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Volumn 16, Issue 7, 2000, Pages 3288-3293

Underpotentially deposited copper promotes self-assembly of alkanephosphonate monolayers on gold substrates

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; CHEMISORPTION; COMPOSITION EFFECTS; COPPER; DEPOSITION; ELECTROCHEMISTRY; MOLECULAR ORIENTATION; MONOLAYERS; PHOSPHORUS COMPOUNDS;

EID: 0033897496     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la991247g     Document Type: Article
Times cited : (32)

References (49)
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    • note
    • 2-, or some mixture of these forms) is not known and could not be established.
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    • note
    • We note that the silver coverage of 0.7 is less than that of 0.9 previously reported by us in ref 21. The value of 0.7 reflects a more accurate estimate of the coverage as the value of 0.9 was determined using an incorrect sensitivity factor for Au in XPS.
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    • note
    • 1 Because any adventitious contaminants on the surface are typically displaced by the monolayer, ellipsometry can underestimate its thickness. Because the Au substrates were plasma cleaned immediately before a sequence of Cu upd and ellipsometric characterization, the Au/Cu(upd) samples used here likely had a lower level of adsorbed contaminants than substrates used in other studies without plasma cleaning. Consequently, the extent that substrate contamination would cause ellipsometry to underestimate the thickness of a monolayer should be less than that in other work.
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    • (After 20 continuous cyclic voltammograms, the integrated intensity for the ferrocene signal for an adsorbed ferrocenylundecanephosphonate SAM on the Au/Cu(upd) substrate was ∼85% of its initial value.
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    • note
    • See ref 30 for examples of odd-even spectral variations in alkanethiolate SAMs on gold.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.