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1642620930
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note
-
-1 in air) -Δw (200-450°C) = 20.4%. EDAX gave a Mn:V ratio of 1:3.8. Elemental combustion analysis: found (calc); C 8.48 (8.38); H 3.19 (3.14); N 9.65 (9.77)%.
-
-
-
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28
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1642620931
-
-
note
-
-3.
-
-
-
-
30
-
-
1642636416
-
-
note
-
Synthesis of MnVO-4: As for MnVO-3 above, but at 110°C. Isolated ∼10 mg of MnVO-4 as a minor component with MnVO-1 and MnVO-3. EDAX gave Mn:V ratio 1:5.7.
-
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31
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1642605361
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-
note
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-3.
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-
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33
-
-
1642620932
-
-
note
-
4 (110 mg, 1.0 mmol). Reaction pH: 6. Yield: 105 mg of MnVO-5, (∼70% yield based on V). TGA: -Δw (250-450°C) = 14.6%, XPS gave a Mn:V:F ratio of 1.1:2.8:1.0. Elemental combustion analysis: found (calc); C 5.88 (5.54); H 2.42 (2.31); N 6.34 (6.47)%.
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