Kinetic and mechanistic study of the H-transfer reduction of dimethyl itaconate by a Rh/TPPTS catalyst under biphasic conditions: Evidence for a rhodametallacycle intermediate

European Journal of Inorganic Chemistry

Volumn , Issue 7, 2000, Pages 1495-1502

  Tanchoux, Nathalie ^a   De Bellefon, Claude ^a  

^a CPE LYON   (France)

Author keywords

Biphasic catalysis; H transfer; Kinetics; Metallacyclobutanes; Reaction mechanisms; Rhodium

Indexed keywords

CATALYSIS; REACTION KINETICS; RHODIUM COMPOUNDS; SODIUM COMPOUNDS;

% REDUCTIONS; BIPHASIC CATALYSIS; DIMETHYL ITACONATE; H-TRANSFER; KINETIC STUDY; MECHANISTIC STUDIES; METALLACYCLOBUTANE; REACTION MECHANISM; RH/TPPTS; ]+ CATALYST;

KINETICS;

CYCLOBUTANE DERIVATIVE; ITACONIC ACID; RHODIUM DERIVATIVE; SODIUM DERIVATIVE; WATER;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; GAS CHROMATOGRAPHY; PROTON TRANSPORT; REACTION ANALYSIS;

EID: 0033940247     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200007)2000:7<1495::AID-EJIC1495>3.0.CO;2-J     Document Type: Article

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