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note
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Apparently, Brooks is attempting to convey the Brtnsted acidity of these materials using a familiar frame of reference, although it is unclear whether that conveyance is qualitative or quantitative. If it is qualitative, then one could infer that the proton-donating ability of these minerals is significant, as evidenced by the fact that HC1 is a strong, solution-phased acid. Indeed, numerous studies support the . notion that silica-aluminas are strong, solid acids. However, complications arise if the comparison is quantitative. Farneth and Gorte118 state that one "...real problem is the lack of an acceptable scale of solid acidity comparable to...scales for aqueous solutions,...[given]...that solvation effects are extremely important in the overall thermochemistry of proton transfer."
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