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Volumn , Issue 8, 2000, Pages 1845-1848

Self-assembly of meso-pyridylporphyrins and zinc phthalocyanines through axial coordination

Author keywords

Axial coordination; Phthalocyanines; Porphyrins; Self assembly; Zinc

Indexed keywords

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ZINC COMPOUNDS;

EID: 0033855216     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200008)2000:8<1845::aid-ejic1845>3.0.co;2-1     Document Type: Article
Times cited : (25)

References (41)
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    • See for example: [4a] H. Kurreck, M. Huber, Angew. Chem. Int. Ed. Engl. 1995, 34, 849-866 and references cited therein. [4b] H. Imahori, K. Yamada, E. Yoshizawa, K. Hagiwara, T. Okada, Y. Sakata, J. Porphyrins Phthalocyanines 1997, 1, 55-66. [4c] A. G. Hyslop, M. J. Therien, Inorg. Chim. Acta, 1998, 275-276, 427-434.
    • (1995) Angew. Chem. Int. Ed. Engl. , vol.34 , pp. 849-866
    • Kurreck, H.1    Huber, M.2
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    • See for example: [4a] H. Kurreck, M. Huber, Angew. Chem. Int. Ed. Engl. 1995, 34, 849-866 and references cited therein. [4b] H. Imahori, K. Yamada, E. Yoshizawa, K. Hagiwara, T. Okada, Y. Sakata, J. Porphyrins Phthalocyanines 1997, 1, 55-66. [4c] A. G. Hyslop, M. J. Therien, Inorg. Chim. Acta, 1998, 275-276, 427-434.
    • (1998) Inorg. Chim. Acta , vol.275-276 , pp. 427-434
    • Hyslop, A.G.1    Therien, M.J.2
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    • 0033531665 scopus 로고    scopus 로고
    • See for example: [5a] T. Da Ros, M. Prato, D. Guldi, E. Alessio, M. Ruzzi, L. Pasimeni, Chem. Commun. 1999, 635-636. [5b] N. Armaroli, F. Diederich, L. Echegoyen, T. Habicher, L. Flamigni, G. Marconi, J.-F. Nierengarten, New J. Chem. 1999, 77-83. [5c] F. D'Souza, G. R. Deviprasad, M. S. Rahman and J.-p. Choi, Inorg. Chem. 1999, 38, 2157-2160.
    • (1999) Chem. Commun. , pp. 635-636
    • Da Ros, T.1    Prato, M.2    Guldi, D.3    Alessio, E.4    Ruzzi, M.5    Pasimeni, L.6
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    • See for example: [5a] T. Da Ros, M. Prato, D. Guldi, E. Alessio, M. Ruzzi, L. Pasimeni, Chem. Commun. 1999, 635-636. [5b] N. Armaroli, F. Diederich, L. Echegoyen, T. Habicher, L. Flamigni, G. Marconi, J.-F. Nierengarten, New J. Chem. 1999, 77-83. [5c] F. D'Souza, G. R. Deviprasad, M. S. Rahman and J.-p. Choi, Inorg. Chem. 1999, 38, 2157-2160.
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    • D'Souza, F.1    Deviprasad, G.R.2    Rahman, M.S.3    Choi, J.-P.4
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    • Phthalocyanines - Properties and Applications (Eds.: C. C. Leznoff, A. B. P. Lever), VCH, New York, 1989, vol. 1; 1993, vol. 2; 1993, vol. 3; 1996, vol. 4.
    • (1993) Phthalocyanines - Properties and Applications , vol.2
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    • Phthalocyanines - Properties and Applications (Eds.: C. C. Leznoff, A. B. P. Lever), VCH, New York, 1989, vol. 1; 1993, vol. 2; 1993, vol. 3; 1996, vol. 4.
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    • Phthalocyanines - Properties and Applications (Eds.: C. C. Leznoff, A. B. P. Lever), VCH, New York, 1989, vol. 1; 1993, vol. 2; 1993, vol. 3; 1996, vol. 4.
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    • (Eds.: K. M. Kadish, K. M. Smith, R. Guilard), Academic Press, San Diego, chapter 20
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    • It has recently been reported that azaferrocene quenches the fluorescence of sulfonated zinc(II) phthalocyanine in dimethyl sulfoxide in which a phthalocyanine-azaferrocene adduct linked through axial coordination may be involved (see J. Delaire, C. Giannotti, J. Zakrzewski, J. Photochem. Photobiol. A: Chem. 1998, 112, 205-207).
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    • N-H exchange in free-base porphyrins is normally rapid on the NMR timescale at room temperature, see for example: N. Kariya, T. Imamura, Y. Sasaki, Inorg. Chem. 1997, 36, 833-839.
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    • No attempt was made to calculate the free energy change for both processes using the Rehm-Weller equation (D. Rehm, A. Weller, Isr. J. Chem. 1970, 8, 259) as electrochemical potentials of phthalocyanines are invariably erroneous due to the aggregation phenomena (see for example: H. Isago, C. C. Leznoff, M. F. Ryan, R. A. Metcalfe, R. Davids, A. B. P. Lever, Bull. Chem. Soc. Jpn. 1998, 71, 1039-1047).
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    • No attempt was made to calculate the free energy change for both processes using the Rehm-Weller equation (D. Rehm, A. Weller, Isr. J. Chem. 1970, 8, 259) as electrochemical potentials of phthalocyanines are invariably erroneous due to the aggregation phenomena (see for example: H. Isago, C. C. Leznoff, M. F. Ryan, R. A. Metcalfe, R. Davids, A. B. P. Lever, Bull. Chem. Soc. Jpn. 1998, 71, 1039-1047).
    • (1998) Bull. Chem. Soc. Jpn. , vol.71 , pp. 1039-1047
    • Isago, H.1    Leznoff, C.C.2    Ryan, M.F.3    Metcalfe, R.A.4    Davids, R.5    Lever, A.B.P.6
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    • note
    • Some of the pyridyl and β protons' signals of 1 were so broad that the integration could not be determined accurately.


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