murata, K., "An overview of the research-and-development of solid polymer electrolyte batteries," Electrochim. Acta, 40, 2177(1995).
18. Nicholas, C. V., D. J. Wilson, C. Booth, and J. R. M. Giles, "Mesogenic structure and charge-transfer reactions in poly(ethylene oxide) complexes," Brit. Polymer J., 20, 293 (1988).
19. Ramanujachary, K. V., X. Tong, Y. Lu, J. Kohn and M. Greenblatt, "Lithium ionic conductivity in poly(ether urethanes) derived from poly(ethylene glycol) and lysine ethyl ester," J. Appl. Polym. Sci., 63, 1449(1997).
20. 3 films," J. Electrochem. Soc., 136, 2565 (1989).
21. 3," J. Electrochem. Soc., 141, 2978 (1994).
22. Watanabe, M., K. Sanui, N. Ogata, T. Kobayashi, and Z. Ohtaki, "Ionic-conductivity and mobility in network polymers from poly(propylene oxide) containing lithium perchlorate," J. Appl. Phys., 57, 123 (1985).
23. Watanabe, M., S. Oohashi, N. Ogata, Z. Ohtaki, K. Sanui, and T. Kobayashi, "Morphology and ionic-conductivity of polymer complexes formed by segmented polyether poly ( urethane urea ) and lithium perchlorate," Macromolecules, 18, 1945(1985).
24. 4/PC," J. Electrochem. Soc., in revision (1998).
25. Yang, C. H., S. M. Lin and T. C. Wen, "Application of Statistical Experimental Strategies to the Process Optimization of Waterborne Polyurethane," Polym. Eng. Sci., 35, 722(1995).