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Volumn 12, Issue 8, 2000, Pages 2070-2072

Organo-directed synthesis of manganese vanadates with variable stoichiometry and dimensionality: 1-D [(Hen)2Mn(VO3)4], 2-D [H2en]2[Mn(VO3)6], and 3-D [H2en][MnF(VO3)3]

Author keywords

[No Author keywords available]

Indexed keywords

FLUORIDE; ION; MANGANESE; VANADIC ACID;

EID: 0033802927     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm000190c     Document Type: Article
Times cited : (46)

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    • -1 in air) -Δw (200-450°C) = 20.4%. EDAX gave a Mn:V ratio of 1:3.8. Elemental combustion analysis: found (calc); C 8.48 (8.38); H 3.19 (3.14); N 9.65 (9.77)%.
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    • Synthesis of MnVO-4: As for MnVO-3 above, but at 110°C. Isolated ∼10 mg of MnVO-4 as a minor component with MnVO-1 and MnVO-3. EDAX gave Mn:V ratio 1:5.7.
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    • 4 (110 mg, 1.0 mmol). Reaction pH: 6. Yield: 105 mg of MnVO-5, (∼70% yield based on V). TGA: -Δw (250-450°C) = 14.6%, XPS gave a Mn:V:F ratio of 1.1:2.8:1.0. Elemental combustion analysis: found (calc); C 5.88 (5.54); H 2.42 (2.31); N 6.34 (6.47)%.
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