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Volumn 36, Issue 10, 1997, Pages 1103-1105

Proof of Chiral Dihydride Complexes Including Catalyst and Substrate during the Bis(phosphinite)rhodium(I)-Catalyzed Hydrogenation of Dimethyl Itaconate

Author keywords

Homogeneous catalysis; Hydrido complexes; NMR spectroscopy; Parahydrogen; Rhodium

Indexed keywords


EID: 0030814292     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199711031     Document Type: Article
Times cited : (32)

References (16)
  • 4
    • 0030445706 scopus 로고    scopus 로고
    • A. Harthun, R. Selke, J. Bargon, Angew. Chem. 1996, 108, 2666-2669; Angew. Chem. Int. Ed. Engl. 1996, 35, 2505-2507.
    • (1996) Angew. Chem. Int. Ed. Engl. , vol.35 , pp. 2505-2507
  • 8
    • 0000634303 scopus 로고
    • P. L. Bogdan, J. J. Irwin, B. Bosnich, Organometallics 1989, 8, 1450-1453; J. M. Brown, P. L. Evans, Tetrahedron 1988, 44, 4905-4916.
    • (1988) Tetrahedron , vol.44 , pp. 4905-4916
    • Brown, J.M.1    Evans, P.L.2
  • 9
    • 0000935935 scopus 로고
    • Molecular modeling calculations under assumption of an ideal octahedral geometry show lengthening of the Rh-P bond trans to the hydride (distortion of the octahedral geometry was not considered): J. S. Giovannetti, C. M. Kelly, C. R. Landis, J. Am. Chem. Soc. 1993, 115, 4040-4057.
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 4040-4057
    • Giovannetti, J.S.1    Kelly, C.M.2    Landis, C.R.3
  • 10
    • 0642382619 scopus 로고    scopus 로고
    • Simulations were performed with the computer program PHIP+ + , which was developed by T. Greve (Bonn, Germany)
    • Simulations were performed with the computer program PHIP+ + , which was developed by T. Greve (Bonn, Germany).
  • 11
    • 0642352159 scopus 로고    scopus 로고
    • Ph.D. thesis, Universität Bonn
    • A. Harthun, Ph.D. thesis, Universität Bonn, 1996.
    • (1996)
    • Harthun, A.1
  • 14
    • 0003960956 scopus 로고
    • (Ed.: A. Dedieu), VCH, Weinheim
    • Polarization signals of the dihydride catalyst-substrate complex by hydrogenation with 2c are only observed when 1 is partially deuterated beforehand; this may be due to an inverse kinetic isotope effect: M. R. Bullock in Transition Metal Hydrides (Ed.: A. Dedieu), VCH, Weinheim, 1992, 263-307.
    • (1992) Transition Metal Hydrides , pp. 263-307
    • Bullock, M.R.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.