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26
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0343168705
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note
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2 S), where A is a constant including the volume of a critical germ and the interfacial enthalpy by surface unit. Equation 2 is obtained from the two previous expressions injected in eq 1. In eq 3 B is a constant depending on the type of the growth (dislocation, spiral, etc.).
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29
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0343604164
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note
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-1. The turnover numbers given are relative to the total mass of metal present on the silica, and take no account of the slightly different aggregate sizes in the different catalysts. Even at relatively low conversion levels, the palladium catalysts are completely specific for the formation of benzene, and no cyclohexene was observed. However, cyclohexene was observed when the reaction was catalyzed with platinum, and was the majority product when the reaction was carried out under a regime of low conversion.
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30
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0343604162
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Unpublished results
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Unpublished results.
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