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Volumn 14, Issue 2, 2000, Pages 235-258

Mechanisms and kinetics of reactions leading to natural gas formation during coal maturation

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CARBON DIOXIDE; CATALYTIC CRACKING; COAL HYDROGENATION; KEROGEN; METHANE; NATURAL GAS; REACTION KINETICS;

EID: 0033898542     PISSN: 08870624     EISSN: None     Source Type: Journal    
DOI: 10.1021/ef990076k     Document Type: Article
Times cited : (26)

References (178)
  • 178
    • 33749139907 scopus 로고    scopus 로고
    • note
    • Apparently, Brooks is attempting to convey the Brtnsted acidity of these materials using a familiar frame of reference, although it is unclear whether that conveyance is qualitative or quantitative. If it is qualitative, then one could infer that the proton-donating ability of these minerals is significant, as evidenced by the fact that HC1 is a strong, solution-phased acid. Indeed, numerous studies support the . notion that silica-aluminas are strong, solid acids. However, complications arise if the comparison is quantitative. Farneth and Gorte118 state that one "...real problem is the lack of an acceptable scale of solid acidity comparable to...scales for aqueous solutions,...[given]...that solvation effects are extremely important in the overall thermochemistry of proton transfer."


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.