Electron-poor olefin polymerization catalysts based on semi-fluorinated bis(phosphane)s

European Journal of Inorganic Chemistry

Volumn , Issue 9, 2000, Pages 2063-2070

  Wursche, Roland ^a   Debaerdemaeker, Tony ^a   Klinga, Martti ^b   Rieger, Bernhard ^a  

^a UNIVERSITY OF ULM   (Germany)

^b UNIVERSITY OF HELSINKI   (Finland)

Author keywords

Fluorine; Palladium; Phosphanes; Platinum; Polymerizations

Indexed keywords

CATALYSTS; IODINE COMPOUNDS; PALLADIUM COMPOUNDS; PLATINUM COMPOUNDS; SINGLE CRYSTALS; SODIUM IODIDE; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION ANALYSIS;

DICHLORO COMPLEXES; DIFLUOROPHENYL; DIPHENYLPHOSPHANE; HALIDE EXCHANGE; OLEFIN POLYMERIZATION CATALYSTS; PHOSPHANES; RELATED COMPOUNDS; SOLID-STATE STRUCTURES; SYNTHESISED; TRIFLUOROMETHYL;

POLYMERIZATION;

ALKENE; BISPHOSPHONIC ACID DERIVATIVE; P,P' (1,2 ETHANEDIYL)BIS[BIS(2,4 DIFLUOROPHENYL)PHOSPHANE] DERIVATIVE; P,P' (1,2 ETHANEDIYL)BIS[BIS(2,4,5 TRIFLUOROPHENYL)PHOSPHANE] DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; COMPLEX FORMATION; CRYSTAL STRUCTURE; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; SOLID STATE; STEREOSPECIFICITY; STRUCTURE ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

EID: 0033801623     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200009)2000:9<2063::aid-ejic2063>3.0.co;2-e     Document Type: Article

References (48)

1. Recent review: H.-U. Blaser, Tetrahedron: Asymmetry 1991, 2, 843 and references cited therein.
2. K. Tamo, K. Sumitami, M. Kumada, J. Am Chem. Soc. 1972, 94, 4374.
3. M. Kumada, Pure Appl. Chem. 1980, 52, 669.
4. G. Wilke, Angew. Chem. Int. Ed. Engl. 1988, 27, 185.
5. V. M. Möhring, G. Fink, Angew. Chem. Int. Ed. Engl. 1985, 24, 1001.
6. M. F. Ernst, D. M. Roddick, Inorg. Chem. 1989, 28, 1624.
7. R. L. Cook, J. G. Morse, Inorg. Chem. 1982, 21, 4103.
8. R. C. Schnabel, D. M. Roddick, ACS Symp. Ser. 1994, 55, 421 and references cited therein.
9. R. C. Schnabel, R. S. Carroll, D. M. Roddick, Organometallics 1996, 15, 655.
10. B. L. Bennett, J. Birnbaum, D. M. Roddick, Polyhedron 1995, 14, 187.
11. M. F. Ernst, D. M. Roddick, Organometallics 1990, 9, 1586.
12. M. F. Ernst, D. M. Roddick, Inorg. Chem. 1990, 29, 3627.
13. M. Brookhart, W. A. Chandler, A. C. Pfister, C. C. Santini, P. S. White, Organometallics 1992, 11, 1263.
14. R. K. Merwin, R. C. Schnabel, J. D. Koola, D. M. Roddick, Organometallics 1992, 11, 2972.
15. L. D. Field, M. P. Wilkinson, Organometallics 1997, 16, 1841.
16. R. B. King, W. M. Rhee, Inorg. Chem. 1978, 17, 2961.
17. R. J. Burt, J. Chatt, W. Hussain, G. J. Leigh, J. Organomet. Chem. 1979, 182, 203.
18. H. Nishida, N. Takada, M. Yoshimura, T. Sonoda, H. Kobayashi. Bull. Chem. Soc. Jpn. 1984, 57, 2600.
19. C. P. Casey, E. L. Paulsen, E. W. Beuttenmueller, B. R. Proft, L. M. Petrovich, B. A. Matter, D. R. Powell, J. Am. Chem. Soc. 1997, 119, 11817 and related supplementary material.
20. P. E. Garrou, Inorg. Chem. 1975, 14, 1435.
21. BISBI = 2,2′-bis[(diphenylphosphanyl)methyl]-1,1′-biphenyl.
22. M. J. Atherton, K. S. Coleman, J. Fawcett, J. H. Holloway, E. G. Hope, A. Karacar, L. A. Peck, G. C. Saunders, J. Chem. Soc., Dalton Trans. 1995, 4029.
23. M. J. Atherton, K. S. Coleman, J. Fawcett, J. H. Holloway, E. G Hope, A. Karacar, D. R. Russell, G. C. Saunders, J. Chem. Soc., Dalton Trans. 1996, 3215.
24. W. Oberhauser, C. Bachmann, T. Stampfl, R. Haid, P. Brügeller, Polyhedron 1997, 16, 2827.
25. S. Singh, N. K. Jha, P. Narula, T. P. Singh, Acta Crystallogr. C 1995, 51, 593.
26. W. E. Steffen, G. J. Palenik, Inorg. Chem. 1976, 15, 2432.
27. F. Rix, M. Brookhart, J. Am. Chem. Soc. 1995, 117, 1137.
28. M. Peuckert, W. Keim, Organometallics 1983, 2, 594.
29. G. F. Schmidt, M. Brookhart, J. Am. Chem. Soc. 1985, 107, 1443.
30. Brookhart, A. F. Volpe, Jr., D. M. Eincoln, I. T. Horvath, J. M. Millar, J. Am. Chem. Soc. 1990, 112, 5643.
31. U. Klabunde, S. D. Ittel, J. Mol. Catal. 1987, 41, 123.
32. E. K. Johnson, C. M. Killian, M. Brookhart, J. Am. Chem. Soc. 1995, 117, 6414.
33. w 260-470) using an iron catalyst, see: G. J. P. Britovsek, V. C. Gibson, B. S. Kimberley, P. J. Maddox, S. J. McTavish, G. A. Solan, A. J. P. White, D. J. Williams, Chem. Commun. 1998, 849.
34. w 260-470) using an iron catalyst, see: G. J. P. Britovsek, V. C. Gibson, B. S. Kimberley, P. J. Maddox, S. J. McTavish, G. A. Solan, A. J. P. White, D. J. Williams, Chem. Commun. 1998, 849.
35. J. Melia, E. Connor, S. Rush, S. Breunig, C. Mehler, W. Risse, Macromol. Symp. 1995, 89, 433.
36. B. L. Goodall, G. M. Benedikt, L. H. McIntosh III, D. A. Barnes (B. F. Goodrich Co.), World Patent WO 95 14048 A1; Chem. Abstr. 1995, 123, 341322p.
37. 11-based system: D. Pappalardo, M. Mazzeo, C. Pellechia, Makromol. Chem. Rapid. Commun. 1997, 18, 1017.
38. DPPP = P,P′-(1,3-propanediyl)bis(diphenylphosphane), DPPE = P,P′-(1,2-ethanediyl)bis(diphenylphosphane).
39. 11 and, as a consequence, enhanced steric interactions between the ligand, the growing polymer chain, and the coordinated monomer, this complex is less active in the polymerization of norbornene.
40. In the case of Pt-alkyl complexes, the insertion process of a C=C bond is energetically less favourable than for Pd or Ni complexes due to the high stability of the Pt-C bond.
41. F. P. Alt, W. Heitz, Macromol. Chem. Phys. 1998, 199, 1951.
42. B. L. Goodall, L. H. McIntosh III, L. F. Rhodes, Macromol. Symp. 1995, 59, 421.
43. R. R. Schrock, Acc. Chem. Res. 1990, 23, 158.
44. B. M. Novak, W. Risse, R. H. Grubbs, Adv. Polym. Sci. 1992, 102, 47.
45. A. S. Abu-Surrah, B. Rieger, J. Mol. Catal. A: Chemical 1998, 128, 239.
46. D. Drew, J. R. Doyle, Inorg. Synth. 1972, 13, 52.
47. J. R. Doyle, P. E. Slade, H. B. Jonassen, Inorg. Synth. 1960, 6, 218.
48. T. Debaerdemaeker, Z. Kristallogr. 1993, 206, 173.