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It has recently been reported that azaferrocene quenches the fluorescence of sulfonated zinc(II) phthalocyanine in dimethyl sulfoxide in which a phthalocyanine-azaferrocene adduct linked through axial coordination may be involved (see J. Delaire, C. Giannotti, J. Zakrzewski, J. Photochem. Photobiol. A: Chem. 1998, 112, 205-207).
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No attempt was made to calculate the free energy change for both processes using the Rehm-Weller equation (D. Rehm, A. Weller, Isr. J. Chem. 1970, 8, 259) as electrochemical potentials of phthalocyanines are invariably erroneous due to the aggregation phenomena (see for example: H. Isago, C. C. Leznoff, M. F. Ryan, R. A. Metcalfe, R. Davids, A. B. P. Lever, Bull. Chem. Soc. Jpn. 1998, 71, 1039-1047).
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No attempt was made to calculate the free energy change for both processes using the Rehm-Weller equation (D. Rehm, A. Weller, Isr. J. Chem. 1970, 8, 259) as electrochemical potentials of phthalocyanines are invariably erroneous due to the aggregation phenomena (see for example: H. Isago, C. C. Leznoff, M. F. Ryan, R. A. Metcalfe, R. Davids, A. B. P. Lever, Bull. Chem. Soc. Jpn. 1998, 71, 1039-1047).
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41
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85153328448
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note
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Some of the pyridyl and β protons' signals of 1 were so broad that the integration could not be determined accurately.
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